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Acta Cryst. (2007). E63, m1196-m1197  [ doi:10.1107/S1600536807013931 ]

Hexakis(pyridine N-oxide-[kappa]O)iron(II) tetraphenylborate

J. L. Crossland, L. N. Zakharov and D. R. Tyler

Abstract: The FeII cation in [Fe(C5H5NO)6](C24H20B)2 has a distorted octahedral coordination with the Fe-O distances in the range 2.085 (2)-2.148 (2) Å. In the crystal structure the [Fe(C5H5NO)6]2+ cations and the BPh4- anions are involved in a [pi]-[pi] and six C-H...[pi] intermolecular interactions between pyridine and the phenyl rings of the counter-ions.

Online 4 April 2007


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