Acta Cryst. (2007). E63, m1360-m1361  [ doi:10.1107/S1600536807016996 ]

A molecular corner: fac-tricarbonylchloridobis[3-(4-pyridyl)pentane-2,4-dione-N]rhenium(I) chloroform solvate

J. Kakoullis Jr, A. W. Maverick and F. R. Fronczek

Abstract: The title compound, [ReCl(C₁₀H₁₁NO₂)₂(CO)₃]·CHCl₃, has Re-N distances of 2.202 (8) and 2.237 (7) Å, an N-Re-N angle of 84.1 (3)° and 2-hydroxy-4-oxopent-2-en-3-yl (acacH) units which are uncoordinated. The acacH units are in the enol tautomeric form, with delocalized single and double bonds.

Online 18 April 2007

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