Acta Cryst. (2007). E63, m1704  [ doi:10.1107/S1600536807024853 ]

Chlorido{4-chloro-1-[2-(methylsulfanyl)phenyldiazenyl]phenyl-³C,N,S}palladium(II)

V. Bagchi, P. Das and D. Bandyopadhyay

Abstract: The Pd atom in the title compound, [Pd(C₁₃H₁₀ClN₂S)Cl], is tetracoordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The molecules are found to dimerize through a nonbonded SS interaction [SS = 3.5162 (17) Å]. There are no hydrogen bonds and the crystal packing is stabilized by four intermolecular - interactions; the centroid-centroid distances are 3.808 (2), 3.623 (2), 3.808 (2) and 3.623 (2) Å; the corresponding perpendicular distances are 3.462, 3.454, 3.402 and 3.402 Å with no slippages.

Online 26 May 2007

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