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Acta Cryst. (2007). E63, m1614-m1615  [ doi:10.1107/S1600536807021526 ]

Chlorido(N,N-dimethylformamide-[kappa]O){2-(4-methylphenyldiazenyl)-3-(methylsulfonyl)phenyl-[kappa]2C,N}palladium(II)

V. Bagchi and D. Bandyopadhyay

Abstract: In the title compound, [Pd(C14H13N2O2S)Cl(C3H7NO)], the Pd atom is tetracoordinated by a phenyl C, a diazene N, a Cl and a dimethylformamide O atom in an approximate square-planar geometry. There are intramolecular C-H...O, C-H...N and C-H...Cl interactions. The crystal packing is stabilized by weak intermolecular [pi]-[pi] interactions; the Cg-Cg distance is 3.920 (4) Å and the perpendicular distance is 3.302 Å with a slippage of 2.113 Å.

Online 10 May 2007


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