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Acta Cryst. (2007). E63, m1577  [ doi:10.1107/S1600536807021137 ]

(2,2'-Bipyridine-[kappa]2N,N')(nitrato-[kappa]2O,O')bis(pyrrolidine-1-dithiocarboxylato-[kappa]2S,S')bismuth(III)

F. Li, H.-D. Yin and D.-Q. Wang

Abstract: The title compound, [Bi(C4H8NS2)2(NO3)(C10H8N2)], is monomeric, with the Bi atom chelated by the S atoms of two pyrrolidine-1-dithiocarboxylate ligands and the N atoms of a 2,2'-bipyridine ligand. A nitrate ligand completes the coordination, with the eight-coordinated Bi atom adopting a highly distorted capped pentagonal-bipyramidal geometry.

Online 3 May 2007


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