Acta Cryst. (2007). E63, m1718-m1719  [ doi:10.1107/S1600536807023173 ]

cis-Dichloridobis{[(S)-N-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl]dibenz[b,f]azepin-P}palladium(II) deuterochloroform disolvate

A. Briceño and R. Dorta

Abstract: The chiral bidentate P-olefin ligand (S)-(3,5-dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dibenzo[b,f]azepin reacted with PdCl₂(NCCH₃)₂ to form the title compound, [PdCl₂(C₃₄H₂₂NO₂P)₂]·2CDCl₃. The Pd atom displays a distorted PdCl₂P₂ square-planar cis geometry. The title compound forms a three-dimensional hydrogen-bonded network from supramolecular right-handed helices assembled via C-HCl interactions, resulting in an array of channels along the c axis filled with deuterochloroform solvent molecules.

Online 26 May 2007

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