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Acta Cryst. (2007). E63, m1715-m1716  [ doi:10.1107/S1600536807024518 ]

Triaqua(5-formyl-N-salicylidene-DL-alaninato-[kappa]3N,O,O')nickel(II) monohydrate

J.-H. Cai, J.-M. Li and S. W. Ng

Abstract: The deprotonated Schiff-base dianion in the title compound, [Ni(C11H9NO4)(H2O)3]·H2O, occupies the meridional sites of the NiO5N octahedron. The neutral complex molecule interacts with the uncoordinated water molecule by way of O-H...O hydrogen bonds to give rise to a three-dimensional network. The ethylidene part of the molecule is disordered over two positions in a 0.74:0.26 ratio.

Online 26 May 2007


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