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Acta Cryst. (2007). E63, m1747 [ doi:10.1107/S1600536807023707 ]
Abstract: In the title complex, [Mn(SCN)2(H-Pysc)2(H2O)2] {H-Pysc = 3-[2-(aminocarbonyl)hydrazonomethyl]pyridine, C7H8N4O}, MnII, located at an inversion centre, is coordinated by two thiocyanate anions, two water molecules and two molecules of the neutral Schiff base ligand H-Pysc, forming an octahedral configuration. The Schiff base acts as a monodentate ligand, coordinating to the metal through the pyridyl N atom, whereas the amide O and imine N atoms remain uncoordinated. The complex molecules are held together by intermolecular hydrogen bonds into a three-dimensional supramolecular network.
Online 26 May 2007
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