Acta Cryst. (2007). E63, m1676  [ doi:10.1107/S1600536807022908 ]

(Acetato-²O,O')bis(1,10-phenanthroline-²N,N')cadmium(II) perchlorate dihydrate

B. Hu, M. Wang, S.-M. Lan, X.-Y. Wang and X.-T. Deng

Abstract: In the title compound, [Cd(C₂H₄O₂)(C₁₂H₈N₂)₂]ClO₄·H₂O, the Cu^II ion is in a distorted octahedral coordination geometry with normal Cd-O and Cd-N bond lengths. The cation and anion both lie on crystallographic twofold axes. In the crystal structure, intermolecular O-HO hydrogen bonds form one-dimensional chains along [100] and in addition weak - stacking interactions connect molecules along [001]. The Cg1 (central fused benzene ring) and Cg2 (outer fused pyridine ring) centroid-centroid and perpendicular distances are 3.746 (2) and 3.623 (2) Å, respectively, with Cg1Cg2ⁱ = 3.602 (2) Å [symmety code: (i) -x, 1 - y, 1 - z].

Online 23 May 2007

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