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Acta Cryst. (2007). E63, m1641-m1642  [ doi:10.1107/S1600536807020442 ]

[Lambda]L[Lambda]L-Bis([mu]-L-cysteinato)-1:2[kappa]3S:N,S;1:3[kappa]3S:N,S-tetrakis(ethylenediamine)-2[kappa]4N,N';3[kappa]4N,N'-dicobalt(III)silver(I) tris(perchlorate) pentahydrate

M. Tamura, N. Yoshinari, A. Igashira-Kamiyama and T. Konno

Abstract: In the crystal structure of the title compound, [Lambda]L[Lambda]L-[AgCo2(C3H5NO2S)2(C2H8N2)4](ClO4)3·5H2O, the AgI atom, which lies on a twofold rotation axis, is linearly coordinated by two thiolate S atoms from two [Lambda]L-[Co(C3H5NO2S)(C2H8N2)2]+ octahedral units, forming an S-bridged CoIII-AgI-CoIII trinuclear unit. The compound has two uncoordinated carboxylate groups.

Online 10 May 2007


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