Acta Cryst. (2007). E63, m1641-m1642  [ doi:10.1107/S1600536807020442 ]

_LL-Bis(-L-cysteinato)-1:2³S:N,S;1:3³S:N,S-tetrakis(ethylenediamine)-2⁴N,N';3⁴N,N'-dicobalt(III)silver(I) tris(perchlorate) pentahydrate

M. Tamura, N. Yoshinari, A. Igashira-Kamiyama and T. Konno

Abstract: In the crystal structure of the title compound, _LL-[AgCo₂(C₃H₅NO₂S)₂(C₂H₈N₂)₄](ClO₄)₃·5H₂O, the Ag^I atom, which lies on a twofold rotation axis, is linearly coordinated by two thiolate S atoms from two _L-[Co(C₃H₅NO₂S)(C₂H₈N₂)₂]⁺ octahedral units, forming an S-bridged Co^III-Ag^I-Co^III trinuclear unit. The compound has two uncoordinated carboxylate groups.

Online 10 May 2007

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