Acta Cryst. (2007). E63, m1641-m1642 [ doi:10.1107/S1600536807020442 ]
Abstract: In the crystal structure of the title compound, LL-[AgCo2(C3H5NO2S)2(C2H8N2)4](ClO4)3·5H2O, the AgI atom, which lies on a twofold rotation axis, is linearly coordinated by two thiolate S atoms from two L-[Co(C3H5NO2S)(C2H8N2)2]+ octahedral units, forming an S-bridged CoIII-AgI-CoIII trinuclear unit. The compound has two uncoordinated carboxylate groups.
Online 10 May 2007
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