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Acta Cryst. (2007). E63, m1742-m1743 [ doi:10.1107/S1600536807024026 ]
![[mu]](/logos/entities/mu_rmgif.gif)
3-Trithiocyanurato-![[kappa]](/logos/entities/kappa_rmgif.gif)
6N1,S2:N3,S4:N5,S6)tris[(N,N,N',N'',N''-pentamethyldiethylenetriamine-3N,N',N'')copper(II)] tris(perchlorate)Abstract: In the title compound, [Cu3(C9H23N3)3(C3N3S3)](ClO4)3, the three CuII centres, related by the body-diagonal threefold rotation symmetry along [111], are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a considerably distorted trigonal-bipyramidal geometry and bonded to three N atoms of a tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of weak hydrogen bonds of the type C-H
O (HA < 2.7 Å) connecting the cation and perchlorate anions.
Online 26 May 2007
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