Acta Cryst. (2007). E63, m1650  [ doi:10.1107/S1600536807022179 ]

(Isoquinoline-2N)bis[-1-(2-oxidobenzylidene)-4-phenylthiosemicarbazonato]-1:2⁴S,N,O:O;1:2⁴O:O,N,S-(quinoline-1N)dizinc(II) hemiquinoline hemiisoquinoline solvate

Z.-P. Deng, S. Gao and S. W. Ng

Abstract: The deprotonated salicylaldimine-4-phenylthiosemicarbazide dianion chelates in an N,O,S-tridentate manner to zinc in the dinuclear title compound, [Zn₂(C₁₄H₁₁N₃OS)₂(C₉H₇N)₂]·0.5C₉H₇N·0.5C₉H₇N, which crystallizes with one molecule each of quinoline and isoquinoline in the asymmetric unit; the O atom also bridges the mononuclear units. One Zn atom is coordinated by a quinoline heterocycle in a trigonal-bipyramidal geometry; the other is coordinated by an isoquinoline heterocycle in a square-pyramidal geometry. The two independent dinuclear molecules in the asymmetric unit display similar bond dimensions.

Online 23 May 2007

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