Acta Cryst. (2007). E63, m1943  [ doi:10.1107/S1600536807029042 ]

Di--iodido-bis[bis(cyclohexyldiphenylphosphine-P)silver(I)]

J. F. Young and G. P. A. Yap

Abstract: The title compound, [Ag₂I₂(C₁₈H₂₁P)₄], has a dimeric structure located on a twofold rotation axis with each tetrahedral Ag^I ion coordinated by two terminal phosphines and bridged by iodide ligands. Although this structural motif has been reported in bromide- and chloride-silver complexes, this is the first reported dimeric iodide-silver complex with monodentate phosphine.

Online 20 June 2007

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