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Acta Cryst. (2007). E63, m1790  [ doi:10.1107/S1600536807021915 ]

Tetraethylammonium dichlorido[N,N'-(4,5-dichloro-o-phenylene)bis(4-tert-butylpyridine-2-carboxamide)-[kappa]4N]ferrate(III) acetonitrile solvate

X.-B. Xu, L. Yang, Y.-Y. Qu, L.-X. Li and X.-G. Zhou

Abstract: In the title compound, (C8H20N)[Fe(C26H26Cl2N4O2)Cl2]·CHCl3, conventionally abbreviated as [NEt4][Fe(bbpc)Cl2]·CHCl3 [H2bbpc = N,N'-(4,5-dichloro-o-phenylene)bis(4-tert-butylpyridine-2-carboxamide)], the FeIII ion is six-coordinate, forming a distorted octahedron with two pyridine and two deprotonated amide N atoms in the equatorial plane, while the two axial sites are occupied by two Cl atoms.

Online 6 June 2007


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