Di-μ-diphenyl­phosphido-bis­{chlorido[(mesitylmeth­yl)diphenyl­phosphine-κP]palladium(II)}

In the title dinuclear palladium complex, [Pd₂(C₁₂H₁₀P)₂Cl₂(C₂₂H₂₃P)₂], the terminal ligands adopt a trans configuration with a Pd...Pd distance of 3.6111 (4) Å. A crystallographic twofold rotation axis runs perpendicular to the Pd₂P₂ ring. The Cl atom lies slightly out of the plane of the Pd and three P atoms in each half of the molecule.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.005 Å
• R factor = 0.031
• wR factor = 0.064
• Data-to-parameter ratio = 17.4

checkCIF/PLATON results

No syntax errors found



Alert level C
GOODF01_ALERT_2_C  The least squares goodness of fit parameter lies
            outside the range 0.80 <> 2.00
            Goodness of fit given =      0.775
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.98 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.26 Ratio
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      66.00 A   3 

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   4 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   3 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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S1. Comment

The title compound, [PdCl(µ₂-PPh₂){PPh₂CH₂(2,4,6-Me₃C₆H₂)}]₂, (I), is prepared in a similar manner as the isoelectronic dinuclear palladium complex [PdCl(µ₂-PPh₂)(PPh₃)]₂ (Brandon & Dixon, 1981). The triphenylphosphine being replaced by (mesithylmethyl)(diphenyl)phosphine (Chahen et al., 2006). The ³¹P{¹H} NMR spectrum gives rise to two multiplets centred at 7.5 and -142.6 p.p.m. respectively. The signals are consistent with an AA'BB' spin system (Brandon & Dixon, 1981). The molecular structure of (I) shows the palladium atoms to be surrounded by two phosphido-bridged ligands, a chloride, and a PPh₂CH₂(2,4,6-Me₃C₆H₂) ligand. The complex adopts the trans-symmetrical isomer, see scheme.

The two halves of the dinuclear complex are related by a crystallography twofold rotation axis, see Fig. 1. The Pd atoms are in a slightly distorted square-planar geometry. The plane formed by the palladium, the chloride and the three P atoms is mainly planar, with a maximum deviation from the mean plane of 0.0770 (4)Å for one bridging P atom. However, the angle between the two square-planar units is 12.63 (1)°, giving rise to a slightly bent conformation for the dimeric unit, see Fig. 2. Otherwise, the bond distances and angles are similar to those found in [PtCl(µ₂-PPh₂)(HPPh₂)]₂ (Carty et al., 1982), [PdCl(µ₂-PPh₂)(HPPh₂)]₂ (Gebauer et al., 1992) and [PdI(µ₂-PPh₂)(HPPh₂)]₂ (Zhuravel et al., 2000).

Related literature

For similar dinuclear palladium complexes, see: Brandon & Dixon (1981); Carty et al. (1982); Gebauer et al. (1992); Zhuravel et al. (2000). For the synthesis of PPh₂CH₂(2,4,6-Me₃C₆H₂), see: Chahen et al. (2006).

S2. Experimental

The synthesis of [PdCl(µ₂-PPh₂){PPh₂CH₂(2,4,6-Me₃C₆H₂)}]₂ is identical to the synthesis of [PdCl(µ₂-PPh₂)(PPh₃)]₂ (Brandon & Dixon, 1981). The yellow product is purified by column chromatography on silica gel (dichloromethane:acetone, 1:2).

¹H NMR (CDCl₃): 6.9–6.2 (m, 44H), 2.76 (m, 4H), 1.58 (s, 12H), 1.34 (m, 6H). ³¹P NMR (CDCl₃): 7.5 and -142.6 p.p.m.. MS (ESI, m/z): 1291; [C₆₈H₆₆Cl₂P₄Pd₂] Calcd. for C₆₈H₆₆Cl₂P₄Pd₂: C, 63.27; H, 5.15 Found: C, 62.87; H, 5.02.

[PdCl(µ₂-PPh₂){PPh₂CH₂(2,4,6-Me₃C₆H₂)}]₂ is disolved in chloroform, and crystals suitable for X-ray diffraction analysis are obtained by slow evaporation of the chloroform solution.

S3. Refinement

The H atoms were included in calculated positions and refined using a riding model, with C—H = 0.93–0.96 Å and with U_iso(H) = 1.2 (1.5 for methyl groups) times U_eq(C).

Computing details

Data collection: EXPOSE in IPDS Software (Stoe & Cie, 2000); cell refinement: CELL in IPDS Software; data reduction: INTEGRATE in IPDS Software; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997) and Mercury (Version 1.4.1; Bruno et al., 2002); software used to prepare material for publication: SHELXL97.

Figures

	Fig. 1. The molecular structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. H atoms have been omitted for clarity.
	Fig. 2. Bent conformation adopted by the title compound.

Di-µ-diphenylphosphido-bis{chlorido[(mesitylmethyl)diphenylphosphine- κP]palladium(II)]}

Crystal data

[Pd2(C12H10P)2Cl2(C22H23P)2]	F(000) = 2640
Mr = 1290.83	Dx = 1.392 Mg m^−3
Orthorhombic, Pccn	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ab 2ac	Cell parameters from 8000 reflections
a = 12.0793 (7) Å	θ = 2.1–25.9°
b = 22.6156 (14) Å	µ = 0.81 mm^−1
c = 22.5499 (14) Å	T = 173 K
V = 6160.2 (6) Å^3	Plate, yellow
Z = 4	0.31 × 0.24 × 0.17 mm

Data collection

Stoe IPDS diffractometer	3498 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.089
Graphite monochromator	θmax = 26.0°, θmin = 2.0°
Detector resolution: 0.81 pixels mm^-1	h = −14→14
φ oscillation scans	k = −27→27
46413 measured reflections	l = −27→27
6011 independent reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.031	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.064	H-atom parameters constrained
S = 0.78	w = 1/[σ^2(Fo^2) + (0.0284P)^2] where P = (Fo^2 + 2Fc^2)/3
6011 reflections	(Δ/σ)max = 0.002
346 parameters	Δρmax = 0.53 e Å^−3
0 restraints	Δρmin = −0.98 e Å^−3

Special details

Experimental. A crystal was mounted at 173 K on a Stoe Image Plate Diffraction System (Stoe, 2000) using Mo Kα graphite monochromated radiation. Image plate distance 70 mm, φ oscillation scans 0 - 200°, step Δφ = 1.0°, 3 minutes per frame.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.3394 (2)	0.68728 (15)	0.14638 (15)	0.0288 (8)
H1A	0.3333	0.7299	0.1498	0.035*
H1B	0.2726	0.6729	0.1273	0.035*
C2	0.3467 (2)	0.66113 (15)	0.20757 (16)	0.0313 (8)
C3	0.2996 (3)	0.60533 (16)	0.21955 (18)	0.0348 (9)
C4	0.3181 (3)	0.57908 (17)	0.27389 (19)	0.0446 (10)
H4	0.2867	0.5423	0.2813	0.054*
C5	0.3810 (3)	0.60503 (18)	0.31752 (19)	0.0467 (10)
C6	0.4210 (3)	0.66176 (18)	0.30728 (18)	0.0442 (10)
H6	0.4601	0.6810	0.3371	0.053*
C7	0.4040 (3)	0.69051 (15)	0.25328 (16)	0.0332 (8)
C8	0.2300 (3)	0.57336 (17)	0.17367 (18)	0.0455 (10)
H8A	0.2078	0.5356	0.1890	0.068*
H8B	0.2726	0.5678	0.1382	0.068*
H8C	0.1654	0.5965	0.1648	0.068*
C9	0.4049 (4)	0.5717 (2)	0.3747 (2)	0.0758 (14)
H9A	0.3390	0.5517	0.3876	0.114*
H9B	0.4282	0.5991	0.4047	0.114*
H9C	0.4625	0.5433	0.3679	0.114*
C10	0.4471 (3)	0.75305 (17)	0.24475 (16)	0.0434 (9)
H10A	0.3857	0.7799	0.2420	0.065*
H10B	0.4899	0.7550	0.2090	0.065*
H10C	0.4927	0.7638	0.2779	0.065*
C11	0.4922 (2)	0.59215 (13)	0.11434 (15)	0.0257 (8)
C12	0.4717 (3)	0.54607 (15)	0.07458 (17)	0.0335 (9)
H12	0.4377	0.5538	0.0384	0.040*
C13	0.5023 (3)	0.48856 (15)	0.08905 (17)	0.0379 (10)
H13	0.4872	0.4579	0.0628	0.045*
C14	0.5544 (3)	0.47669 (17)	0.14176 (19)	0.0409 (10)
H14	0.5772	0.4384	0.1504	0.049*
C15	0.5733 (3)	0.52168 (16)	0.18205 (18)	0.0364 (9)
H15	0.6068	0.5135	0.2183	0.044*
C16	0.5420 (2)	0.57898 (15)	0.16824 (17)	0.0304 (8)
H16	0.5545	0.6091	0.1955	0.036*
C17	0.4122 (2)	0.67027 (14)	0.02220 (15)	0.0279 (8)
C18	0.4917 (3)	0.67252 (16)	−0.02190 (16)	0.0372 (9)
H18	0.5662	0.6716	−0.0117	0.045*
C19	0.4618 (3)	0.67611 (17)	−0.08118 (17)	0.0443 (10)
H19	0.5163	0.6770	−0.1103	0.053*
C20	0.3531 (3)	0.67830 (17)	−0.09702 (19)	0.0508 (11)
H20	0.3329	0.6810	−0.1367	0.061*
C21	0.2743 (3)	0.6765 (2)	−0.0539 (2)	0.0614 (13)
H21	0.2000	0.6780	−0.0646	0.074*
C22	0.3022 (3)	0.67225 (18)	0.00542 (18)	0.0475 (11)
H22	0.2469	0.6708	0.0341	0.057*
C23	0.7748 (2)	0.63475 (14)	0.04978 (15)	0.0256 (8)
C24	0.7492 (3)	0.57485 (15)	0.05565 (16)	0.0324 (8)
H24	0.7251	0.5605	0.0921	0.039*
C25	0.7593 (3)	0.53672 (18)	0.00822 (18)	0.0466 (10)
H25	0.7424	0.4969	0.0130	0.056*
C26	0.7940 (3)	0.5572 (2)	−0.0457 (2)	0.0540 (12)
H26	0.8001	0.5314	−0.0777	0.065*
C27	0.8196 (3)	0.6159 (2)	−0.05260 (18)	0.0527 (11)
H27	0.8432	0.6297	−0.0894	0.063*
C28	0.8109 (3)	0.65508 (17)	−0.00562 (16)	0.0378 (9)
H28	0.8289	0.6947	−0.0108	0.045*
C29	0.7848 (2)	0.65141 (14)	0.17945 (16)	0.0262 (8)
C30	0.8636 (3)	0.60701 (15)	0.18551 (18)	0.0357 (9)
H30	0.9022	0.5934	0.1526	0.043*
C31	0.8840 (3)	0.58332 (18)	0.2410 (2)	0.0500 (11)
H31	0.9355	0.5530	0.2450	0.060*
C32	0.8293 (3)	0.6039 (2)	0.2902 (2)	0.0550 (12)
H32	0.8440	0.5875	0.3272	0.066*
C33	0.7531 (4)	0.64862 (19)	0.28494 (17)	0.0513 (11)
H33	0.7170	0.6631	0.3183	0.062*
C34	0.7303 (3)	0.67193 (16)	0.22955 (16)	0.0375 (9)
H34	0.6778	0.7018	0.2258	0.045*
Cl1	0.46039 (6)	0.81271 (4)	0.08771 (4)	0.0368 (2)
P3	0.76040 (6)	0.68822 (3)	0.10901 (4)	0.02197 (18)
P5	0.46032 (6)	0.66918 (4)	0.09866 (4)	0.02419 (19)
Pd1	0.601393 (16)	0.741408 (10)	0.103340 (11)	0.02204 (7)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.0208 (15)	0.033 (2)	0.033 (2)	0.0008 (14)	0.0053 (14)	−0.0005 (17)
C2	0.0270 (17)	0.035 (2)	0.032 (2)	0.0045 (15)	0.0070 (15)	0.0018 (18)
C3	0.0304 (17)	0.038 (2)	0.037 (2)	0.0009 (16)	0.0071 (16)	−0.0002 (19)
C4	0.039 (2)	0.042 (2)	0.052 (3)	−0.0029 (18)	0.012 (2)	0.010 (2)
C5	0.048 (2)	0.055 (3)	0.037 (3)	0.002 (2)	0.006 (2)	0.007 (2)
C6	0.045 (2)	0.055 (3)	0.033 (3)	0.0003 (19)	0.0029 (18)	−0.004 (2)
C7	0.0287 (16)	0.036 (2)	0.034 (2)	0.0011 (17)	0.0073 (17)	−0.0054 (17)
C8	0.042 (2)	0.046 (3)	0.048 (3)	−0.0153 (18)	0.0046 (18)	0.005 (2)
C9	0.095 (4)	0.081 (4)	0.052 (3)	−0.002 (3)	−0.010 (3)	0.024 (3)
C10	0.0496 (19)	0.045 (2)	0.036 (2)	−0.0038 (19)	0.0057 (16)	−0.010 (2)
C11	0.0238 (15)	0.0244 (17)	0.029 (2)	0.0010 (13)	0.0014 (14)	0.0013 (16)
C12	0.0353 (18)	0.033 (2)	0.033 (2)	−0.0068 (15)	−0.0013 (16)	0.0033 (17)
C13	0.048 (2)	0.0225 (19)	0.043 (3)	−0.0054 (16)	0.0112 (18)	−0.0054 (18)
C14	0.046 (2)	0.029 (2)	0.048 (3)	0.0036 (16)	0.0113 (19)	0.007 (2)
C15	0.0339 (19)	0.038 (2)	0.038 (3)	0.0032 (15)	0.0048 (16)	0.0130 (19)
C16	0.0228 (16)	0.032 (2)	0.037 (2)	0.0005 (14)	0.0033 (15)	0.0003 (18)
C17	0.0299 (17)	0.0249 (18)	0.029 (2)	−0.0019 (15)	−0.0042 (15)	−0.0012 (15)
C18	0.0399 (19)	0.040 (2)	0.031 (2)	−0.0046 (17)	0.0001 (17)	0.0013 (19)
C19	0.062 (3)	0.042 (2)	0.029 (2)	−0.0030 (19)	0.0041 (19)	−0.0003 (19)
C20	0.070 (3)	0.053 (2)	0.029 (3)	0.0086 (19)	−0.016 (2)	0.000 (2)
C21	0.046 (3)	0.090 (4)	0.048 (3)	0.011 (2)	−0.024 (2)	−0.006 (3)
C22	0.0335 (19)	0.070 (3)	0.039 (3)	0.0002 (19)	−0.0039 (18)	−0.001 (2)
C23	0.0205 (17)	0.030 (2)	0.026 (2)	0.0043 (13)	−0.0024 (13)	−0.0059 (16)
C24	0.0297 (15)	0.032 (2)	0.036 (2)	−0.0042 (15)	0.0036 (19)	−0.0080 (18)
C25	0.046 (2)	0.042 (2)	0.052 (3)	−0.0046 (18)	0.001 (2)	−0.019 (2)
C26	0.059 (2)	0.061 (3)	0.042 (3)	0.002 (2)	−0.002 (2)	−0.028 (2)
C27	0.063 (3)	0.076 (3)	0.019 (2)	0.007 (2)	0.002 (2)	−0.005 (2)
C28	0.047 (2)	0.041 (2)	0.026 (2)	0.0048 (17)	−0.0022 (18)	−0.0015 (19)
C29	0.0283 (17)	0.0248 (19)	0.026 (2)	−0.0061 (14)	−0.0016 (14)	0.0050 (16)
C30	0.0361 (19)	0.036 (2)	0.035 (2)	0.0031 (15)	−0.0041 (16)	0.0025 (18)
C31	0.055 (2)	0.043 (2)	0.052 (3)	0.010 (2)	−0.018 (2)	0.014 (2)
C32	0.064 (3)	0.068 (3)	0.032 (3)	−0.006 (2)	−0.013 (2)	0.019 (2)
C33	0.059 (2)	0.070 (3)	0.025 (2)	−0.003 (2)	0.005 (2)	0.007 (2)
C34	0.041 (2)	0.039 (2)	0.032 (2)	0.0016 (16)	−0.0012 (16)	0.0034 (19)
Cl1	0.0234 (4)	0.0269 (5)	0.0601 (7)	0.0045 (3)	−0.0014 (4)	0.0051 (4)
P3	0.0207 (4)	0.0218 (4)	0.0234 (5)	0.0006 (3)	0.0003 (4)	0.0009 (4)
P5	0.0200 (4)	0.0234 (4)	0.0291 (5)	−0.0016 (3)	0.0004 (4)	0.0007 (4)
Pd1	0.01932 (10)	0.02174 (12)	0.02506 (13)	0.00082 (11)	−0.00015 (11)	0.00017 (13)

Geometric parameters (Å, º)

C1—C2	1.504 (5)	C18—C19	1.387 (5)
C1—P5	1.860 (3)	C18—H18	0.9300
C1—H1A	0.9700	C19—C20	1.362 (5)
C1—H1B	0.9700	C19—H19	0.9300
C2—C7	1.408 (5)	C20—C21	1.361 (6)
C2—C3	1.410 (5)	C20—H20	0.9300
C3—C4	1.380 (5)	C21—C22	1.382 (6)
C3—C8	1.517 (5)	C21—H21	0.9300
C4—C5	1.375 (5)	C22—H22	0.9300
C4—H4	0.9300	C23—C24	1.396 (4)
C5—C6	1.390 (5)	C23—C28	1.401 (5)
C5—C9	1.521 (6)	C23—P3	1.810 (3)
C6—C7	1.396 (5)	C24—C25	1.379 (5)
C6—H6	0.9300	C24—H24	0.9300
C7—C10	1.519 (5)	C25—C26	1.368 (6)
C8—H8A	0.9600	C25—H25	0.9300
C8—H8B	0.9600	C26—C27	1.373 (6)
C8—H8C	0.9600	C26—H26	0.9300
C9—H9A	0.9600	C27—C28	1.385 (5)
C9—H9B	0.9600	C27—H27	0.9300
C9—H9C	0.9600	C28—H28	0.9300
C10—H10A	0.9600	C29—C34	1.388 (5)
C10—H10B	0.9600	C29—C30	1.390 (4)
C10—H10C	0.9600	C29—P3	1.817 (3)
C11—C16	1.388 (5)	C30—C31	1.383 (5)
C11—C12	1.397 (5)	C30—H30	0.9300
C11—P5	1.819 (3)	C31—C32	1.372 (6)
C12—C13	1.391 (5)	C31—H31	0.9300
C12—H12	0.9300	C32—C33	1.373 (6)
C13—C14	1.372 (5)	C32—H32	0.9300
C13—H13	0.9300	C33—C34	1.383 (5)
C14—C15	1.383 (5)	C33—H33	0.9300
C14—H14	0.9300	C34—H34	0.9300
C15—C16	1.385 (5)	Cl1—Pd1	2.3718 (8)
C15—H15	0.9300	P3—Pd1	2.2699 (8)
C16—H16	0.9300	P3—Pd1^i	2.3101 (8)
C17—C18	1.383 (5)	P5—Pd1	2.3629 (8)
C17—C22	1.383 (4)	Pd1—P3^i	2.3101 (8)
C17—P5	1.819 (3)
C2—C1—P5	113.5 (2)	C20—C19—C18	120.4 (4)
C2—C1—H1A	108.9	C20—C19—H19	119.8
P5—C1—H1A	108.9	C18—C19—H19	119.8
C2—C1—H1B	108.9	C21—C20—C19	119.0 (4)
P5—C1—H1B	108.9	C21—C20—H20	120.5
H1A—C1—H1B	107.7	C19—C20—H20	120.5
C7—C2—C3	118.7 (3)	C20—C21—C22	121.5 (4)
C7—C2—C1	121.0 (3)	C20—C21—H21	119.2
C3—C2—C1	120.3 (3)	C22—C21—H21	119.2
C4—C3—C2	119.3 (4)	C21—C22—C17	120.1 (4)
C4—C3—C8	119.4 (3)	C21—C22—H22	120.0
C2—C3—C8	121.3 (3)	C17—C22—H22	120.0
C5—C4—C3	122.8 (4)	C24—C23—C28	118.2 (3)
C5—C4—H4	118.6	C24—C23—P3	123.9 (3)
C3—C4—H4	118.6	C28—C23—P3	117.9 (3)
C4—C5—C6	117.9 (4)	C25—C24—C23	120.9 (4)
C4—C5—C9	120.0 (4)	C25—C24—H24	119.5
C6—C5—C9	122.1 (4)	C23—C24—H24	119.5
C5—C6—C7	121.6 (4)	C26—C25—C24	120.3 (4)
C5—C6—H6	119.2	C26—C25—H25	119.8
C7—C6—H6	119.2	C24—C25—H25	119.8
C6—C7—C2	119.4 (3)	C25—C26—C27	119.8 (4)
C6—C7—C10	119.6 (3)	C25—C26—H26	120.1
C2—C7—C10	121.0 (3)	C27—C26—H26	120.1
C3—C8—H8A	109.5	C26—C27—C28	121.0 (4)
C3—C8—H8B	109.5	C26—C27—H27	119.5
H8A—C8—H8B	109.5	C28—C27—H27	119.5
C3—C8—H8C	109.5	C27—C28—C23	119.8 (4)
H8A—C8—H8C	109.5	C27—C28—H28	120.1
H8B—C8—H8C	109.5	C23—C28—H28	120.1
C5—C9—H9A	109.5	C34—C29—C30	119.1 (3)
C5—C9—H9B	109.5	C34—C29—P3	118.8 (3)
H9A—C9—H9B	109.5	C30—C29—P3	121.9 (3)
C5—C9—H9C	109.5	C31—C30—C29	119.4 (4)
H9A—C9—H9C	109.5	C31—C30—H30	120.3
H9B—C9—H9C	109.5	C29—C30—H30	120.3
C7—C10—H10A	109.5	C32—C31—C30	120.9 (4)
C7—C10—H10B	109.5	C32—C31—H31	119.5
H10A—C10—H10B	109.5	C30—C31—H31	119.5
C7—C10—H10C	109.5	C31—C32—C33	120.2 (4)
H10A—C10—H10C	109.5	C31—C32—H32	119.9
H10B—C10—H10C	109.5	C33—C32—H32	119.9
C16—C11—C12	118.6 (3)	C32—C33—C34	119.4 (4)
C16—C11—P5	117.9 (3)	C32—C33—H33	120.3
C12—C11—P5	123.5 (3)	C34—C33—H33	120.3
C13—C12—C11	120.0 (3)	C33—C34—C29	120.9 (4)
C13—C12—H12	120.0	C33—C34—H34	119.5
C11—C12—H12	120.0	C29—C34—H34	119.5
C14—C13—C12	120.5 (3)	C23—P3—C29	108.87 (16)
C14—C13—H13	119.7	C23—P3—Pd1	113.18 (10)
C12—C13—H13	119.7	C29—P3—Pd1	115.42 (11)
C13—C14—C15	120.1 (4)	C23—P3—Pd1^i	110.50 (10)
C13—C14—H14	120.0	C29—P3—Pd1^i	104.28 (10)
C15—C14—H14	120.0	Pd1—P3—Pd1^i	104.08 (3)
C14—C15—C16	119.7 (4)	C11—P5—C17	105.36 (15)
C14—C15—H15	120.2	C11—P5—C1	105.35 (15)
C16—C15—H15	120.2	C17—P5—C1	107.13 (15)
C15—C16—C11	121.1 (3)	C11—P5—Pd1	120.04 (10)
C15—C16—H16	119.5	C17—P5—Pd1	105.25 (10)
C11—C16—H16	119.5	C1—P5—Pd1	112.86 (11)
C18—C17—C22	118.0 (3)	P3—Pd1—P3^i	75.55 (3)
C18—C17—P5	117.4 (2)	P3—Pd1—P5	104.26 (3)
C22—C17—P5	124.5 (3)	P3^i—Pd1—P5	179.37 (4)
C17—C18—C19	121.0 (3)	P3—Pd1—Cl1	167.50 (3)
C17—C18—H18	119.5	P3^i—Pd1—Cl1	93.37 (3)
C19—C18—H18	119.5	P5—Pd1—Cl1	86.87 (3)
P5—C1—C2—C7	85.3 (3)	C31—C32—C33—C34	1.2 (6)
P5—C1—C2—C3	−92.2 (3)	C32—C33—C34—C29	−1.1 (6)
C7—C2—C3—C4	−4.9 (5)	C30—C29—C34—C33	−0.3 (5)
C1—C2—C3—C4	172.6 (3)	P3—C29—C34—C33	−174.6 (3)
C7—C2—C3—C8	175.6 (3)	C24—C23—P3—C29	31.2 (3)
C1—C2—C3—C8	−6.9 (5)	C28—C23—P3—C29	−150.5 (2)
C2—C3—C4—C5	0.0 (5)	C24—C23—P3—Pd1	−98.5 (3)
C8—C3—C4—C5	179.5 (3)	C28—C23—P3—Pd1	79.7 (2)
C3—C4—C5—C6	4.3 (6)	C24—C23—P3—Pd1^i	145.2 (2)
C3—C4—C5—C9	−175.6 (4)	C28—C23—P3—Pd1^i	−36.6 (3)
C4—C5—C6—C7	−3.7 (6)	C34—C29—P3—C23	−149.4 (3)
C9—C5—C6—C7	176.2 (4)	C30—C29—P3—C23	36.5 (3)
C5—C6—C7—C2	−1.1 (5)	C34—C29—P3—Pd1	−20.9 (3)
C5—C6—C7—C10	178.6 (3)	C30—C29—P3—Pd1	165.0 (2)
C3—C2—C7—C6	5.5 (5)	C34—C29—P3—Pd1^i	92.6 (3)
C1—C2—C7—C6	−172.1 (3)	C30—C29—P3—Pd1^i	−81.5 (3)
C3—C2—C7—C10	−174.2 (3)	C16—C11—P5—C17	173.5 (2)
C1—C2—C7—C10	8.3 (5)	C12—C11—P5—C17	−5.0 (3)
C16—C11—C12—C13	−0.8 (5)	C16—C11—P5—C1	−73.4 (3)
P5—C11—C12—C13	177.6 (2)	C12—C11—P5—C1	108.1 (3)
C11—C12—C13—C14	−1.2 (5)	C16—C11—P5—Pd1	55.2 (3)
C12—C13—C14—C15	2.5 (5)	C12—C11—P5—Pd1	−123.2 (2)
C13—C14—C15—C16	−1.8 (5)	C18—C17—P5—C11	−83.7 (3)
C14—C15—C16—C11	−0.3 (5)	C22—C17—P5—C11	100.0 (3)
C12—C11—C16—C15	1.5 (4)	C18—C17—P5—C1	164.5 (3)
P5—C11—C16—C15	−177.0 (2)	C22—C17—P5—C1	−11.8 (3)
C22—C17—C18—C19	−0.6 (5)	C18—C17—P5—Pd1	44.1 (3)
P5—C17—C18—C19	−177.1 (3)	C22—C17—P5—Pd1	−132.2 (3)
C17—C18—C19—C20	0.9 (6)	C2—C1—P5—C11	40.5 (3)
C18—C19—C20—C21	−0.5 (6)	C2—C1—P5—C17	152.3 (2)
C19—C20—C21—C22	−0.2 (7)	C2—C1—P5—Pd1	−92.3 (2)
C20—C21—C22—C17	0.5 (7)	C23—P3—Pd1—P3^i	−126.54 (12)
C18—C17—C22—C21	−0.1 (6)	C29—P3—Pd1—P3^i	107.09 (11)
P5—C17—C22—C21	176.2 (3)	Pd1^i—P3—Pd1—P3^i	−6.53 (5)
C28—C23—C24—C25	0.0 (5)	C23—P3—Pd1—P5	54.08 (13)
P3—C23—C24—C25	178.3 (3)	C29—P3—Pd1—P5	−72.29 (12)
C23—C24—C25—C26	−0.4 (6)	Pd1^i—P3—Pd1—P5	174.09 (3)
C24—C25—C26—C27	0.5 (6)	C23—P3—Pd1—Cl1	−98.4 (2)
C25—C26—C27—C28	−0.1 (6)	C29—P3—Pd1—Cl1	135.22 (18)
C26—C27—C28—C23	−0.3 (6)	Pd1^i—P3—Pd1—Cl1	21.60 (18)
C24—C23—C28—C27	0.4 (5)	C11—P5—Pd1—P3	11.84 (14)
P3—C23—C28—C27	−178.0 (3)	C17—P5—Pd1—P3	−106.51 (11)
C34—C29—C30—C31	1.5 (5)	C1—P5—Pd1—P3	136.98 (12)
P3—C29—C30—C31	175.6 (3)	C11—P5—Pd1—Cl1	−173.91 (14)
C29—C30—C31—C32	−1.4 (6)	C17—P5—Pd1—Cl1	67.74 (11)
C30—C31—C32—C33	0.0 (6)	C1—P5—Pd1—Cl1	−48.76 (12)

Symmetry code: (i) −x+3/2, −y+3/2, z.