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Acta Cryst. (2007). E63, m1839-m1840  [ doi:10.1107/S1600536807027067 ]

catena-Poly[[bis(benzene-1,3-dicarboxylato-[kappa]2O,O')zinc(II)]-[mu]-4,4'-bipyridine-[kappa]2N:N']

X.-M. Li, Y.-H. Dong, Q.-W. Wang and B. Liu

Abstract: In the title compound, [Zn(C8H5O4)2(C10H8N2)]n, the ZnII atom lies on a twofold rotation axis, and is coordinated by two N atoms of two 4,4'-bipyridine ligands and two carboxylate groups, each in a chelating mode, from two isophthalate ligands. The 4,4'-bipyridine ligand, located on an inversion center, bridges the ZnII atoms, forming a one-dimensional zigzag chain structure. O-H...O hydrogen bonds and [pi]-[pi] stacking interactions [with a shortest atom-to-atom distance of 3.41 (1) Å] are observed between the chains.

Online 8 June 2007


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