Acta Cryst. (2007). E63, m1877  [ doi:10.1107/S1600536807026384 ]

Di--sulfido-bis[(2-aminoethanethiolato-²N,S)oxidomolybdate(V)]

Y.-M. Li, J.-L. Zhang and X.-W. Zhao

Abstract: The title compound, [Mo₂O₂S₂(C₂H₆NS)₂], was obtained by the reaction of sodium molybdate, H₂S, sodium hydrosulfite and 2-aminoethanethiol. In the crystal structure, each Mo^V atom, in a square-pyramidal geometry, is coordinated by two -S atoms, one terminal O atom, one S atom and one N atom of the 2-aminoethanethiolate ligand. A three-dimensional hydrogen-bonding network is constructed by intermolecular N-HO and N-HS hydrogen bonds.

Online 13 June 2007

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