Acta Cryst. (2007). E63, m1947  [ doi:10.1107/S1600536807027791 ]

Chlorido(1-pyrrolidinecarbodithioato-²S,S')(triphenylphosphine-P)nickel(II) chloroform hemisolvate

A. Kropidlowska, J. Janczak, J. Golaszewska and B. Becker

Abstract: In the crystal structure of the title complex, [Ni{S₂CN(CH₂)₄}Cl(C₁₈H₁₅P)]·0.5CHCl₃, the Ni atom is coordinated by a bidentate dithiocarbamate, one chloride and triphenylphosphine in a square-planar arrangement. The chloroform solvent molecule interacts with the complex through a weak C-HS hydrogen bond. The solvent molecule is disordered equally over two inversion-related sites.

Online 20 June 2007

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