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Acta Cryst. (2007). E63, m1931  [ doi:10.1107/S1600536807028875 ]

Bis[[mu]-diphenyl(2-pyridylmethyl)phosphine-[kappa]2N,P]bis[nitratosilver(I)](Ag-Ag)

K. K. Klausmeyer and F. Hung-Low

Abstract: In the title molecular structure, [Ag2(NO3)2(C18H16NP)2], the AgI atoms are held in close proximity by the chelating effect of the diphenyl(2-pyridylmethyl)phosphine ligand, with an Ag-Ag bond distance of 2.9171 (7) Å. The angles around the metal centers describe a distorted tetrahedral geometry, with the NO3- ions bound to the AgI atoms in a monodentate fashion. The molecule is centrosymmetric.

Online 20 June 2007


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