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Acta Cryst. (2007). E63, m1792  [ doi:10.1107/S1600536807025615 ]

[Bis(1H-benzimidazol-2-ylmethyl)amine-[kappa]3N,N',N'']dinitratolead(II)

Y. Zhang, X.-Y. Xia, X.-Q. Liu, X.-M. Chen and T. Liu

Abstract: In the title compound, [Pb(NO3)2(C16H15N5)], the PbII ion is chelated by three N atoms of a bis(1H-benzimidazol-2-ylmethyl)amine (IDB) ligand and two O atoms from each of two nitrate ligands, resulting in an asymmetric seven-coordinate configuration. The crystal structure is stabilized by intermolecular N-H...O and C-H...O hydrogen bonds and [pi]-[pi] interactions, with ring-centroid separations of 3.578 (5) and 3.686 (5) Å, leading to a three-dimensional network.

Online 6 June 2007


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