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Acta Cryst. (2007). E63, m1970  [ doi:10.1107/S1600536807029832 ]

catena-Poly[[diaquabis[(4-chlorophenylsulfinyl)acetato-[kappa]O]nickel(II)]-[mu]-4,4'-bipyridine-[kappa]2N:N']

Y. Su, Y.-J. Hou, Z.-Z. Sun, B.-Y. Li and G.-F. Hou

Abstract: In the title coordination polymer, [Ni(C8H6ClO3S)2(C10H8N2)(H2O)2]n, the NiII ion exists in an octahedral coordination environment formed by two carboxylate O atoms from two 4-chlorophenylsulfinylacetate ligands, two N atoms from two bipyridine ligands and two water molecules. The NiII ion lies on a twofold rotation axis. Bridging by the bipyridine ligand leads to a linear chain structure; intermolecular O-H...O hydrogen bonds link the chains into a three-dimensional network.

Online 22 June 2007


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