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Acta Cryst. (2007). E63, m1847  [ doi:10.1107/S1600536807027183 ]

Bis{2-[(dimethylamino-[kappa]N)methyl]benzenethiolato-[kappa]S}zinc(II)

L. S. von Chrzanowski, M. Lutz, A. L. Spek, H. Kleijn and G. van Koten

Abstract: In the title compound, [Zn(C9H12NS)2], the ZnII center is located on a twofold rotation axis and is coordinated in a distorted tetrahedral environment in a bidentate fashion by anionic thiolate S and neutral amino N atoms of two 2-[(dimethylamino)methyl]benzenethiolate ligands. All the molecules are in the [Delta] form. The chosen crystal can thus be considered enantiomerically pure. Intermolecular C-H...[pi] contacts connect the molecules into a two-dimensional network.

Online 13 June 2007


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