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Acta Cryst. (2007). E63, m1993-m1994 [ doi:10.1107/S1600536807030450 ]
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2N,N')copper(I) chloridobis(1,10-phenanthroline-2N,N')copper(II) hexacosaoxidooctamolybdate(VI) dihydrateAbstract: The title complex, [CuIICl(C12H8N2)2]2[CuI(C12H8N2)2]2[Mo8O26]·2H2O, features a centrosymmetric ![[alpha]](/logos/entities/alpha_rmgif.gif)
-type octamolybdate anion, two complex copper counter-cations with Cu in oxidation states +II and +I, and two water molecules of crystallization. The CuII ion exhibits a distorted CuN4Cl square-pyramidal coordination, whereas the CuI ion is in a distorted tetrahedral CuN4 coordination. The anions, cations and uncoordinated water molecules are linked into a three-dimensional network by O-H
O and C-HO hydrogen bonds.
Online 27 June 2007
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