Acta Cryst. (2007). E63, m1872  [ doi:10.1107/S1600536807027079 ]

Bis[2-(cycloheptyliminomethyl)pyridine-²N,N']silver(I) tetraphenylborate

W. Massa, S. Dehghanpour, G. Tashakori and K. Aoki

Abstract: In the title complex, [Ag(C₂₆H₃₆N₄)₂](C₂₄H₂₀B), the Ag^I atom has a distorted tetrahedral coordination. The organic ligand is bidentate, coordinating the Ag^I atom via two imine N atoms. One of the cycloheptyl groups and the Ag atom are disordered over two sites, with occupancy factors of ca 0.87 and 0.13. In this arrangement, the closest methylene group is more remote and the Ag atom also moves out by 0.405 (5) Å toward an alternative position.

Online 13 June 2007

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