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Acta Cryst. (2007). E63, m2176  [ doi:10.1107/S1600536807034472 ]

Hexakis(1H-imidazole-[kappa]N3)nickel(II) sulfate dihydrate

X.-C. Sun, G.-P. Zhou, Z.-B. Liu and Y. Xu

Abstract: The title compound, [Ni(C3H4N2)6]SO4·2H2O, was prepared by hydrothermal synthesis. The NiII atom lies on a site of \\overline{3} point symmetry and is coordinated by six imidazole ligands in a regular octahedral geometry. The sulfate anion is disordered about a site of 32 point symmetry; water molecules lie on sites of 32 point symmetry and on general positions. The coordinated imidazole molecules make N-H...O hydrogen bonds with the sulfate anions.

Online 18 July 2007


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