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Acta Cryst. (2007). E63, m2131-m2132  [ doi:10.1107/S1600536807033430 ]

Poly[[silver(I)-bis[[mu]2-3-(aminomethyl)pyridine]-[kappa]2N1:N3;[kappa]2N3:N1] hexafluoridophosphate]

C. E. Carson, R. P. Feazell and K. K. Klausmeyer

Abstract: In the title compound, {[Ag(C6H8N2)2]PF6}n, a two-dimensional coordination polymer is formed by linking each Ag atom of the [Ag(3-AMP)]2 rings [3-AMP is 3-(aminomethyl)pyridine] with an additional equivalent of 3-AMP. This polymer exhibits hydrogen bonding to the anion, which sits in channels forming a three-dimensional network. Each Ag atom is ligated by two pyridine and two amine groups.

Online 13 July 2007


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