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Acta Cryst. (2007). E63, m2074  [ doi:10.1107/S1600536807032047 ]

Di-[mu]-chlorido-bis(chlorido{2-[4-(dimethylamino)benzylideneamino]pyridine-[kappa]N}mercury(II))

Q. Wang and D. Wang

Abstract: The title complex, [Hg2Cl4(C14H15N3)2], has a centre of symmetry at the centre of the four-membered ring formed by the two Hg and two bridging Cl atoms. Each HgII atom is four-coordinated in a distorted tetrahedral coordination geometry by one N atom from the pyridyl ring of a Schiff base ligand, two bridging Cl atoms and one terminal Cl atom. The Hg...Hg distance is 3.774 (2) Å. In the crystal structure, the molecules are linked into a two-dimensional network by intermolecular C-H...Cl hydrogen bonds.

Online 5 July 2007


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