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Acta Cryst. (2007). E63, m2097 [ doi:10.1107/S1600536807032254 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-Carbonyl-1:2![[kappa]](/logos/entities/kappa_rmgif.gif)
2C-carbonyl-1C-(1![[eta]](/logos/entities/eta_rmgif.gif)
5-cyclopentadienyl)(-phenylvinylidene)bis(triphenylphosphine-2P)manganeseplatinum(Mn-Pt)Abstract: The title compound, [MnPt(C5H5)(C8H6)(C18H15P)2(CO)2], is a dinuclear heterometallic Mn-Pt(-C=CHPh) complex obtained as a product of the addition of [Pt(PPh3)]2 to (5-C5H5)(CO)2Mn=C=CHPh. The two metal atoms are bridged by the -phenylvinylidene ligand and semibridged by a carbonyl group. The central fragment of the molecule is an almost planar methylenedimetallacyclopropane Mn-Pt(-C=CHPh) system. The coordination of the Mn atom is formed by two parallel planes: the first plane consists of three carbonyl C atoms and the second is the cyclopentadienyl plane. A distorted square-planar coordination of the Pt atom is formed by two P atoms of PPh3 and C atoms of the semi-bridging and C=CHPh ligands.
Online 11 July 2007
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