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Acta Cryst. (2007). E63, m2097    [ doi:10.1107/S1600536807032254 ]

[mu]-Carbonyl-1:2[kappa]2C-carbonyl-1[kappa]C-(1[eta]5-cyclopentadienyl)([mu]-phenylvinylidene)bis(triphenylphosphine-2[kappa]P)manganeseplatinum(Mn-Pt)

A. D. Vasiliev, A. B. Antonova and O. S. Chudin

Abstract top

The title compound, [MnPt(C5H5)(C8H6)(C18H15P)2(CO)2], is a dinuclear heterometallic Mn-Pt([mu]-C=CHPh) complex obtained as a product of the addition of [Pt(PPh3)]2 to ([eta]5-C5H5)(CO)2Mn=C=CHPh. The two metal atoms are bridged by the [mu]-phenylvinylidene ligand and semibridged by a carbonyl group. The central fragment of the molecule is an almost planar methylenedimetallacyclopropane Mn-Pt([mu]-C=CHPh) system. The coordination of the Mn atom is formed by two parallel planes: the first plane consists of three carbonyl C atoms and the second is the cyclopentadienyl plane. A distorted square-planar coordination of the Pt atom is formed by two P atoms of PPh3 and C atoms of the semi-bridging and C=CHPh ligands.

Comment top

The molecule of the title compound, (I), is the dinuclear complex containing the Mn and Pt atoms bridged by the µ-phenylvinylidene ligand and semi-bridged by carbonyl group. The phenyl ring and the C?C bond of vinylidene coupling with the Mn—Pt-µ-C triangle form an almost planar system. Corresponding geometry was found for the related MnPt complex with chelating bis(diphenylphosphino)methane at the Pt atom (Dolgushin et al., 2001). The structures of some µ-carbene complexes containing the Mn—Pt-µ-C triangle system as a molecular central fragment were reported (Jeffery et al., 1981).

Related literature top

Corresponding geometry in the related MnPt complex with the chelating bis(diphenylphosphino)methane ligand was reported by Dolgushin et al. (2001). For crystal structures of related µ-carbene complexes containing the Mn—Pt-µ-C triangle system, see: Jeffery et al. (1981). For details of the synthesis, see: Antonova et al. (1985).

Experimental top

The title compound was prepared by the interaction between Cp(CO)2Mn?C? CHPh and Pt(PPh3)4 (diethyl ether, 298 K, 1 h) (Antonova et al., 1985). Suitable single crystals were obtained by isothermal evaporation of an ether solution at 298 K.

Refinement top

Seven phenyl rings of the title molecule were idealized and refined as rigid groups with C—C bond lengths of 1.390 Å. All H atoms were positioned geometrically (C—H 0.93 Å) and refined using a riding model with Uiso(H) = 1.2 Ueq(C).

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1998); program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Figures top
[Figure 1] Fig. 1. The molecular structure of the title compound with atomic labels and 50% probability displacement ellipsoids. All H-atoms, except H2, omitted for clarity.
µ-Carbonyl-1:2κ2C-carbonyl-1κC-(1η5-cyclopentadienyl)(µ- phenylvinylidene)bis(triphenylphosphine-2κP)manganeseplatinum(Mn—Pt) top
Crystal data top
[MnPt(C5H5)(C8H6)(C18H15P)2(CO)2]F(000) = 1984
Mr = 997.81Dx = 1.569 Mg m−3
Orthorhombic, P212121Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2abCell parameters from 9978 reflections
a = 11.1320 (4) Åθ = 2.4–27.5°
b = 19.4463 (7) ŵ = 3.72 mm−1
c = 19.5174 (7) ÅT = 283 K
V = 4225.1 (3) Å3Block, red
Z = 40.29 × 0.17 × 0.14 mm
Data collection top
Bruker SMART 4K CCD area-detector
diffractometer		9675 independent reflections
Radiation source: sealed tube8974 reflections with I > 2σ(I)
graphiteRint = 0.026
φ and ω scansθmax = 27.5°, θmin = 2.1°
Absorption correction: multi-scan
(SADABS; Sheldrick, 2004)		h = −14→14
Tmin = 0.352, Tmax = 0.624k = −25→25
37385 measured reflectionsl = −25→25
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: constr
R[F2 > 2σ(F2)] = 0.020H-atom parameters constrained
wR(F2) = 0.045 w = 1/[σ2(Fo2) + (0.0241P)2 + 2.8014P]
where P = (Fo2 + 2Fc2)/3
S = 0.95(Δ/σ)max = 0.011
9675 reflectionsΔρmax = 0.63 e Å−3
433 parametersΔρmin = −0.25 e Å−3
0 restraintsAbsolute structure: Flack (1983), 4291 Friedel pairs
Primary atom site location: structure-invariant direct methodsFlack parameter: −0.007 (3)
Crystal data top
[MnPt(C5H5)(C8H6)(C18H15P)2(CO)2]V = 4225.1 (3) Å3
Mr = 997.81Z = 4
Orthorhombic, P212121Mo Kα radiation
a = 11.1320 (4) ŵ = 3.72 mm−1
b = 19.4463 (7) ÅT = 283 K
c = 19.5174 (7) Å0.29 × 0.17 × 0.14 mm
Data collection top
Bruker SMART 4K CCD area-detector
diffractometer		9675 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 2004)		8974 reflections with I > 2σ(I)
Tmin = 0.352, Tmax = 0.624Rint = 0.026
37385 measured reflectionsθmax = 27.5°
Refinement top
R[F2 > 2σ(F2)] = 0.020H-atom parameters constrained
wR(F2) = 0.045Δρmax = 0.63 e Å−3
S = 0.95Δρmin = −0.25 e Å−3
9675 reflectionsAbsolute structure: Flack (1983), 4291 Friedel pairs
433 parametersFlack parameter: −0.007 (3)
0 restraints
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Pt0.442096 (9)0.414461 (5)0.378591 (5)0.03419 (3)
Mn0.22734 (4)0.46992 (2)0.36592 (2)0.03741 (10)
C30.2363 (3)0.37832 (16)0.38176 (18)0.0476 (7)
O30.2169 (2)0.32086 (12)0.39299 (14)0.0623 (7)
C40.1687 (3)0.47710 (18)0.44942 (19)0.0527 (8)
O40.1316 (3)0.48242 (15)0.50469 (14)0.0829 (9)
C110.0687 (3)0.48385 (18)0.30666 (18)0.0572 (9)
H11−0.00550.46560.31900.069*
C120.1152 (3)0.54915 (18)0.32649 (17)0.0523 (8)
H120.07680.58110.35430.063*
C130.2283 (3)0.55672 (17)0.29704 (16)0.0465 (7)
H130.27840.59470.30150.056*
C140.2538 (3)0.49653 (17)0.25917 (15)0.0476 (7)
H140.32360.48770.23450.057*
C150.1545 (3)0.45249 (17)0.26547 (17)0.0535 (9)
H150.14730.40930.24540.064*
C10.3757 (2)0.50564 (15)0.40819 (14)0.0367 (6)
C20.4220 (3)0.56321 (15)0.43342 (16)0.0451 (7)
H20.49970.55840.45020.054*
C50.37250 (19)0.63388 (8)0.43978 (11)0.0466 (7)
C60.45344 (16)0.68831 (12)0.43990 (13)0.0639 (9)
H60.53550.67970.43720.077*
C70.4117 (2)0.75556 (10)0.44408 (13)0.0756 (12)
H70.46590.79200.44420.091*
C80.2891 (3)0.76837 (8)0.44814 (13)0.0763 (13)
H80.26120.81340.45090.092*
C90.20817 (18)0.71395 (12)0.44802 (12)0.0665 (11)
H90.12610.72250.45070.080*
C100.24987 (17)0.64670 (10)0.44383 (11)0.0509 (8)
H100.19570.61030.44380.061*
P10.61667 (6)0.41618 (4)0.43912 (3)0.03333 (14)
C160.58867 (16)0.41181 (11)0.53218 (7)0.0375 (6)
C170.67643 (14)0.38760 (11)0.57673 (10)0.0492 (8)
H170.74930.37180.55960.059*
C180.65531 (19)0.38708 (12)0.64692 (9)0.0590 (9)
H180.71400.37090.67670.071*
C190.5464 (2)0.41076 (13)0.67256 (7)0.0680 (10)
H190.53230.41040.71950.082*
C200.45865 (17)0.43497 (12)0.62802 (10)0.0678 (10)
H200.38580.45080.64520.081*
C210.47977 (15)0.43550 (11)0.55783 (10)0.0505 (8)
H210.42100.45170.52800.061*
C220.73105 (14)0.34921 (8)0.42635 (11)0.0349 (6)
C230.71731 (16)0.28461 (10)0.45581 (10)0.0481 (8)
H230.64980.27500.48220.058*
C240.8044 (2)0.23441 (8)0.44583 (12)0.0587 (9)
H240.79530.19120.46550.070*
C250.90533 (17)0.24880 (10)0.40639 (12)0.0617 (10)
H250.96360.21520.39970.074*
C260.91907 (14)0.31340 (11)0.37693 (12)0.0617 (9)
H260.98660.32300.35050.074*
C270.83193 (17)0.36360 (8)0.38691 (11)0.0512 (8)
H270.84110.40680.36720.061*
C280.70882 (17)0.49435 (9)0.42915 (11)0.0394 (7)
C290.7922 (2)0.51345 (10)0.47865 (10)0.0567 (9)
H290.80220.48670.51770.068*
C300.86057 (18)0.57258 (11)0.46976 (12)0.0675 (11)
H300.91630.58540.50290.081*
C310.8456 (2)0.61260 (9)0.41137 (13)0.0636 (10)
H310.89140.65220.40540.076*
C320.7623 (2)0.59349 (10)0.36187 (10)0.0669 (10)
H320.75230.62030.32280.080*
C330.69389 (18)0.53437 (11)0.37076 (10)0.0524 (8)
H330.63810.52160.33760.063*
P20.47665 (7)0.32551 (4)0.29914 (4)0.03942 (18)
C340.36562 (19)0.32082 (12)0.22906 (10)0.0497 (8)
C350.2647 (2)0.27973 (11)0.23820 (12)0.0650 (11)
H350.25700.25320.27760.078*
C360.1754 (2)0.27830 (14)0.18846 (17)0.0879 (15)
H360.10790.25080.19460.105*
C370.1870 (3)0.31797 (17)0.12958 (14)0.107 (2)
H370.12720.31700.09630.128*
C380.2879 (3)0.35906 (15)0.12044 (10)0.0996 (16)
H380.29560.38560.08100.120*
C390.3772 (2)0.36048 (12)0.17018 (12)0.0717 (11)
H390.44470.38800.16410.086*
C400.48294 (18)0.23474 (8)0.32309 (10)0.0408 (7)
C410.4953 (2)0.18370 (11)0.27372 (8)0.0534 (8)
H410.49830.19540.22760.064*
C420.5033 (2)0.11515 (9)0.29336 (12)0.0644 (10)
H420.51160.08100.26030.077*
C430.4989 (2)0.09763 (8)0.36236 (14)0.0696 (11)
H430.50420.05180.37550.083*
C440.4865 (2)0.14866 (12)0.41172 (9)0.0654 (10)
H440.48350.13690.45790.079*
C450.47853 (19)0.21722 (10)0.39209 (9)0.0514 (8)
H450.47020.25140.42510.062*
C460.61840 (18)0.34361 (13)0.25456 (11)0.0539 (9)
C470.6366 (3)0.41109 (12)0.23350 (14)0.0776 (12)
H470.57720.44390.24080.093*
C480.7435 (3)0.42947 (15)0.20160 (15)0.112 (2)
H480.75570.47460.18750.134*
C490.8322 (2)0.3804 (2)0.19075 (15)0.124 (3)
H490.90380.39270.16940.149*
C500.8140 (2)0.31289 (19)0.21181 (15)0.1025 (18)
H500.87340.28000.20460.123*
C510.7071 (2)0.29451 (12)0.24372 (13)0.0691 (11)
H510.69500.24940.25780.083*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt0.02976 (5)0.03379 (5)0.03903 (5)0.00328 (4)−0.00323 (5)−0.00160 (5)
Mn0.0300 (2)0.0391 (2)0.0431 (3)0.00275 (17)−0.00165 (19)0.0078 (2)
C30.0390 (15)0.0498 (18)0.0541 (19)−0.0004 (13)−0.0131 (16)0.0089 (17)
O30.0487 (13)0.0455 (13)0.093 (2)−0.0087 (10)−0.0133 (13)0.0173 (13)
C40.0438 (18)0.055 (2)0.059 (2)0.0040 (16)0.0026 (17)0.0154 (17)
O40.090 (2)0.097 (2)0.0622 (17)0.0087 (17)0.0326 (16)0.0184 (15)
C110.0343 (17)0.069 (2)0.068 (2)−0.0031 (18)−0.0116 (18)0.0224 (18)
C120.0473 (18)0.057 (2)0.053 (2)0.0162 (16)−0.0060 (15)0.0099 (16)
C130.0469 (18)0.0446 (17)0.0480 (18)0.0006 (14)−0.0064 (15)0.0105 (14)
C140.0517 (19)0.054 (2)0.0376 (16)0.0057 (16)−0.0038 (14)0.0048 (14)
C150.059 (2)0.0473 (19)0.054 (2)−0.0007 (16)−0.0217 (17)0.0066 (15)
C10.0316 (14)0.0388 (16)0.0396 (15)0.0069 (12)0.0003 (12)−0.0027 (12)
C20.0403 (17)0.0436 (16)0.0514 (17)0.0076 (13)−0.0065 (14)−0.0063 (13)
C50.056 (2)0.0446 (18)0.0386 (17)0.0059 (15)−0.0002 (14)−0.0043 (14)
C60.072 (3)0.051 (2)0.068 (2)−0.010 (2)0.005 (2)−0.0109 (17)
C70.106 (3)0.041 (2)0.080 (3)−0.008 (2)0.003 (2)−0.0045 (19)
C80.120 (4)0.043 (2)0.066 (3)0.017 (2)−0.013 (3)−0.0073 (18)
C90.080 (3)0.061 (2)0.058 (2)0.027 (2)−0.010 (2)−0.0063 (18)
C100.059 (2)0.0469 (19)0.0462 (19)0.0103 (16)−0.0040 (15)−0.0026 (15)
P10.0283 (3)0.0347 (3)0.0370 (4)0.0017 (3)−0.0003 (3)−0.0014 (3)
C160.0362 (14)0.0360 (14)0.0403 (14)−0.0019 (13)0.0017 (11)−0.0037 (14)
C170.0465 (18)0.057 (2)0.0438 (18)0.0013 (15)−0.0061 (14)−0.0044 (14)
C180.076 (2)0.058 (2)0.0427 (18)−0.0018 (18)−0.0076 (17)−0.0030 (15)
C190.100 (3)0.068 (2)0.0370 (16)−0.004 (3)0.0128 (19)−0.0091 (17)
C200.074 (2)0.074 (2)0.056 (2)0.0110 (19)0.023 (2)−0.0104 (18)
C210.0527 (19)0.0512 (19)0.0475 (18)0.0101 (15)0.0081 (15)−0.0024 (14)
C220.0291 (14)0.0395 (16)0.0363 (15)0.0046 (12)−0.0008 (11)−0.0031 (12)
C230.0418 (18)0.0488 (19)0.054 (2)0.0067 (14)0.0009 (15)0.0010 (15)
C240.067 (2)0.0404 (18)0.069 (2)0.0173 (17)−0.0057 (19)−0.0005 (16)
C250.053 (2)0.059 (2)0.073 (2)0.0256 (17)−0.0055 (17)−0.0111 (19)
C260.0396 (17)0.071 (2)0.075 (2)0.0102 (15)0.0130 (18)−0.010 (2)
C270.0396 (16)0.0487 (17)0.065 (2)0.0065 (13)0.0086 (17)0.0031 (17)
C280.0326 (15)0.0343 (15)0.0513 (18)0.0027 (12)0.0053 (13)−0.0041 (13)
C290.055 (2)0.0459 (19)0.069 (2)−0.0013 (16)−0.0159 (17)0.0033 (17)
C300.056 (2)0.041 (2)0.106 (3)−0.0062 (16)−0.017 (2)−0.0147 (19)
C310.055 (2)0.0401 (18)0.095 (3)−0.0094 (16)0.014 (2)−0.0115 (19)
C320.081 (2)0.050 (2)0.070 (2)−0.0014 (19)0.019 (2)0.0101 (19)
C330.0588 (19)0.0487 (17)0.0497 (19)−0.0058 (15)0.0030 (17)0.0020 (16)
P20.0405 (4)0.0372 (4)0.0406 (4)0.0017 (3)−0.0012 (3)−0.0043 (3)
C340.062 (2)0.0414 (18)0.0456 (18)0.0124 (16)−0.0118 (16)−0.0120 (14)
C350.062 (2)0.046 (2)0.088 (3)0.0081 (17)−0.028 (2)−0.0165 (19)
C360.078 (3)0.065 (3)0.121 (4)0.014 (2)−0.047 (3)−0.040 (3)
C370.125 (4)0.111 (4)0.084 (4)0.050 (3)−0.063 (3)−0.050 (3)
C380.143 (5)0.111 (4)0.044 (2)0.042 (3)−0.025 (3)−0.007 (3)
C390.091 (3)0.079 (3)0.045 (2)0.018 (2)−0.006 (2)−0.0082 (19)
C400.0361 (15)0.0367 (16)0.0498 (17)0.0043 (12)−0.0015 (12)−0.0017 (13)
C410.0520 (19)0.0454 (19)0.063 (2)0.0126 (15)0.0006 (17)−0.0043 (16)
C420.056 (2)0.045 (2)0.092 (3)0.0104 (17)−0.003 (2)−0.0141 (19)
C430.060 (2)0.044 (2)0.104 (3)0.0073 (16)0.000 (2)0.015 (2)
C440.055 (2)0.069 (3)0.072 (2)−0.0015 (18)−0.0058 (18)0.020 (2)
C450.0461 (17)0.0490 (18)0.059 (2)0.0055 (13)−0.0013 (15)0.0006 (15)
C460.055 (2)0.066 (2)0.0409 (18)−0.0111 (18)0.0037 (16)−0.0115 (16)
C470.094 (3)0.075 (3)0.063 (2)−0.031 (3)0.013 (2)−0.004 (2)
C480.137 (5)0.121 (5)0.076 (3)−0.074 (4)0.035 (3)−0.009 (3)
C490.096 (4)0.199 (7)0.076 (3)−0.075 (4)0.030 (3)−0.046 (4)
C500.056 (3)0.168 (5)0.083 (3)−0.017 (3)0.019 (2)−0.045 (3)
C510.051 (2)0.092 (3)0.064 (2)−0.005 (2)0.0084 (18)−0.017 (2)
Geometric parameters (Å, °) top
Pt—C12.006 (3)C23—H230.9300
Pt—C32.397 (3)C24—C251.3900
Pt—P12.2745 (7)C24—H240.9300
Pt—P22.3548 (8)C25—C261.3900
Pt—Mn2.6344 (4)C25—H250.9300
Mn—C11.972 (3)C26—C271.3900
Mn—C31.811 (3)C26—H260.9300
Mn—C41.761 (4)C27—H270.9300
Mn—C112.129 (3)C28—C291.3900
Mn—C122.127 (3)C28—C331.3900
Mn—C132.158 (3)C29—C301.3900
Mn—C142.167 (3)C29—H290.9300
Mn—C152.149 (3)C30—C311.3900
C3—O31.159 (3)C30—H300.9300
C4—O41.160 (4)C31—C321.3900
C11—C151.390 (5)C31—H310.9300
C11—C121.425 (5)C32—C331.3900
C11—H110.9300C32—H320.9300
C12—C131.391 (5)C33—H330.9300
C12—H120.9300P2—C401.8273 (16)
C13—C141.413 (4)P2—C461.8359 (19)
C13—H130.9300P2—C341.8457 (18)
C14—C151.404 (5)C34—C351.3900
C14—H140.9300C34—C391.3900
C15—H150.9300C35—C361.3900
C1—C21.327 (4)C35—H350.9300
C2—C51.486 (3)C36—C371.3900
C2—H20.9300C36—H360.9300
C5—C61.3900C37—C381.3900
C5—C101.3900C37—H370.9300
C6—C71.3900C38—C391.3900
C6—H60.9300C38—H380.9300
C7—C81.3900C39—H390.9300
C7—H70.9300C40—C411.3900
C8—C91.3900C40—C451.3900
C8—H80.9300C41—C421.3900
C9—C101.3900C41—H410.9300
C9—H90.9300C42—C431.3900
C10—H100.9300C42—H420.9300
P1—C221.8382 (15)C43—C441.3900
P1—C281.8442 (16)C43—H430.9300
P1—C161.8448 (15)C44—C451.3900
C16—C171.3900C44—H440.9300
C16—C211.3900C45—H450.9300
C17—C181.3900C46—C471.3900
C17—H170.9300C46—C511.3900
C18—C191.3900C47—C481.3900
C18—H180.9300C47—H470.9300
C19—C201.3900C48—C491.3900
C19—H190.9300C48—H480.9300
C20—C211.3900C49—C501.3900
C20—H200.9300C49—H490.9300
C21—H210.9300C50—C511.3900
C22—C231.3900C50—H500.9300
C22—C271.3900C51—H510.9300
C23—C241.3900
C1—Pt—P198.76 (8)C21—C16—P1119.12 (11)
C1—Pt—P2154.04 (8)C16—C17—C18120.0
P1—Pt—P2102.31 (3)C16—C17—H17120.0
C1—Pt—C384.23 (11)C18—C17—H17120.0
P1—Pt—C3143.85 (8)C19—C18—C17120.0
P2—Pt—C387.58 (8)C19—C18—H18120.0
C1—Pt—Mn47.99 (8)C17—C18—H18120.0
P1—Pt—Mn144.90 (2)C20—C19—C18120.0
P2—Pt—Mn112.78 (2)C20—C19—H19120.0
C3—Pt—Mn41.86 (7)C18—C19—H19120.0
C4—Mn—C386.59 (16)C21—C20—C19120.0
C4—Mn—C184.00 (14)C21—C20—H20120.0
C3—Mn—C1103.22 (13)C19—C20—H20120.0
C4—Mn—C1293.44 (14)C20—C21—C16120.0
C3—Mn—C12143.79 (13)C20—C21—H21120.0
C1—Mn—C12112.80 (13)C16—C21—H21120.0
C4—Mn—C11100.66 (15)C23—C22—C27120.0
C3—Mn—C11105.29 (14)C23—C22—P1120.53 (11)
C1—Mn—C11151.32 (13)C27—C22—P1119.47 (11)
C12—Mn—C1139.13 (13)C22—C23—C24120.0
C4—Mn—C15135.80 (15)C22—C23—H23120.0
C3—Mn—C1591.22 (14)C24—C23—H23120.0
C1—Mn—C15138.88 (13)C25—C24—C23120.0
C12—Mn—C1564.06 (13)C25—C24—H24120.0
C11—Mn—C1537.91 (13)C23—C24—H24120.0
C4—Mn—C13121.09 (14)C24—C25—C26120.0
C3—Mn—C13151.11 (15)C24—C25—H25120.0
C1—Mn—C1388.91 (12)C26—C25—H25120.0
C12—Mn—C1337.89 (12)C25—C26—C27120.0
C11—Mn—C1364.29 (12)C25—C26—H26120.0
C15—Mn—C1363.70 (12)C27—C26—H26120.0
C4—Mn—C14157.10 (14)C26—C27—C22120.0
C3—Mn—C14113.05 (15)C26—C27—H27120.0
C1—Mn—C14101.79 (12)C22—C27—H27120.0
C12—Mn—C1463.82 (13)C29—C28—C33120.0
C11—Mn—C1463.89 (13)C29—C28—P1121.22 (12)
C15—Mn—C1437.96 (12)C33—C28—P1118.79 (12)
C13—Mn—C1438.14 (12)C30—C29—C28120.0
C4—Mn—Pt106.38 (11)C30—C29—H29120.0
C3—Mn—Pt62.03 (9)C28—C29—H29120.0
C1—Mn—Pt49.08 (8)C31—C30—C29120.0
C12—Mn—Pt149.66 (10)C31—C30—H30120.0
C11—Mn—Pt148.89 (11)C29—C30—H30120.0
C15—Mn—Pt111.32 (10)C30—C31—C32120.0
C13—Mn—Pt111.97 (9)C30—C31—H31120.0
C14—Mn—Pt93.71 (9)C32—C31—H31120.0
O3—C3—Mn166.0 (3)C33—C32—C31120.0
O3—C3—Pt117.7 (2)C33—C32—H32120.0
Mn—C3—Pt76.11 (11)C31—C32—H32120.0
O4—C4—Mn178.9 (4)C32—C33—C28120.0
C15—C11—C12107.3 (3)C32—C33—H33120.0
C15—C11—Mn71.82 (19)C28—C33—H33120.0
C12—C11—Mn70.36 (18)C40—P2—C46105.87 (11)
C15—C11—H11126.3C40—P2—C3499.64 (10)
C12—C11—H11126.3C46—P2—C34103.53 (11)
Mn—C11—H11123.2C40—P2—Pt123.19 (7)
C13—C12—C11108.1 (3)C46—P2—Pt108.16 (8)
C13—C12—Mn72.27 (18)C34—P2—Pt114.51 (8)
C11—C12—Mn70.51 (18)C35—C34—C39120.0
C13—C12—H12125.9C35—C34—P2118.32 (14)
C11—C12—H12125.9C39—C34—P2121.55 (14)
Mn—C12—H12122.9C36—C35—C34120.0
C12—C13—C14108.1 (3)C36—C35—H35120.0
C12—C13—Mn69.84 (18)C34—C35—H35120.0
C14—C13—Mn71.28 (18)C35—C36—C37120.0
C12—C13—H13126.0C35—C36—H36120.0
C14—C13—H13126.0C37—C36—H36120.0
Mn—C13—H13124.5C38—C37—C36120.0
C15—C14—C13107.5 (3)C38—C37—H37120.0
C15—C14—Mn70.31 (19)C36—C37—H37120.0
C13—C14—Mn70.58 (17)C39—C38—C37120.0
C15—C14—H14126.2C39—C38—H38120.0
C13—C14—H14126.2C37—C38—H38120.0
Mn—C14—H14124.5C38—C39—C34120.0
C11—C15—C14108.9 (3)C38—C39—H39120.0
C11—C15—Mn70.27 (19)C34—C39—H39120.0
C14—C15—Mn71.73 (18)C41—C40—C45120.0
C11—C15—H15125.5C41—C40—P2121.08 (12)
C14—C15—H15125.5C45—C40—P2118.90 (12)
Mn—C15—H15124.1C42—C41—C40120.0
C2—C1—Mn141.0 (2)C42—C41—H41120.0
C2—C1—Pt135.2 (2)C40—C41—H41120.0
Mn—C1—Pt82.93 (11)C41—C42—C43120.0
C1—C2—C5131.9 (3)C41—C42—H42120.0
C1—C2—H2114.1C43—C42—H42120.0
C5—C2—H2114.1C44—C43—C42120.0
C6—C5—C10120.0C44—C43—H43120.0
C6—C5—C2117.66 (18)C42—C43—H43120.0
C10—C5—C2122.32 (18)C43—C44—C45120.0
C5—C6—C7120.0C43—C44—H44120.0
C5—C6—H6120.0C45—C44—H44120.0
C7—C6—H6120.0C44—C45—C40120.0
C8—C7—C6120.0C44—C45—H45120.0
C8—C7—H7120.0C40—C45—H45120.0
C6—C7—H7120.0C47—C46—C51120.0
C9—C8—C7120.0C47—C46—P2116.51 (15)
C9—C8—H8120.0C51—C46—P2123.45 (15)
C7—C8—H8120.0C48—C47—C46120.0
C8—C9—C10120.0C48—C47—H47120.0
C8—C9—H9120.0C46—C47—H47120.0
C10—C9—H9120.0C47—C48—C49120.0
C9—C10—C5120.0C47—C48—H48120.0
C9—C10—H10120.0C49—C48—H48120.0
C5—C10—H10120.0C50—C49—C48120.0
C22—P1—C28100.62 (9)C50—C49—H49120.0
C22—P1—C16102.59 (9)C48—C49—H49120.0
C28—P1—C16103.64 (10)C49—C50—C51120.0
C22—P1—Pt120.73 (7)C49—C50—H50120.0
C28—P1—Pt115.63 (7)C51—C50—H50120.0
C16—P1—Pt111.49 (6)C50—C51—C46120.0
C17—C16—C21120.0C50—C51—H51120.0
C17—C16—P1120.84 (11)C46—C51—H51120.0
Table 1
Selected geometric parameters (Å) top
Pt—C12.006 (3)Mn—C41.761 (4)
Pt—C32.397 (3)Mn—C112.129 (3)
Pt—P12.2745 (7)Mn—C122.127 (3)
Pt—P22.3548 (8)Mn—C132.158 (3)
Pt—Mn2.6344 (4)Mn—C142.167 (3)
Mn—C11.972 (3)Mn—C152.149 (3)
Mn—C31.811 (3)
Acknowledgements top

This work was supported by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project No. NSh-4137.2006.2) and the Krasnoyarsk Regional Science Foundation (grant Nos. 10TS145 and 17 G002).

references
References top

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