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Acta Cryst. (2007). E63, m2163    [ doi:10.1107/S1600536807034083 ]

Chlorido[(1,2,5,6-[eta])-1,3,5,7-cyclooctatetraene]phenylplatinum(II)

A.-R. Song, I.-C. Hwang and K. Ha

Abstract top

In the title complex, [Pt(C6H5)Cl(C8H8)], the PtII centre lies in a square-planar environment defined by the Cl and [sigma]-bonded phenyl C atoms and the mid-points of the two [pi]-coordinated double bonds of 1,3,5,7-cyclooctatetraene. Because of the different trans influences of the Cl atom and the phenyl group, the Pt-C bonds trans to the phenyl group are longer than those trans to the Cl atom. The asymmetric unit contains four independent molecules with identical geometry within experimental errors.

Comment top

The crystal structure analysis of the title complex, [Pt(C6H5)Cl(C8H8)], reveals that an asymmetric unit contains four chemically equivalent, but crystallographically independent molecules (Fig. 1).

In the complex, the central PtII ion lies in an essentially square-planar environment defined by the Cl and σ-bonded phenyl C atoms and by the two midpoints (M1x, M2x; x = a, b, c, d) of the π-coordinated double bonds of the 1,3,5,7-cyclooctatetraene (cot) ligand (M1x and M2x denote the midpoints of the olefinic bonds C1x—C2x and C5x—C6x, respectively). The Pt, Cl, C9x atoms and the midpoints lie in a coordination plane with the largest deviation of 0.031 Å (C9b) from the least-squares plane, and with bond angles in the range 84.8°–94.8°. The dihedral angles between the respective least-squares planes and phenyl rings in four complexes are 76.93°, 71.16°, 85.90° or 71.73°.

Owing to the different trans influences of the Cl atom and phenyl group, the Pt—C bonds trans to C9x are on average 0.201 Å longer than those trans to Cl (mean lengths: Pt—C1x/C2x = 2.325 Å, Pt—C5x/C6x = 2.124 Å). The mean distances between the Pt atom and the midpoints are 2.225 Å (M1x) and 2.005 Å (M2x). The COT ligand coordinates symmetrically to the Pt atom in the "tub" conformation, and displays some increase in the coordinated double-bond distances (1.352 (12)–1.428 (12) Å) compared to the non-coordinated double bonds (1.280 (11)–1.327 (12) Å). The four coordinating C atoms (C1x, C2x, C5x and C6x) and the four non-coordinating C atoms (C3x, C4x, C7x and C8x) lie on respective planes, with the torsion angles C1x—C2x—C5x—C6x = -0.7 (8)–1.1 (8)° and C3x—C4x—C7x—C8x = -1.2 (8)–0.5 (8)°. The Pt atom is displaced on average by 1.550 Å from the plane C1x/C2x/C5x/C6x, and by 2.495 Å from the plane C3x/C4x/C7x/C8x. In the complex, the cot ring angles lie in the range 120.1 (8)°–124.7 (9)°.

Related literature top

For related literature, see: Song et al. (2007).

Experimental top

A solution of [PtCl2(C8H8)] (0.0829 g, 0.224 mmol) and [Pt(C6H5)2(C8H8)] (0.1005 g, 0.222 mmol) in CH2Cl2 (30 ml) was stirred for 48 h at room temperature. Pentane was added to the solution, the orange precipitate formed by -5 °C was removed by filtration. Evaporation of the solvent gave a yellow powder (0.0188 g). Crystals suitable for X-ray analysis were obtained by slow evaporation from a pentane solution.

Refinement top

All H atoms were fixed geometrically and treated as riding with C—H = 0.93 \%A (aromatic) or 0.98 \%A (methine) with Uĩso~(H) = 1.2U~eq~(C).

Computing details top

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

Figures top
[Figure 1] Fig. 1. View of the four complexes within the asymmetric unit showing the atom-labelling scheme. Ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity.
Chlorido[(1,2,5,6-η)-1,3,5,7-cyclooctatetraene]phenylplatinum(II) top
Crystal data top
[Pt(C6H5)Cl(C8H8)]Z = 8
Mr = 411.78F(000) = 1536
Triclinic, P1Dx = 2.169 Mg m−3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 13.1746 (9) ÅCell parameters from 4742 reflections
b = 13.5924 (9) Åθ = 2.3–26.4°
c = 14.7998 (10) ŵ = 11.31 mm−1
α = 90.199 (1)°T = 293 K
β = 105.024 (1)°Cylinder, yellow
γ = 99.466 (1)°0.25 × 0.20 × 0.15 mm
V = 2521.9 (3) Å3
Data collection top
Bruker SMART 1000 CCD
diffractometer		10050 independent reflections
Radiation source: fine-focus sealed tube7293 reflections with I > 2σ(I)
graphiteRint = 0.021
φ and ω scansθmax = 26.4°, θmin = 1.5°
Absorption correction: multi-scan
(SADABS; Bruker, 2000)		h = −12→16
Tmin = 0.571, Tmax = 1.000k = −16→15
14816 measured reflectionsl = −18→17
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.081H-atom parameters constrained
S = 0.98 w = 1/[σ2(Fo2) + (0.0278P)2]
where P = (Fo2 + 2Fc2)/3
10050 reflections(Δ/σ)max = 0.001
577 parametersΔρmax = 1.42 e Å−3
0 restraintsΔρmin = −1.10 e Å−3
Crystal data top
[Pt(C6H5)Cl(C8H8)]γ = 99.466 (1)°
Mr = 411.78V = 2521.9 (3) Å3
Triclinic, P1Z = 8
a = 13.1746 (9) ÅMo Kα radiation
b = 13.5924 (9) ŵ = 11.31 mm−1
c = 14.7998 (10) ÅT = 293 K
α = 90.199 (1)°0.25 × 0.20 × 0.15 mm
β = 105.024 (1)°
Data collection top
Bruker SMART 1000 CCD
diffractometer		10050 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2000)		7293 reflections with I > 2σ(I)
Tmin = 0.571, Tmax = 1.000Rint = 0.021
14816 measured reflectionsθmax = 26.4°
Refinement top
R[F2 > 2σ(F2)] = 0.038H-atom parameters constrained
wR(F2) = 0.081Δρmax = 1.42 e Å−3
S = 0.98Δρmin = −1.10 e Å−3
10050 reflectionsAbsolute structure: ?
577 parametersFlack parameter: ?
0 restraintsRogers parameter: ?
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Pt10.75425 (2)0.05213 (2)0.00332 (2)0.03832 (9)
Cl10.64525 (16)0.09078 (16)0.09255 (15)0.0493 (5)
C1A0.6543 (6)0.1110 (7)−0.1330 (6)0.050 (2)
H1A0.60790.1577−0.12430.059*
C2A0.6147 (7)0.0130 (8)−0.1309 (6)0.063 (3)
H2A0.5429−0.0030−0.12160.076*
C3A0.6516 (10)−0.0678 (8)−0.1765 (7)0.081 (3)
H3A0.6030−0.1059−0.22630.097*
C4A0.7473 (10)−0.0875 (8)−0.1505 (8)0.078 (3)
H4A0.7644−0.1397−0.18140.093*
C5A0.8284 (8)−0.0312 (8)−0.0751 (7)0.061 (3)
H5A0.8790−0.0701−0.03740.073*
C6A0.8679 (7)0.0704 (8)−0.0757 (7)0.063 (3)
H6A0.94220.0920−0.03980.076*
C7A0.8295 (8)0.1311 (8)−0.1570 (7)0.070 (3)
H7A0.87720.1581−0.19050.084*
C8A0.7336 (8)0.1478 (7)−0.1828 (7)0.065 (3)
H8A0.71400.1849−0.23520.078*
C9A0.8677 (6)0.0426 (7)0.1219 (6)0.044 (2)
C10A0.8879 (6)−0.0479 (7)0.1570 (6)0.051 (2)
H10A0.8504−0.10680.12430.062*
C11A0.9640 (7)−0.0515 (8)0.2412 (7)0.065 (3)
H11A0.9761−0.11300.26500.077*
C12A1.0208 (8)0.0339 (11)0.2892 (7)0.081 (4)
H12A1.07270.03120.34490.097*
C13A1.0009 (7)0.1229 (9)0.2549 (8)0.081 (3)
H13A1.03840.18170.28800.097*
C14A0.9266 (7)0.1276 (8)0.1724 (7)0.067 (3)
H14A0.91550.18970.14960.080*
Pt20.24071 (3)0.13962 (2)0.51937 (2)0.04122 (9)
Cl20.10337 (18)0.21454 (18)0.54705 (18)0.0648 (7)
C1B0.1702 (7)−0.0199 (6)0.5571 (7)0.055 (2)
H1B0.0944−0.03140.55580.066*
C2B0.2390 (7)0.0271 (6)0.6363 (6)0.055 (2)
H2B0.20570.04510.68460.066*
C3B0.3519 (7)0.0145 (6)0.6711 (6)0.055 (2)
H3B0.3740−0.01700.72670.065*
C4B0.4201 (7)0.0475 (7)0.6240 (7)0.058 (3)
H4B0.49050.03900.64760.070*
C5B0.3920 (6)0.0977 (6)0.5353 (7)0.053 (2)
H5B0.44770.15040.52510.064*
C6B0.3208 (6)0.0502 (6)0.4540 (6)0.049 (2)
H6B0.33400.07460.39520.058*
C7B0.2714 (7)−0.0540 (6)0.4501 (6)0.054 (2)
H7B0.2903−0.09940.41280.065*
C8B0.2025 (7)−0.0866 (7)0.4958 (6)0.059 (3)
H8B0.1726−0.15400.48970.071*
C9B0.2847 (6)0.2603 (6)0.4528 (6)0.043 (2)
C10B0.3340 (7)0.3488 (6)0.5044 (7)0.056 (2)
H10B0.34220.35170.56870.068*
C11B0.3711 (7)0.4323 (7)0.4621 (8)0.068 (3)
H11B0.40460.49030.49840.082*
C12B0.3593 (8)0.4307 (7)0.3679 (8)0.069 (3)
H12B0.38470.48720.33970.083*
C13B0.3097 (8)0.3451 (8)0.3154 (7)0.070 (3)
H13B0.30130.34300.25100.084*
C14B0.2719 (7)0.2613 (6)0.3581 (6)0.054 (2)
H14B0.23680.20410.32120.065*
Pt30.75795 (2)0.56154 (2)−0.02313 (2)0.04247 (10)
Cl30.89540 (17)0.68604 (17)−0.03954 (19)0.0667 (7)
C1C0.8416 (8)0.4314 (7)−0.0552 (7)0.066 (3)
H1C0.91870.4483−0.04790.079*
C2C0.7781 (7)0.4540 (7)−0.1375 (7)0.056 (2)
H2C0.81580.4857−0.18170.067*
C3C0.6695 (8)0.4024 (7)−0.1796 (6)0.064 (3)
H3C0.65480.3654−0.23580.077*
C4C0.5911 (8)0.4070 (7)−0.1395 (7)0.066 (3)
H4C0.52350.3713−0.16740.079*
C5C0.6075 (6)0.4656 (6)−0.0542 (7)0.053 (2)
H5C0.54730.4974−0.04960.063*
C6C0.6727 (8)0.4407 (6)0.0329 (7)0.064 (3)
H6C0.65070.45820.08840.076*
C7C0.7324 (9)0.3554 (7)0.0429 (6)0.068 (3)
H7C0.71600.30420.08100.082*
C8C0.8065 (8)0.3495 (7)0.0007 (7)0.071 (3)
H8C0.83790.29260.00590.086*
C9C0.7030 (7)0.6638 (6)0.0429 (7)0.052 (2)
C10C0.6319 (8)0.7219 (7)−0.0084 (7)0.069 (3)
H10C0.61070.7155−0.07340.083*
C11C0.5926 (8)0.7905 (7)0.0399 (9)0.073 (3)
H11C0.54600.83040.00680.088*
C12C0.6233 (8)0.7979 (7)0.1355 (9)0.075 (3)
H12C0.59730.84290.16740.089*
C13C0.6912 (7)0.7405 (7)0.1845 (7)0.062 (3)
H13C0.71120.74650.24960.075*
C14C0.7301 (7)0.6746 (6)0.1399 (7)0.053 (2)
H14C0.77620.63550.17500.063*
Pt40.24901 (3)0.64012 (2)0.50050 (2)0.04303 (10)
Cl40.36282 (16)0.71145 (16)0.41460 (15)0.0517 (5)
C1D0.3456 (8)0.7358 (8)0.6342 (6)0.063 (3)
H1D0.39230.79640.62410.076*
C2D0.3859 (8)0.6502 (8)0.6361 (6)0.068 (3)
H2D0.45810.65670.62770.082*
C3D0.3525 (11)0.5642 (10)0.6877 (8)0.093 (4)
H3D0.40050.54600.74020.112*
C4D0.2571 (14)0.5137 (9)0.6609 (8)0.110 (5)
H4D0.24020.45810.69410.132*
C5D0.1726 (8)0.5385 (8)0.5806 (7)0.072 (3)
H5D0.12320.48120.54510.086*
C6D0.1318 (9)0.6268 (8)0.5785 (8)0.077 (3)
H6D0.05810.62240.54030.093*
C7D0.1648 (10)0.7040 (8)0.6544 (8)0.081 (3)
H7D0.11460.72030.68320.097*
C8D0.2648 (10)0.7513 (7)0.6829 (7)0.076 (3)
H8D0.28430.79540.73510.091*
C9D0.1368 (6)0.5940 (6)0.3809 (6)0.044 (2)
C10D0.1077 (7)0.4927 (7)0.3491 (6)0.052 (2)
H10D0.14130.44480.38400.063*
C11D0.0301 (7)0.4643 (8)0.2670 (7)0.063 (3)
H11D0.01130.39720.24710.075*
C12D−0.0193 (7)0.5329 (9)0.2148 (7)0.068 (3)
H12D−0.07230.51300.15980.082*
C13D0.0092 (8)0.6318 (9)0.2435 (8)0.081 (3)
H13D−0.02350.67910.20690.097*
C14D0.0858 (7)0.6621 (7)0.3259 (7)0.062 (3)
H14D0.10340.72950.34470.075*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt10.03622 (18)0.0448 (2)0.03543 (18)0.01073 (15)0.00968 (14)0.00399 (15)
Cl10.0459 (12)0.0617 (14)0.0460 (12)0.0162 (11)0.0176 (10)0.0055 (11)
C1A0.044 (5)0.066 (6)0.042 (5)0.022 (5)0.008 (4)0.006 (5)
C2A0.049 (6)0.091 (8)0.036 (5)0.001 (6)−0.009 (4)−0.001 (5)
C3A0.124 (10)0.060 (7)0.040 (6)−0.009 (7)0.003 (7)−0.018 (5)
C4A0.121 (10)0.058 (7)0.061 (7)0.031 (7)0.025 (7)−0.002 (6)
C5A0.074 (7)0.070 (7)0.055 (6)0.041 (6)0.029 (5)0.008 (5)
C6A0.047 (6)0.089 (8)0.067 (7)0.022 (6)0.031 (5)0.004 (6)
C7A0.077 (7)0.082 (8)0.069 (7)0.018 (6)0.046 (6)0.025 (6)
C8A0.088 (7)0.066 (7)0.052 (6)0.028 (6)0.029 (6)0.018 (5)
C9A0.035 (4)0.056 (6)0.046 (5)0.019 (4)0.012 (4)0.007 (4)
C10A0.048 (5)0.057 (6)0.053 (6)0.016 (5)0.017 (4)0.008 (5)
C11A0.062 (6)0.088 (8)0.057 (7)0.042 (6)0.021 (5)0.034 (6)
C12A0.051 (6)0.151 (12)0.043 (6)0.042 (8)−0.001 (5)−0.001 (7)
C13A0.058 (7)0.087 (9)0.082 (8)0.019 (6)−0.013 (6)−0.022 (7)
C14A0.059 (6)0.068 (7)0.064 (7)0.016 (5)−0.003 (5)−0.001 (6)
Pt20.0467 (2)0.03656 (19)0.0405 (2)0.00732 (16)0.01160 (15)−0.00008 (15)
Cl20.0615 (15)0.0645 (16)0.0802 (18)0.0242 (13)0.0310 (13)0.0090 (14)
C1B0.044 (5)0.044 (6)0.071 (7)−0.004 (4)0.014 (5)0.013 (5)
C2B0.068 (6)0.054 (6)0.051 (6)0.010 (5)0.031 (5)0.015 (5)
C3B0.071 (6)0.052 (6)0.033 (5)0.001 (5)0.007 (5)0.004 (4)
C4B0.049 (6)0.057 (6)0.063 (6)0.020 (5)−0.003 (5)0.004 (5)
C5B0.045 (5)0.052 (6)0.072 (7)0.017 (5)0.027 (5)0.019 (5)
C6B0.057 (5)0.049 (6)0.048 (5)0.014 (5)0.025 (5)−0.002 (4)
C7B0.067 (6)0.044 (6)0.055 (6)0.018 (5)0.015 (5)−0.009 (5)
C8B0.070 (7)0.041 (6)0.055 (6)0.007 (5)−0.002 (5)−0.008 (5)
C9B0.046 (5)0.036 (5)0.046 (5)0.005 (4)0.013 (4)0.006 (4)
C10B0.071 (6)0.036 (5)0.060 (6)0.010 (5)0.014 (5)−0.004 (5)
C11B0.063 (6)0.034 (5)0.102 (9)0.003 (5)0.015 (6)−0.004 (6)
C12B0.069 (7)0.046 (6)0.095 (9)0.013 (5)0.027 (6)0.021 (6)
C13B0.080 (7)0.064 (7)0.071 (7)0.019 (6)0.025 (6)0.022 (6)
C14B0.070 (6)0.046 (5)0.047 (6)0.007 (5)0.020 (5)0.003 (4)
Pt30.0442 (2)0.0390 (2)0.0488 (2)0.00902 (16)0.01913 (16)0.00806 (16)
Cl30.0537 (14)0.0526 (14)0.095 (2)−0.0053 (12)0.0314 (14)0.0033 (14)
C1C0.077 (7)0.059 (7)0.077 (8)0.036 (6)0.035 (6)−0.001 (6)
C2C0.059 (6)0.068 (7)0.053 (6)0.014 (5)0.034 (5)−0.001 (5)
C3C0.091 (8)0.064 (7)0.042 (6)0.019 (6)0.020 (6)0.004 (5)
C4C0.067 (7)0.050 (6)0.061 (7)−0.011 (5)−0.003 (5)−0.006 (5)
C5C0.038 (5)0.051 (6)0.073 (7)−0.003 (4)0.026 (5)0.005 (5)
C6C0.090 (7)0.039 (5)0.070 (7)−0.008 (5)0.047 (6)0.011 (5)
C7C0.119 (9)0.041 (6)0.047 (6)0.012 (6)0.026 (6)0.012 (5)
C8C0.100 (9)0.055 (7)0.061 (7)0.033 (6)0.013 (6)−0.003 (5)
C9C0.065 (6)0.035 (5)0.062 (6)0.020 (5)0.020 (5)0.013 (5)
C10C0.087 (8)0.055 (6)0.072 (7)0.028 (6)0.020 (6)0.022 (6)
C11C0.060 (7)0.061 (7)0.106 (10)0.031 (6)0.022 (7)0.010 (7)
C12C0.069 (7)0.053 (7)0.105 (10)−0.001 (6)0.036 (7)−0.024 (7)
C13C0.063 (6)0.056 (6)0.063 (7)0.008 (5)0.010 (5)−0.012 (5)
C14C0.054 (6)0.046 (5)0.062 (6)0.017 (5)0.017 (5)0.003 (5)
Pt40.0513 (2)0.03866 (19)0.0395 (2)0.00395 (16)0.01497 (16)0.00282 (15)
Cl40.0522 (13)0.0488 (13)0.0546 (14)−0.0013 (11)0.0210 (11)0.0012 (11)
C1D0.068 (7)0.064 (7)0.049 (6)−0.004 (6)0.007 (5)−0.008 (5)
C2D0.078 (7)0.077 (8)0.042 (6)0.022 (6)−0.004 (5)0.002 (5)
C3D0.149 (12)0.082 (10)0.044 (7)0.044 (9)0.002 (8)0.008 (7)
C4D0.229 (18)0.065 (9)0.046 (8)0.035 (10)0.050 (10)0.011 (7)
C5D0.095 (8)0.064 (7)0.058 (7)−0.016 (6)0.040 (6)0.010 (6)
C6D0.101 (8)0.066 (7)0.087 (9)0.012 (7)0.064 (7)0.009 (6)
C7D0.127 (10)0.061 (7)0.071 (8)0.007 (7)0.063 (8)−0.001 (6)
C8D0.115 (9)0.056 (7)0.054 (7)0.008 (7)0.022 (7)−0.007 (5)
C9D0.034 (4)0.052 (5)0.044 (5)−0.004 (4)0.014 (4)−0.007 (4)
C10D0.047 (5)0.055 (6)0.058 (6)0.002 (5)0.025 (5)−0.001 (5)
C11D0.053 (6)0.058 (6)0.078 (8)−0.008 (5)0.030 (6)−0.008 (6)
C12D0.035 (5)0.097 (9)0.058 (7)−0.013 (6)0.002 (5)−0.015 (6)
C13D0.059 (7)0.083 (9)0.087 (9)0.007 (6)−0.002 (6)0.001 (7)
C14D0.061 (6)0.050 (6)0.068 (7)0.009 (5)0.004 (5)0.006 (5)
Geometric parameters (Å, °) top
Pt1—C9A2.009 (8)Pt3—C9C2.025 (9)
Pt1—C6A2.113 (8)Pt3—C5C2.125 (8)
Pt1—C5A2.127 (8)Pt3—C6C2.130 (7)
Pt1—Cl12.304 (2)Pt3—C2C2.327 (9)
Pt1—C2A2.321 (8)Pt3—Cl32.329 (2)
Pt1—C1A2.329 (8)Pt3—C1C2.340 (8)
C1A—C2A1.352 (12)C1C—C2C1.355 (12)
C1A—C8A1.455 (11)C1C—C8C1.475 (13)
C1A—H1A0.9800C1C—H1C0.9800
C2A—C3A1.495 (14)C2C—C3C1.461 (12)
C2A—H2A0.9800C2C—H2C0.9800
C3A—C4A1.292 (14)C3C—C4C1.327 (12)
C3A—H3A0.9300C3C—H3C0.9300
C4A—C5A1.443 (14)C4C—C5C1.438 (13)
C4A—H4A0.9300C4C—H4C0.9300
C5A—C6A1.395 (12)C5C—C6C1.428 (12)
C5A—H5A0.9800C5C—H5C0.9800
C6A—C7A1.486 (12)C6C—C7C1.492 (12)
C6A—H6A0.9800C6C—H6C0.9800
C7A—C8A1.280 (11)C7C—C8C1.300 (12)
C7A—H7A0.9300C7C—H7C0.9300
C8A—H8A0.9300C8C—H8C0.9300
C9A—C14A1.376 (12)C9C—C14C1.387 (12)
C9A—C10A1.376 (10)C9C—C10C1.399 (11)
C10A—C11A1.389 (11)C10C—C11C1.412 (13)
C10A—H10A0.9300C10C—H10C0.9300
C11A—C12A1.359 (13)C11C—C12C1.366 (14)
C11A—H11A0.9300C11C—H11C0.9300
C12A—C13A1.353 (14)C12C—C13C1.353 (12)
C12A—H12A0.9300C12C—H12C0.9300
C13A—C14A1.361 (12)C13C—C14C1.351 (11)
C13A—H13A0.9300C13C—H13C0.9300
C14A—H14A0.9300C14C—H14C0.9300
Pt2—C9B1.998 (7)Pt4—C9D2.010 (8)
Pt2—C6B2.114 (8)Pt4—C5D2.121 (8)
Pt2—C5B2.118 (8)Pt4—C6D2.141 (9)
Pt2—C2B2.316 (8)Pt4—Cl42.307 (2)
Pt2—Cl22.338 (2)Pt4—C2D2.311 (9)
Pt2—C1B2.343 (8)Pt4—C1D2.316 (9)
C1B—C2B1.363 (12)C1D—C2D1.355 (12)
C1B—C8B1.466 (12)C1D—C8D1.473 (13)
C1B—H1B0.9800C1D—H1D0.9800
C2B—C3B1.481 (12)C2D—C3D1.468 (14)
C2B—H2B0.9800C2D—H2D0.9800
C3B—C4B1.300 (11)C3D—C4D1.289 (16)
C3B—H3B0.9300C3D—H3D0.9300
C4B—C5B1.470 (11)C4D—C5D1.486 (16)
C4B—H4B0.9300C4D—H4D0.9300
C5B—C6B1.398 (11)C5D—C6D1.390 (13)
C5B—H5B0.9800C5D—H5D0.9800
C6B—C7B1.453 (11)C6D—C7D1.464 (14)
C6B—H6B0.9800C6D—H6D0.9800
C7B—C8B1.291 (11)C7D—C8D1.325 (13)
C7B—H7B0.9300C7D—H7D0.9300
C8B—H8B0.9300C8D—H8D0.9300
C9B—C14B1.368 (11)C9D—C14D1.378 (11)
C9B—C10B1.390 (11)C9D—C10D1.411 (11)
C10B—C11B1.378 (11)C10D—C11D1.377 (12)
C10B—H10B0.9300C10D—H10D0.9300
C11B—C12B1.362 (13)C11D—C12D1.354 (12)
C11B—H11B0.9300C11D—H11D0.9300
C12B—C13B1.365 (13)C12D—C13D1.370 (13)
C12B—H12B0.9300C12D—H12D0.9300
C13B—C14B1.388 (11)C13D—C14D1.377 (13)
C13B—H13B0.9300C13D—H13D0.9300
C14B—H14B0.9300C14D—H14D0.9300
C9A—Pt1—C6A91.4 (3)C9C—Pt3—C5C91.4 (4)
C9A—Pt1—C5A91.6 (4)C9C—Pt3—C6C92.1 (4)
C6A—Pt1—C5A38.4 (3)C5C—Pt3—C6C39.2 (3)
C9A—Pt1—Cl189.0 (2)C9C—Pt3—C2C162.1 (3)
C6A—Pt1—Cl1160.3 (3)C5C—Pt3—C2C79.6 (3)
C5A—Pt1—Cl1161.2 (3)C6C—Pt3—C2C90.6 (3)
C9A—Pt1—C2A163.3 (4)C9C—Pt3—Cl389.0 (2)
C6A—Pt1—C2A91.7 (4)C5C—Pt3—Cl3160.1 (3)
C5A—Pt1—C2A80.7 (4)C6C—Pt3—Cl3160.7 (3)
Cl1—Pt1—C2A93.6 (3)C2C—Pt3—Cl394.2 (2)
C9A—Pt1—C1A162.5 (3)C9C—Pt3—C1C163.5 (4)
C6A—Pt1—C1A80.3 (3)C5C—Pt3—C1C91.4 (4)
C5A—Pt1—C1A91.3 (3)C6C—Pt3—C1C79.9 (4)
Cl1—Pt1—C1A93.7 (2)C2C—Pt3—C1C33.8 (3)
C2A—Pt1—C1A33.8 (3)Cl3—Pt3—C1C93.9 (3)
C2A—C1A—C8A123.1 (9)C2C—C1C—C8C122.2 (10)
C2A—C1A—Pt172.8 (5)C2C—C1C—Pt372.6 (5)
C8A—C1A—Pt1103.3 (5)C8C—C1C—Pt3104.1 (6)
C2A—C1A—H1A116.0C2C—C1C—H1C116.2
C8A—C1A—H1A116.0C8C—C1C—H1C116.2
Pt1—C1A—H1A116.0Pt3—C1C—H1C116.2
C1A—C2A—C3A123.0 (9)C1C—C2C—C3C124.7 (9)
C1A—C2A—Pt173.4 (5)C1C—C2C—Pt373.6 (6)
C3A—C2A—Pt1101.0 (6)C3C—C2C—Pt3103.5 (6)
C1A—C2A—H2A116.3C1C—C2C—H2C115.2
C3A—C2A—H2A116.3C3C—C2C—H2C115.2
Pt1—C2A—H2A116.3Pt3—C2C—H2C115.2
C4A—C3A—C2A123.6 (10)C4C—C3C—C2C121.5 (9)
C4A—C3A—H3A118.2C4C—C3C—H3C119.2
C2A—C3A—H3A118.2C2C—C3C—H3C119.2
C3A—C4A—C5A122.0 (10)C3C—C4C—C5C122.1 (9)
C3A—C4A—H4A119.0C3C—C4C—H4C119.0
C5A—C4A—H4A119.0C5C—C4C—H4C119.0
C6A—C5A—C4A124.6 (9)C6C—C5C—C4C121.9 (9)
C6A—C5A—Pt170.2 (5)C6C—C5C—Pt370.6 (5)
C4A—C5A—Pt1108.9 (7)C4C—C5C—Pt3110.3 (6)
C6A—C5A—H5A114.7C6C—C5C—H5C115.3
C4A—C5A—H5A114.7C4C—C5C—H5C115.3
Pt1—C5A—H5A114.7Pt3—C5C—H5C115.3
C5A—C6A—C7A122.0 (10)C5C—C6C—C7C123.6 (9)
C5A—C6A—Pt171.4 (5)C5C—C6C—Pt370.2 (4)
C7A—C6A—Pt1108.3 (6)C7C—C6C—Pt3108.7 (6)
C5A—C6A—H6A115.5C5C—C6C—H6C115.1
C7A—C6A—H6A115.5C7C—C6C—H6C115.1
Pt1—C6A—H6A115.5Pt3—C6C—H6C115.1
C8A—C7A—C6A123.0 (9)C8C—C7C—C6C122.8 (9)
C8A—C7A—H7A118.5C8C—C7C—H7C118.6
C6A—C7A—H7A118.5C6C—C7C—H7C118.6
C7A—C8A—C1A122.4 (9)C7C—C8C—C1C121.3 (9)
C7A—C8A—H8A118.8C7C—C8C—H8C119.4
C1A—C8A—H8A118.8C1C—C8C—H8C119.4
C14A—C9A—C10A117.4 (8)C14C—C9C—C10C118.2 (9)
C14A—C9A—Pt1120.6 (6)C14C—C9C—Pt3121.2 (6)
C10A—C9A—Pt1121.9 (7)C10C—C9C—Pt3120.5 (7)
C9A—C10A—C11A120.3 (9)C9C—C10C—C11C119.2 (10)
C9A—C10A—H10A119.8C9C—C10C—H10C120.4
C11A—C10A—H10A119.8C11C—C10C—H10C120.4
C12A—C11A—C10A120.7 (9)C12C—C11C—C10C119.5 (9)
C12A—C11A—H11A119.7C12C—C11C—H11C120.2
C10A—C11A—H11A119.7C10C—C11C—H11C120.2
C13A—C12A—C11A119.1 (9)C13C—C12C—C11C120.8 (10)
C13A—C12A—H12A120.5C13C—C12C—H12C119.6
C11A—C12A—H12A120.5C11C—C12C—H12C119.6
C12A—C13A—C14A120.9 (11)C14C—C13C—C12C120.7 (10)
C12A—C13A—H13A119.6C14C—C13C—H13C119.6
C14A—C13A—H13A119.6C12C—C13C—H13C119.6
C13A—C14A—C9A121.6 (10)C13C—C14C—C9C121.5 (8)
C13A—C14A—H14A119.2C13C—C14C—H14C119.2
C9A—C14A—H14A119.2C9C—C14C—H14C119.2
C9B—Pt2—C6B92.5 (3)C9D—Pt4—C5D92.7 (4)
C9B—Pt2—C5B90.3 (3)C9D—Pt4—C6D91.5 (4)
C6B—Pt2—C5B38.6 (3)C5D—Pt4—C6D38.1 (3)
C9B—Pt2—C2B160.3 (3)C9D—Pt4—Cl489.8 (2)
C6B—Pt2—C2B90.6 (3)C5D—Pt4—Cl4162.1 (3)
C5B—Pt2—C2B80.1 (3)C6D—Pt4—Cl4159.6 (3)
C9B—Pt2—Cl289.0 (2)C9D—Pt4—C2D164.8 (4)
C6B—Pt2—Cl2159.9 (2)C5D—Pt4—C2D80.8 (4)
C5B—Pt2—Cl2161.5 (3)C6D—Pt4—C2D91.7 (4)
C2B—Pt2—Cl294.8 (2)Cl4—Pt4—C2D92.4 (3)
C9B—Pt2—C1B164.9 (4)C9D—Pt4—C1D160.9 (4)
C6B—Pt2—C1B79.3 (3)C5D—Pt4—C1D91.1 (4)
C5B—Pt2—C1B91.0 (3)C6D—Pt4—C1D80.0 (4)
C2B—Pt2—C1B34.0 (3)Cl4—Pt4—C1D92.4 (3)
Cl2—Pt2—C1B94.5 (2)C2D—Pt4—C1D34.1 (3)
C2B—C1B—C8B122.7 (8)C2D—C1D—C8D123.5 (10)
C2B—C1B—Pt271.9 (5)C2D—C1D—Pt472.8 (6)
C8B—C1B—Pt2103.4 (6)C8D—C1D—Pt4104.1 (6)
C2B—C1B—H1B116.3C2D—C1D—H1D115.7
C8B—C1B—H1B116.3C8D—C1D—H1D115.7
Pt2—C1B—H1B116.3Pt4—C1D—H1D115.7
C1B—C2B—C3B124.3 (9)C1D—C2D—C3D122.4 (10)
C1B—C2B—Pt274.1 (5)C1D—C2D—Pt473.2 (5)
C3B—C2B—Pt2104.0 (5)C3D—C2D—Pt4103.9 (7)
C1B—C2B—H2B115.2C1D—C2D—H2D116.0
C3B—C2B—H2B115.2C3D—C2D—H2D116.0
Pt2—C2B—H2B115.2Pt4—C2D—H2D116.0
C4B—C3B—C2B120.1 (8)C4D—C3D—C2D120.7 (11)
C4B—C3B—H3B120.0C4D—C3D—H3D119.6
C2B—C3B—H3B120.0C2D—C3D—H3D119.6
C3B—C4B—C5B123.6 (8)C3D—C4D—C5D124.2 (11)
C3B—C4B—H4B118.2C3D—C4D—H4D117.9
C5B—C4B—H4B118.2C5D—C4D—H4D117.9
C6B—C5B—C4B122.9 (8)C6D—C5D—C4D122.9 (11)
C6B—C5B—Pt270.6 (5)C6D—C5D—Pt471.7 (5)
C4B—C5B—Pt2108.7 (6)C4D—C5D—Pt4107.1 (8)
C6B—C5B—H5B115.3C6D—C5D—H5D115.4
C4B—C5B—H5B115.3C4D—C5D—H5D115.4
Pt2—C5B—H5B115.3Pt4—C5D—H5D115.4
C5B—C6B—C7B122.3 (8)C5D—C6D—C7D124.5 (11)
C5B—C6B—Pt270.8 (5)C5D—C6D—Pt470.2 (5)
C7B—C6B—Pt2110.1 (6)C7D—C6D—Pt4109.2 (7)
C5B—C6B—H6B115.1C5D—C6D—H6D114.7
C7B—C6B—H6B115.1C7D—C6D—H6D114.7
Pt2—C6B—H6B115.1Pt4—C6D—H6D114.7
C8B—C7B—C6B123.1 (9)C8D—C7D—C6D121.5 (11)
C8B—C7B—H7B118.5C8D—C7D—H7D119.2
C6B—C7B—H7B118.5C6D—C7D—H7D119.2
C7B—C8B—C1B121.5 (9)C7D—C8D—C1D121.7 (10)
C7B—C8B—H8B119.2C7D—C8D—H8D119.1
C1B—C8B—H8B119.2C1D—C8D—H8D119.1
C14B—C9B—C10B116.8 (8)C14D—C9D—C10D117.3 (8)
C14B—C9B—Pt2124.0 (7)C14D—C9D—Pt4120.2 (7)
C10B—C9B—Pt2119.3 (6)C10D—C9D—Pt4122.5 (7)
C11B—C10B—C9B121.3 (9)C11D—C10D—C9D120.6 (9)
C11B—C10B—H10B119.4C11D—C10D—H10D119.7
C9B—C10B—H10B119.4C9D—C10D—H10D119.7
C12B—C11B—C10B120.8 (10)C12D—C11D—C10D120.7 (10)
C12B—C11B—H11B119.6C12D—C11D—H11D119.6
C10B—C11B—H11B119.6C10D—C11D—H11D119.6
C11B—C12B—C13B119.1 (9)C11D—C12D—C13D119.6 (10)
C11B—C12B—H12B120.5C11D—C12D—H12D120.2
C13B—C12B—H12B120.5C13D—C12D—H12D120.2
C12B—C13B—C14B120.0 (10)C12D—C13D—C14D120.8 (10)
C12B—C13B—H13B120.0C12D—C13D—H13D119.6
C14B—C13B—H13B120.0C14D—C13D—H13D119.6
C9B—C14B—C13B122.0 (9)C13D—C14D—C9D120.9 (9)
C9B—C14B—H14B119.0C13D—C14D—H14D119.5
C13B—C14B—H14B119.0C9D—C14D—H14D119.5
C9A—Pt1—C1A—C2A170.6 (9)C9C—Pt3—C2C—C1C−169.4 (9)
C6A—Pt1—C1A—C2A108.0 (6)C5C—Pt3—C2C—C1C−108.5 (6)
C5A—Pt1—C1A—C2A71.1 (6)C6C—Pt3—C2C—C1C−70.6 (6)
Cl1—Pt1—C1A—C2A−90.8 (6)Cl3—Pt3—C2C—C1C90.6 (6)
C9A—Pt1—C1A—C8A49.7 (13)C9C—Pt3—C2C—C3C−46.7 (13)
C6A—Pt1—C1A—C8A−13.0 (6)C5C—Pt3—C2C—C3C14.2 (6)
C5A—Pt1—C1A—C8A−49.9 (7)C6C—Pt3—C2C—C3C52.0 (6)
Cl1—Pt1—C1A—C8A148.2 (6)Cl3—Pt3—C2C—C3C−146.7 (6)
C2A—Pt1—C1A—C8A−121.0 (9)C1C—Pt3—C2C—C3C122.7 (9)
C8A—C1A—C2A—C3A2.4 (14)C1C—C2C—C3C—C4C66.0 (14)
Pt1—C1A—C2A—C3A−92.5 (9)Pt3—C2C—C3C—C4C−13.3 (11)
C8A—C1A—C2A—Pt194.9 (8)C2C—C3C—C4C—C5C2.1 (15)
C9A—Pt1—C2A—C1A−170.2 (9)C3C—C4C—C5C—C6C−67.2 (12)
C6A—Pt1—C2A—C1A−69.7 (6)C3C—C4C—C5C—Pt312.0 (12)
C5A—Pt1—C2A—C1A−106.6 (6)C9C—Pt3—C5C—C6C−91.6 (6)
Cl1—Pt1—C2A—C1A91.4 (5)C2C—Pt3—C5C—C6C104.0 (6)
C9A—Pt1—C2A—C3A−48.8 (14)Cl3—Pt3—C5C—C6C177.5 (6)
C6A—Pt1—C2A—C3A51.8 (7)C1C—Pt3—C5C—C6C72.2 (6)
C5A—Pt1—C2A—C3A14.8 (7)C9C—Pt3—C5C—C4C150.6 (7)
Cl1—Pt1—C2A—C3A−147.2 (6)C6C—Pt3—C5C—C4C−117.9 (9)
C1A—Pt1—C2A—C3A121.4 (9)C2C—Pt3—C5C—C4C−13.9 (7)
C1A—C2A—C3A—C4A64.9 (15)Cl3—Pt3—C5C—C4C59.6 (11)
Pt1—C2A—C3A—C4A−12.4 (13)C1C—Pt3—C5C—C4C−45.7 (7)
C2A—C3A—C4A—C5A−1.1 (18)C4C—C5C—C6C—C7C2.5 (13)
C3A—C4A—C5A—C6A−62.9 (15)Pt3—C5C—C6C—C7C−99.8 (8)
C3A—C4A—C5A—Pt115.7 (13)C4C—C5C—C6C—Pt3102.3 (8)
C9A—Pt1—C5A—C6A−90.3 (6)C9C—Pt3—C6C—C5C89.7 (6)
Cl1—Pt1—C5A—C6A178.2 (6)C2C—Pt3—C6C—C5C−72.7 (6)
C2A—Pt1—C5A—C6A104.7 (6)Cl3—Pt3—C6C—C5C−177.4 (6)
C1A—Pt1—C5A—C6A72.4 (6)C1C—Pt3—C6C—C5C−104.8 (6)
C9A—Pt1—C5A—C4A148.8 (7)C9C—Pt3—C6C—C7C−150.4 (7)
C6A—Pt1—C5A—C4A−120.9 (10)C5C—Pt3—C6C—C7C119.9 (9)
Cl1—Pt1—C5A—C4A57.2 (12)C2C—Pt3—C6C—C7C47.2 (7)
C2A—Pt1—C5A—C4A−16.3 (7)Cl3—Pt3—C6C—C7C−57.5 (12)
C1A—Pt1—C5A—C4A−48.5 (7)C1C—Pt3—C6C—C7C15.0 (7)
C4A—C5A—C6A—C7A−0.6 (14)C5C—C6C—C7C—C8C61.6 (14)
Pt1—C5A—C6A—C7A−100.4 (8)Pt3—C6C—C7C—C8C−16.6 (12)
C4A—C5A—C6A—Pt199.9 (9)C6C—C7C—C8C—C1C4.4 (16)
C9A—Pt1—C6A—C5A90.7 (6)C2C—C1C—C8C—C7C−69.1 (14)
Cl1—Pt1—C6A—C5A−178.3 (6)Pt3—C1C—C8C—C7C9.0 (12)
C2A—Pt1—C6A—C5A−72.8 (6)C5C—Pt3—C9C—C14C104.0 (8)
C1A—Pt1—C6A—C5A−104.7 (6)C6C—Pt3—C9C—C14C64.8 (8)
C9A—Pt1—C6A—C7A−150.8 (7)C2C—Pt3—C9C—C14C163.3 (9)
C5A—Pt1—C6A—C7A118.5 (10)Cl3—Pt3—C9C—C14C−95.9 (7)
Cl1—Pt1—C6A—C7A−59.8 (12)C1C—Pt3—C9C—C14C4.4 (17)
C2A—Pt1—C6A—C7A45.7 (7)C5C—Pt3—C9C—C10C−72.6 (7)
C1A—Pt1—C6A—C7A13.7 (7)C6C—Pt3—C9C—C10C−111.8 (8)
C5A—C6A—C7A—C8A65.0 (14)C2C—Pt3—C9C—C10C−13.3 (15)
Pt1—C6A—C7A—C8A−14.0 (13)Cl3—Pt3—C9C—C10C87.5 (7)
C6A—C7A—C8A—C1A1.7 (17)C1C—Pt3—C9C—C10C−172.2 (10)
C2A—C1A—C8A—C7A−67.7 (14)C14C—C9C—C10C—C11C1.4 (14)
Pt1—C1A—C8A—C7A10.2 (12)Pt3—C9C—C10C—C11C178.2 (7)
C6A—Pt1—C9A—C14A84.4 (7)C9C—C10C—C11C—C12C−0.9 (15)
C5A—Pt1—C9A—C14A122.8 (7)C10C—C11C—C12C—C13C0.2 (16)
Cl1—Pt1—C9A—C14A−76.0 (7)C11C—C12C—C13C—C14C0.0 (15)
C2A—Pt1—C9A—C14A−175.0 (10)C12C—C13C—C14C—C9C0.5 (15)
C1A—Pt1—C9A—C14A23.3 (14)C10C—C9C—C14C—C13C−1.2 (14)
C6A—Pt1—C9A—C10A−97.3 (7)Pt3—C9C—C14C—C13C−178.0 (7)
C5A—Pt1—C9A—C10A−58.9 (7)C9D—Pt4—C1D—C2D173.1 (8)
Cl1—Pt1—C9A—C10A102.4 (6)C5D—Pt4—C1D—C2D71.6 (7)
C2A—Pt1—C9A—C10A3.3 (15)C6D—Pt4—C1D—C2D108.2 (7)
C1A—Pt1—C9A—C10A−158.4 (9)Cl4—Pt4—C1D—C2D−90.8 (6)
C14A—C9A—C10A—C11A1.0 (12)C9D—Pt4—C1D—C8D51.8 (13)
Pt1—C9A—C10A—C11A−177.4 (6)C5D—Pt4—C1D—C8D−49.6 (7)
C9A—C10A—C11A—C12A−1.2 (13)C6D—Pt4—C1D—C8D−13.0 (7)
C10A—C11A—C12A—C13A1.3 (15)Cl4—Pt4—C1D—C8D147.9 (6)
C11A—C12A—C13A—C14A−1.4 (16)C2D—Pt4—C1D—C8D−121.2 (10)
C12A—C13A—C14A—C9A1.3 (16)C8D—C1D—C2D—C3D−0.2 (16)
C10A—C9A—C14A—C13A−1.1 (14)Pt4—C1D—C2D—C3D−96.0 (10)
Pt1—C9A—C14A—C13A177.3 (8)C8D—C1D—C2D—Pt495.8 (9)
C9B—Pt2—C1B—C2B165.5 (10)C9D—Pt4—C2D—C1D−171.3 (10)
C6B—Pt2—C1B—C2B107.4 (6)C5D—Pt4—C2D—C1D−106.0 (7)
C5B—Pt2—C1B—C2B70.4 (6)C6D—Pt4—C2D—C1D−69.4 (7)
Cl2—Pt2—C1B—C2B−91.9 (5)Cl4—Pt4—C2D—C1D90.6 (6)
C9B—Pt2—C1B—C8B45.1 (15)C9D—Pt4—C2D—C3D−51.2 (16)
C6B—Pt2—C1B—C8B−13.0 (6)C5D—Pt4—C2D—C3D14.1 (8)
C5B—Pt2—C1B—C8B−50.0 (6)C6D—Pt4—C2D—C3D50.8 (8)
C2B—Pt2—C1B—C8B−120.4 (8)Cl4—Pt4—C2D—C3D−149.2 (7)
Cl2—Pt2—C1B—C8B147.7 (6)C1D—Pt4—C2D—C3D120.1 (11)
C8B—C1B—C2B—C3B−1.8 (13)C1D—C2D—C3D—C4D68.0 (17)
Pt2—C1B—C2B—C3B−96.3 (8)Pt4—C2D—C3D—C4D−10.7 (15)
C8B—C1B—C2B—Pt294.5 (8)C2D—C3D—C4D—C5D−3(2)
C9B—Pt2—C2B—C1B−168.8 (9)C3D—C4D—C5D—C6D−63.2 (18)
C6B—Pt2—C2B—C1B−69.7 (6)C3D—C4D—C5D—Pt415.7 (17)
C5B—Pt2—C2B—C1B−107.0 (6)C9D—Pt4—C5D—C6D−89.1 (7)
Cl2—Pt2—C2B—C1B90.9 (5)Cl4—Pt4—C5D—C6D173.5 (8)
C9B—Pt2—C2B—C3B−46.6 (13)C2D—Pt4—C5D—C6D104.8 (7)
C6B—Pt2—C2B—C3B52.5 (6)C1D—Pt4—C5D—C6D72.2 (7)
C5B—Pt2—C2B—C3B15.2 (6)C9D—Pt4—C5D—C4D151.1 (8)
Cl2—Pt2—C2B—C3B−146.9 (6)C6D—Pt4—C5D—C4D−119.8 (11)
C1B—Pt2—C2B—C3B122.2 (9)Cl4—Pt4—C5D—C4D53.7 (15)
C1B—C2B—C3B—C4B67.3 (12)C2D—Pt4—C5D—C4D−15.0 (8)
Pt2—C2B—C3B—C4B−12.8 (11)C1D—Pt4—C5D—C4D−47.6 (8)
C2B—C3B—C4B—C5B−0.4 (15)C4D—C5D—C6D—C7D−1.2 (16)
C3B—C4B—C5B—C6B−63.6 (13)Pt4—C5D—C6D—C7D−100.1 (10)
C3B—C4B—C5B—Pt214.8 (12)C4D—C5D—C6D—Pt498.9 (10)
C9B—Pt2—C5B—C6B−93.5 (5)C9D—Pt4—C6D—C5D92.4 (7)
C2B—Pt2—C5B—C6B103.8 (5)Cl4—Pt4—C6D—C5D−174.2 (7)
Cl2—Pt2—C5B—C6B178.8 (5)C2D—Pt4—C6D—C5D−72.7 (7)
C1B—Pt2—C5B—C6B71.4 (5)C1D—Pt4—C6D—C5D−104.9 (7)
C9B—Pt2—C5B—C4B147.2 (7)C9D—Pt4—C6D—C7D−146.8 (8)
C6B—Pt2—C5B—C4B−119.3 (9)C5D—Pt4—C6D—C7D120.8 (12)
C2B—Pt2—C5B—C4B−15.5 (6)Cl4—Pt4—C6D—C7D−53.5 (15)
Cl2—Pt2—C5B—C4B59.5 (11)C2D—Pt4—C6D—C7D48.1 (8)
C1B—Pt2—C5B—C4B−47.9 (7)C1D—Pt4—C6D—C7D15.9 (8)
C4B—C5B—C6B—C7B−2.0 (13)C5D—C6D—C7D—C8D60.8 (14)
Pt2—C5B—C6B—C7B−102.2 (8)Pt4—C6D—C7D—C8D−17.9 (13)
C4B—C5B—C6B—Pt2100.2 (8)C6D—C7D—C8D—C1D6.0 (16)
C9B—Pt2—C6B—C5B87.4 (5)C2D—C1D—C8D—C7D−70.3 (14)
C2B—Pt2—C6B—C5B−73.1 (5)Pt4—C1D—C8D—C7D8.2 (12)
Cl2—Pt2—C6B—C5B−178.9 (5)C5D—Pt4—C9D—C14D126.8 (7)
C1B—Pt2—C6B—C5B−105.4 (5)C6D—Pt4—C9D—C14D88.7 (7)
C9B—Pt2—C6B—C7B−154.2 (6)Cl4—Pt4—C9D—C14D−70.9 (7)
C5B—Pt2—C6B—C7B118.4 (8)C2D—Pt4—C9D—C14D−169.3 (11)
C2B—Pt2—C6B—C7B45.3 (6)C1D—Pt4—C9D—C14D25.6 (14)
Cl2—Pt2—C6B—C7B−60.5 (10)C5D—Pt4—C9D—C10D−53.9 (7)
C1B—Pt2—C6B—C7B13.0 (6)C6D—Pt4—C9D—C10D−92.0 (7)
C5B—C6B—C7B—C8B67.7 (12)Cl4—Pt4—C9D—C10D108.4 (6)
Pt2—C6B—C7B—C8B−11.9 (11)C2D—Pt4—C9D—C10D10.0 (16)
C6B—C7B—C8B—C1B−1.1 (15)C1D—Pt4—C9D—C10D−155.1 (9)
C2B—C1B—C8B—C7B−65.2 (13)C14D—C9D—C10D—C11D−1.0 (12)
Pt2—C1B—C8B—C7B11.7 (11)Pt4—C9D—C10D—C11D179.7 (6)
C6B—Pt2—C9B—C14B50.4 (7)C9D—C10D—C11D—C12D0.5 (13)
C5B—Pt2—C9B—C14B88.9 (7)C10D—C11D—C12D—C13D0.8 (14)
C2B—Pt2—C9B—C14B149.2 (9)C11D—C12D—C13D—C14D−1.5 (16)
Cl2—Pt2—C9B—C14B−109.6 (7)C12D—C13D—C14D—C9D0.9 (16)
C1B—Pt2—C9B—C14B−6.2 (17)C10D—C9D—C14D—C13D0.3 (13)
C6B—Pt2—C9B—C10B−127.9 (7)Pt4—C9D—C14D—C13D179.6 (7)
C5B—Pt2—C9B—C10B−89.3 (7)C1A—C2A—C5A—C6A1.1 (8)
C2B—Pt2—C9B—C10B−29.1 (13)C3A—C4A—C7A—C8A−0.1 (9)
Cl2—Pt2—C9B—C10B72.2 (6)C3A—C2A—C1A—C8A2.4 (14)
C1B—Pt2—C9B—C10B175.5 (10)C4A—C5A—C6A—C7A−0.6 (14)
C14B—C9B—C10B—C11B−2.0 (12)C2A—C3A—C4A—C5A−1.1 (18)
Pt2—C9B—C10B—C11B176.3 (7)C6A—C7A—C8A—C1A1.7 (17)
C9B—C10B—C11B—C12B0.8 (14)C1B—C2B—C5B—C6B0.5 (7)
C10B—C11B—C12B—C13B0.2 (15)C3B—C4B—C7B—C8B0.5 (8)
C11B—C12B—C13B—C14B0.1 (14)C3B—C2B—C1B—C8B−1.8 (13)
C10B—C9B—C14B—C13B2.4 (13)C4B—C5B—C6B—C7B−2.0 (13)
Pt2—C9B—C14B—C13B−175.9 (6)C2B—C3B—C4B—C5B−0.4 (15)
C12B—C13B—C14B—C9B−1.5 (14)C6B—C7B—C8B—C1B−1.1 (15)
C9C—Pt3—C1C—C2C168.5 (10)C1C—C2C—C5C—C6C−0.7 (8)
C5C—Pt3—C1C—C2C68.9 (6)C3C—C4C—C7C—C8C−1.2 (8)
C6C—Pt3—C1C—C2C106.6 (6)C3C—C2C—C1C—C8C0.7 (15)
Cl3—Pt3—C1C—C2C−91.8 (6)C4C—C5C—C6C—C7C2.5 (13)
C9C—Pt3—C1C—C8C48.8 (16)C2C—C3C—C4C—C5C2.1 (15)
C5C—Pt3—C1C—C8C−50.9 (7)C6C—C7C—C8C—C1C4.4 (16)
C6C—Pt3—C1C—C8C−13.2 (7)C1D—C2D—C5D—C6D0.3 (8)
C2C—Pt3—C1C—C8C−119.8 (10)C3D—C4D—C7D—C8D−0.6 (10)
Cl3—Pt3—C1C—C8C148.4 (6)C3D—C2D—C1D—C8D−0.2 (16)
C8C—C1C—C2C—C3C0.7 (15)C4D—C5D—C6D—C7D−1.2 (16)
Pt3—C1C—C2C—C3C−95.3 (9)C2D—C3D—C4D—C5D−3(2)
C8C—C1C—C2C—Pt396.0 (9)C6D—C7D—C8D—C1D6.0 (16)
Table 1
Comparison of Pt—ligand bond lengths (Å) in the four molecules within the asymmetric unit top
Pt—LigandABCD
Pt—Cl2.304 (2)2.338 (2)2.329 (2)2.307 (2)
Pt—C12.329 (8)2.343 (8)2.340 (8)2.316 (9)
Pt—C22.321 (8)2.316 (8)2.327 (9)2.311 (9)
Pt—C52.127 (8)2.118 (8)2.125 (8)2.121 (8)
Pt—C62.113 (8)2.114 (8)2.130 (7)2.141 (9)
Pt—C92.009 (8)1.998 (7)2.025 (9)2.010 (8)
Acknowledgements top

This study received financial support from Chonnam National University in 2006.

references
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