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Acta Cryst. (2007). E63, m2233 [ doi:10.1107/S1600536807034277 ]
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2-trans-1,2-di-4-pyridylethylene]hexa-2-oxido-nickel(II)divanadate(V)]Abstract: The structure of the title compound, [NiV2O6(C12H10N2)]n, is composed of corner-sharing [V2O6]2- chains along the c axis, with the [Ni(bpe)]2+ (bpe = trans-1,2-di-4-pyridylethylene) units covalently attached to every V site through O atoms. The Ni atom is octahedrally coordinated by two pyridyl N atoms from two different bpe ligands, and four O atoms from four different VO4 tetrahedra. All the C and H atoms are disordered over two positions each; the site occupancy factors are ca 0.55 and 0.45.
Online 31 July 2007
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