Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807032904/hj3046sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807032904/hj3046Isup2.hkl |
CCDC reference: 657567
Key indicators
- Single-crystal X-ray study
- T = 173 K
- Mean (C-C) = 0.004 Å
- Disorder in solvent or counterion
- R factor = 0.024
- wR factor = 0.062
- Data-to-parameter ratio = 14.4
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 0.50 Ratio PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.97 PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent ..... ? PLAT180_ALERT_3_C Check Cell Rounding: # of Values Ending with 0 = 3 PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 50.00 Perc. PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 4
Alert level G FORMU01_ALERT_1_G There is a discrepancy between the atom counts in the _chemical_formula_sum and _chemical_formula_moiety. This is usually due to the moiety formula being in the wrong format. Atom count from _chemical_formula_sum: C12 H18 La1 N3 Ni1 O13 Atom count from _chemical_formula_moiety:C800 H1002 La200 N400 Ni200 PLAT793_ALERT_1_G Check the Absolute Configuration of N1 = ... R PLAT860_ALERT_3_G Note: Number of Least-Squares Restraints ....... 6
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 8 ALERT level C = Check and explain 3 ALERT level G = General alerts; check 6 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check
Iminodiacetic acid (0.399 g, 3.0 mmol), nickel nitrate hexahydrate (0.436 g, 1.50 mmol) and lanthanum trichloride monohydrate (0.407 g, 1.0 mmol) were dissolved in water (15 ml). Aqueous sodium hydroxide (1 M) was added to the solution to a pH of approximately 5.5. The mixtue was placed din a 25-ml, Teflon-lined, stainless-steel Parr bomb. The bomb was heated to 453 K for 8 h. It was cooled to 373 K at 20 K h-1 and then kept at this temperature of 3 h before being allowed to cool to room temperate at 3 K h-1. Blue needle-shaped crystals were obtained in 70% yield (based on iminodiacetic acid. CH&N elemental analysis. Calc. for C12H18LaN3NiO13: Found: C 23.63, N 6.89, H, 2.97%. Found: C 23.45, N, 6.82, H 3.10%.
The water molecule was allowed to refine off the twofold rotation axis, and its anisotropic temperature factors were restrained to be nearly isotropic. An examination of hydrogen bonding interactions suggested that one of its H-atoms occupies the symmetry-related site of the water O-atom and would then not hydrogen bond to an acceptor. The other should be linked to an acceptor. The positions of the two were then set manually. The two H-atoms were not refined.
Carbon- and nitrogen-bound H-atoms were positioned geometrically (C–H 0.93 and 0.97 Å; N–H 0.88 Å), and were included in the refinement in the riding model approximation, with Uiso(H) = 1.2Ueq(C).
The final difference Fourier map had a large peak at 0.85 Å from La1 but was otherwise featureless.
The iminodiacetate [-O(O)CCH2NHCH2C(O)O-] dianion forms a large number of crystalline metal derivatives in which it O,N,O'-chelates to the metal. These studies have largely addressed compounds having one type of metal only; diaquadi(iminodiacetato)calciumcobalt tetrahydrate (Kuz'menko et al., 1992) and diaquadi(iminodiacetato)cadmiumcobalt (Long et al., 2003) represent unusual examples of heterometallic systems. The two compound adopt layer structures. A series of lanthanum/copper complexes is known that exhibit porosity; the three-dimensional network is also thermally stable when lattice molecules are removed (Ren et al., 2003a,b). Another series of lanthanum/copper complexes, [LnCu6(OH)3(C4H6NO4)2(C4H5NO4)4].(ClO4)2.25H2O, features antiferromagnetic Ln–Cu interactions as the rare earth atom is surrounded by six copper atoms at a distance of approximately 3.5 Å (Liu et al., 2003).
The present study extends an earlier study on a metal derivative of iminodiacetic acid that features both d- and f-block elements within the same framework. The hydrothermal reaction of lanthanum nitrate, nickel nitrate and iminodiacetic acid gave a gigantic metal cluster consisting of 20 lanthanum and 30 nickel atoms in the formula unit, [La20Ni30(C4H5NO4)30(CO3)6(NO3)6(OH)30(H2O)12](CO3)6.72H2O (Kong et al., 2007). Changing the lanthanum nitrate reactant to lanthanum chloride yielded the title compound, which has only one of each metal atom in formula unit. In [(C4H5NO4)2(C4H6NO4)LaNi.H2O]n (Fig. 1), two deprotonated iminodiacetate dianions each chelate to the nickel atom, the three chelating atoms occupying fac positions of the octahedral geometry of nickel, a feature that is also found in diaqua(iminodiacetato)nickel (Wu et al., 2003). Meanwhile, the iminodiacetate monoanion, which lies about a twofold rotation axis, O,O'-chelates to the water-coordinated lanthanum atom. One of the two oxygen atoms is additionally involved in bridging to another lanthanum atom, so that the geometry of the f-block metal is a ten-coordinate bicapped square antiprism (Fig. 2) in the layer structure. Hydrogen bonds link the layers into a three-dimensional network motif.
The somewhat uncommon iminodiacetate monoanion has also been found in other rare-earth complexes such as the neodymium (Albertsson & Oskarsson, 1968) praseodymium (Albertsson & Oskarsson, 1974; Li et al., 1999), uranium (Bombieri et al., 1974), yttrium (Li et al., 1997) and lanthanum complexes. The lanthanum complex is also a heterometallic compound having lanthanum and zinc bridged into a linear chain (Xu et al., 2004).
Heterometallic derivatives of iminodiacetic acid are exemplified by diaquabis(iminodiacetato)calciumcobalt tetrahydrate (Kuz'menko et al., 1992) and diaquabis(iminodiacetato)cadmiumcobalt (Long et al., 2003). For a lanthanum/zinc complex, see: Xu et al. (2004). For lanthanum/copper complexes, see: Ren et al. (2003a,b); Liu et al. (2003). For lanthanum/nickel complexes, see: Kong et al. (2007). For diaqua(iminodiacetato)nickel, see: Wu et al. (2003). For other lanthanum derivatives, see: Albertsson & Oskarsson (1968, 1974); Bombieri et al. (1974); Li et al. (1997, 1999).
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2007).
[LaNi(C4H5NO4)2(C4H6NO4)]·H2O | F(000) = 1200 |
Mr = 609.91 | Dx = 2.250 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 6635 reflections |
a = 9.7390 (4) Å | θ = 2.5–28.3° |
b = 23.859 (1) Å | µ = 3.47 mm−1 |
c = 8.5312 (4) Å | T = 173 K |
β = 114.732 (1)° | Column, blue |
V = 1800.5 (1) Å3 | 0.29 × 0.12 × 0.12 mm |
Z = 4 |
Bruker APEX area-detector diffractometer | 2049 independent reflections |
Radiation source: fine-focus sealed tube | 2046 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.020 |
φ and ω scans | θmax = 27.5°, θmin = 1.7° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −12→12 |
Tmin = 0.531, Tmax = 0.681 | k = −30→30 |
7464 measured reflections | l = −11→11 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.024 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.062 | H-atom parameters constrained |
S = 1.25 | w = 1/[σ2(Fo2) + (0.025P)2 + 7.2608P] where P = (Fo2 + 2Fc2)/3 |
2049 reflections | (Δ/σ)max = 0.001 |
142 parameters | Δρmax = 1.07 e Å−3 |
6 restraints | Δρmin = −0.59 e Å−3 |
[LaNi(C4H5NO4)2(C4H6NO4)]·H2O | V = 1800.5 (1) Å3 |
Mr = 609.91 | Z = 4 |
Monoclinic, C2/c | Mo Kα radiation |
a = 9.7390 (4) Å | µ = 3.47 mm−1 |
b = 23.859 (1) Å | T = 173 K |
c = 8.5312 (4) Å | 0.29 × 0.12 × 0.12 mm |
β = 114.732 (1)° |
Bruker APEX area-detector diffractometer | 2049 independent reflections |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | 2046 reflections with I > 2σ(I) |
Tmin = 0.531, Tmax = 0.681 | Rint = 0.020 |
7464 measured reflections |
R[F2 > 2σ(F2)] = 0.024 | 6 restraints |
wR(F2) = 0.062 | H-atom parameters constrained |
S = 1.25 | Δρmax = 1.07 e Å−3 |
2049 reflections | Δρmin = −0.59 e Å−3 |
142 parameters |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
La1 | 0.5000 | 0.506465 (9) | 0.7500 | 0.01011 (8) | |
Ni1 | 0.5000 | 0.66141 (2) | 0.7500 | 0.01438 (12) | |
O1 | 0.3730 (3) | 0.58240 (9) | 1.0855 (3) | 0.0192 (5) | |
O2 | 0.4288 (2) | 0.59806 (9) | 0.8602 (3) | 0.0160 (4) | |
O3 | 0.2951 (3) | 0.66506 (9) | 0.5435 (3) | 0.0201 (5) | |
O4 | 0.0546 (3) | 0.68604 (11) | 0.4774 (4) | 0.0313 (6) | |
O5 | 0.6443 (2) | 0.47668 (9) | 0.5902 (3) | 0.0148 (4) | |
O6 | 0.7921 (2) | 0.45955 (9) | 0.4593 (3) | 0.0175 (4) | |
O1w | 0.958 (3) | 0.4153 (7) | 0.255 (4) | 0.175 (8) | 0.50 |
H1w1 | 0.9572 | 0.4361 | 0.3381 | 0.262* | 0.50 |
H1w2 | 1.0410 | 0.4162 | 0.2436 | 0.262* | 0.50 |
N1 | 0.3913 (3) | 0.71032 (10) | 0.8677 (3) | 0.0166 (5) | |
H1n | 0.4419 | 0.7416 | 0.9068 | 0.020* | |
N2 | 1.0000 | 0.40180 (15) | 0.7500 | 0.0144 (7) | |
H2n1 | 0.9617 | 0.3800 | 0.6587 | 0.017* | 0.50 |
H2n2 | 1.0383 | 0.3800 | 0.8413 | 0.017* | 0.50 |
C1 | 0.3964 (3) | 0.61346 (12) | 0.9834 (4) | 0.0151 (5) | |
C2 | 0.3938 (4) | 0.67636 (13) | 1.0123 (4) | 0.0224 (7) | |
H2A | 0.3035 | 0.6855 | 1.0327 | 0.027* | |
H2B | 0.4842 | 0.6866 | 1.1176 | 0.027* | |
C3 | 0.2385 (4) | 0.72313 (14) | 0.7375 (4) | 0.0217 (6) | |
H3A | 0.2335 | 0.7633 | 0.7064 | 0.026* | |
H3B | 0.1652 | 0.7167 | 0.7883 | 0.026* | |
C4 | 0.1924 (4) | 0.68802 (13) | 0.5741 (4) | 0.0200 (6) | |
C5 | 0.7663 (3) | 0.45831 (12) | 0.5895 (4) | 0.0137 (5) | |
C6 | 0.8756 (3) | 0.43440 (13) | 0.7608 (4) | 0.0169 (6) | |
H6A | 0.9192 | 0.4656 | 0.8434 | 0.020* | |
H6B | 0.8191 | 0.4100 | 0.8070 | 0.020* |
U11 | U22 | U33 | U12 | U13 | U23 | |
La1 | 0.01116 (12) | 0.01078 (12) | 0.00888 (12) | 0.000 | 0.00465 (9) | 0.000 |
Ni1 | 0.0187 (3) | 0.0133 (3) | 0.0114 (2) | 0.000 | 0.0065 (2) | 0.000 |
O1 | 0.0244 (12) | 0.0185 (11) | 0.0194 (11) | 0.0046 (8) | 0.0137 (10) | 0.0052 (8) |
O2 | 0.0205 (10) | 0.0138 (10) | 0.0156 (10) | 0.0006 (8) | 0.0096 (9) | 0.0005 (8) |
O3 | 0.0241 (11) | 0.0190 (11) | 0.0139 (10) | 0.0018 (9) | 0.0048 (9) | −0.0010 (8) |
O4 | 0.0216 (12) | 0.0256 (13) | 0.0340 (14) | 0.0035 (10) | −0.0008 (11) | −0.0099 (11) |
O5 | 0.0124 (9) | 0.0201 (10) | 0.0121 (9) | 0.0036 (8) | 0.0052 (8) | 0.0011 (8) |
O6 | 0.0168 (10) | 0.0225 (11) | 0.0148 (10) | 0.0021 (8) | 0.0082 (8) | 0.0010 (8) |
O1w | 0.169 (12) | 0.198 (11) | 0.168 (10) | 0.028 (8) | 0.082 (9) | −0.011 (8) |
N1 | 0.0220 (13) | 0.0115 (11) | 0.0160 (12) | −0.0005 (9) | 0.0077 (11) | −0.0004 (9) |
N2 | 0.0115 (16) | 0.0148 (16) | 0.0150 (16) | 0.000 | 0.0038 (13) | 0.000 |
C1 | 0.0139 (13) | 0.0169 (14) | 0.0119 (13) | 0.0022 (10) | 0.0029 (11) | 0.0008 (10) |
C2 | 0.0375 (19) | 0.0163 (15) | 0.0182 (15) | 0.0020 (13) | 0.0165 (14) | −0.0005 (12) |
C3 | 0.0230 (16) | 0.0201 (15) | 0.0204 (15) | 0.0057 (12) | 0.0075 (13) | −0.0019 (12) |
C4 | 0.0248 (16) | 0.0136 (14) | 0.0177 (15) | 0.0015 (12) | 0.0052 (13) | 0.0012 (11) |
C5 | 0.0130 (13) | 0.0129 (13) | 0.0145 (13) | −0.0007 (10) | 0.0052 (11) | −0.0004 (10) |
C6 | 0.0119 (13) | 0.0242 (15) | 0.0154 (14) | 0.0047 (11) | 0.0065 (11) | 0.0040 (11) |
La1—O1i | 2.558 (2) | O5—La1iv | 2.673 (2) |
La1—O1ii | 2.558 (2) | O6—C5 | 1.238 (4) |
La1—O2 | 2.585 (2) | O6—La1iv | 2.773 (2) |
La1—O2iii | 2.585 (2) | O1w—H1w1 | 0.87 |
La1—O5 | 2.438 (2) | O1w—H1w2 | 0.856 |
La1—O5iii | 2.438 (2) | N1—C2 | 1.468 (4) |
La1—O5iv | 2.673 (2) | N1—C3 | 1.469 (4) |
La1—O5v | 2.673 (2) | N1—H1n | 0.8800 |
La1—O6iv | 2.773 (2) | N2—C6 | 1.475 (3) |
La1—O6v | 2.773 (2) | N2—C6vi | 1.475 (3) |
Ni1—O2 | 2.048 (2) | N2—H2n1 | 0.8800 |
Ni1—O2iii | 2.048 (2) | N2—H2n2 | 0.8800 |
Ni1—O3 | 2.038 (2) | C1—C2 | 1.523 (4) |
Ni1—O3iii | 2.038 (2) | C2—H2A | 0.9900 |
Ni1—N1 | 2.093 (3) | C2—H2B | 0.9900 |
Ni1—N1iii | 2.093 (3) | C3—C4 | 1.524 (4) |
O1—C1 | 1.235 (4) | C3—H3A | 0.9900 |
O1—La1i | 2.558 (2) | C3—H3B | 0.9900 |
O2—C1 | 1.272 (4) | C5—C6 | 1.514 (4) |
O3—C4 | 1.260 (4) | C6—H6A | 0.9900 |
O4—C4 | 1.248 (4) | C6—H6B | 0.9900 |
O5—C5 | 1.269 (3) | ||
O5iii—La1—O5 | 146.10 (10) | O3—Ni1—N1iii | 94.06 (10) |
O5iii—La1—O1ii | 78.79 (7) | O3iii—Ni1—N1iii | 83.21 (10) |
O5—La1—O1ii | 73.20 (7) | O2iii—Ni1—N1iii | 81.68 (9) |
O5iii—La1—O1i | 73.20 (7) | O2—Ni1—N1iii | 165.47 (9) |
O5—La1—O1i | 78.79 (7) | N1—Ni1—N1iii | 112.22 (14) |
O1ii—La1—O1i | 68.03 (11) | C1—O1—La1i | 134.0 (2) |
O5iii—La1—O2 | 74.83 (7) | C1—O2—Ni1 | 114.52 (19) |
O5—La1—O2 | 138.99 (7) | C1—O2—La1 | 137.87 (19) |
O1ii—La1—O2 | 139.33 (7) | Ni1—O2—La1 | 105.28 (8) |
O1i—La1—O2 | 130.01 (7) | C4—O3—Ni1 | 114.5 (2) |
O5iii—La1—O2iii | 138.99 (7) | C5—O5—La1 | 149.69 (19) |
O5—La1—O2iii | 74.83 (7) | C5—O5—La1iv | 96.62 (17) |
O1ii—La1—O2iii | 130.01 (7) | La1—O5—La1iv | 113.52 (8) |
O1i—La1—O2iii | 139.33 (7) | C5—O6—La1iv | 92.63 (17) |
O2—La1—O2iii | 64.59 (9) | H1w1—O1w—H1w2 | 114 |
O5iii—La1—O5iv | 119.13 (8) | C2—N1—C3 | 113.9 (3) |
O5—La1—O5iv | 66.48 (8) | C2—N1—Ni1 | 105.16 (18) |
O1ii—La1—O5iv | 67.37 (7) | C3—N1—Ni1 | 108.01 (19) |
O1i—La1—O5iv | 129.37 (7) | C2—N1—H1n | 109.9 |
O2—La1—O5iv | 99.69 (6) | C3—N1—H1n | 109.9 |
O2iii—La1—O5iv | 65.00 (7) | Ni1—N1—H1n | 109.9 |
O5iii—La1—O5v | 66.48 (8) | C6—N2—C6vi | 116.3 (3) |
O5—La1—O5v | 119.13 (8) | C6—N2—H2n1 | 108.2 |
O1ii—La1—O5v | 129.37 (7) | C6vi—N2—H2n1 | 108.2 |
O1i—La1—O5v | 67.37 (7) | C6—N2—H2n2 | 108.2 |
O2—La1—O5v | 65.00 (7) | C6vi—N2—H2n2 | 108.2 |
O2iii—La1—O5v | 99.69 (7) | H2n1—N2—H2n2 | 107.4 |
O5iv—La1—O5v | 162.69 (9) | O1—C1—O2 | 126.3 (3) |
O5iii—La1—O6v | 113.67 (6) | O1—C1—C2 | 117.2 (3) |
O5—La1—O6v | 76.65 (7) | O2—C1—C2 | 116.4 (3) |
O1ii—La1—O6v | 136.56 (7) | N1—C2—C1 | 113.8 (3) |
O1i—La1—O6v | 76.04 (7) | N1—C2—H2A | 108.8 |
O2—La1—O6v | 82.97 (7) | C1—C2—H2A | 108.8 |
O2iii—La1—O6v | 68.16 (7) | N1—C2—H2B | 108.8 |
O5iv—La1—O6v | 125.93 (6) | C1—C2—H2B | 108.8 |
O5v—La1—O6v | 47.57 (6) | H2A—C2—H2B | 107.7 |
O5iii—La1—O6iv | 76.65 (7) | N1—C3—C4 | 113.3 (3) |
O5—La1—O6iv | 113.67 (6) | N1—C3—H3A | 108.9 |
O1ii—La1—O6iv | 76.04 (7) | C4—C3—H3A | 108.9 |
O1i—La1—O6iv | 136.56 (7) | N1—C3—H3B | 108.9 |
O2—La1—O6iv | 68.16 (7) | C4—C3—H3B | 108.9 |
O2iii—La1—O6iv | 82.97 (7) | H3A—C3—H3B | 107.7 |
O5iv—La1—O6iv | 47.57 (6) | O4—C4—O3 | 125.0 (3) |
O5v—La1—O6iv | 125.93 (6) | O4—C4—C3 | 116.7 (3) |
O6v—La1—O6iv | 145.99 (9) | O3—C4—C3 | 118.2 (3) |
O3—Ni1—O3iii | 175.11 (13) | O6—C5—O5 | 122.5 (3) |
O3—Ni1—O2iii | 91.83 (9) | O6—C5—C6 | 123.4 (3) |
O3iii—Ni1—O2iii | 91.78 (9) | O5—C5—C6 | 114.1 (2) |
O3—Ni1—O2 | 91.78 (9) | N2—C6—C5 | 113.8 (2) |
O3iii—Ni1—O2 | 91.83 (9) | N2—C6—H6A | 108.8 |
O2iii—Ni1—O2 | 84.85 (12) | C5—C6—H6A | 108.8 |
O3—Ni1—N1 | 83.21 (10) | N2—C6—H6B | 108.8 |
O3iii—Ni1—N1 | 94.06 (10) | C5—C6—H6B | 108.8 |
O2iii—Ni1—N1 | 165.47 (10) | H6A—C6—H6B | 107.7 |
O2—Ni1—N1 | 81.68 (9) | ||
O3—Ni1—O2—C1 | −102.5 (2) | O1ii—La1—O5—La1iv | 72.12 (9) |
O3iii—Ni1—O2—C1 | 74.2 (2) | O1i—La1—O5—La1iv | 142.32 (10) |
O2iii—Ni1—O2—C1 | 165.8 (2) | O2—La1—O5—La1iv | −77.24 (12) |
N1—Ni1—O2—C1 | −19.6 (2) | O2iii—La1—O5—La1iv | −68.93 (8) |
N1iii—Ni1—O2—C1 | 143.8 (3) | O5iv—La1—O5—La1iv | 0.0 |
O3—Ni1—O2—La1 | 91.68 (9) | O5v—La1—O5—La1iv | −161.70 (9) |
O3iii—Ni1—O2—La1 | −91.62 (9) | O6v—La1—O5—La1iv | −139.55 (9) |
O2iii—Ni1—O2—La1 | 0.0 | O6iv—La1—O5—La1iv | 6.16 (11) |
N1—Ni1—O2—La1 | 174.55 (10) | O3—Ni1—N1—C2 | 117.8 (2) |
N1iii—Ni1—O2—La1 | −22.0 (4) | O3iii—Ni1—N1—C2 | −66.3 (2) |
O5iii—La1—O2—C1 | 25.4 (3) | O2iii—Ni1—N1—C2 | 47.2 (5) |
O5—La1—O2—C1 | −151.7 (3) | O2—Ni1—N1—C2 | 25.0 (2) |
O1ii—La1—O2—C1 | 76.8 (3) | N1iii—Ni1—N1—C2 | −150.6 (2) |
O1i—La1—O2—C1 | −26.4 (3) | O3—Ni1—N1—C3 | −4.2 (2) |
O2iii—La1—O2—C1 | −160.6 (3) | O3iii—Ni1—N1—C3 | 171.7 (2) |
O5iv—La1—O2—C1 | 143.2 (3) | O2iii—Ni1—N1—C3 | −74.9 (4) |
O5v—La1—O2—C1 | −45.3 (3) | O2—Ni1—N1—C3 | −97.0 (2) |
O6v—La1—O2—C1 | −91.5 (3) | N1iii—Ni1—N1—C3 | 87.4 (2) |
O6iv—La1—O2—C1 | 106.9 (3) | La1i—O1—C1—O2 | 42.4 (5) |
O5iii—La1—O2—Ni1 | −173.97 (10) | La1i—O1—C1—C2 | −134.4 (3) |
O5—La1—O2—Ni1 | 8.89 (15) | Ni1—O2—C1—O1 | −168.5 (2) |
O1ii—La1—O2—Ni1 | −122.63 (10) | La1—O2—C1—O1 | −9.1 (5) |
O1i—La1—O2—Ni1 | 134.23 (9) | Ni1—O2—C1—C2 | 8.3 (3) |
O2iii—La1—O2—Ni1 | 0.0 | La1—O2—C1—C2 | 167.7 (2) |
O5iv—La1—O2—Ni1 | −56.24 (9) | C3—N1—C2—C1 | 89.9 (3) |
O5v—La1—O2—Ni1 | 115.28 (10) | Ni1—N1—C2—C1 | −28.2 (3) |
O6v—La1—O2—Ni1 | 69.12 (9) | O1—C1—C2—N1 | −168.1 (3) |
O6iv—La1—O2—Ni1 | −92.54 (9) | O2—C1—C2—N1 | 14.7 (4) |
O2iii—Ni1—O3—C4 | 159.8 (2) | C2—N1—C3—C4 | −103.8 (3) |
O2—Ni1—O3—C4 | 74.9 (2) | Ni1—N1—C3—C4 | 12.7 (3) |
N1—Ni1—O3—C4 | −6.5 (2) | Ni1—O3—C4—O4 | −166.8 (3) |
N1iii—Ni1—O3—C4 | −118.5 (2) | Ni1—O3—C4—C3 | 16.0 (4) |
O5iii—La1—O5—C5 | −78.8 (4) | N1—C3—C4—O4 | 162.7 (3) |
O1ii—La1—O5—C5 | −114.4 (4) | N1—C3—C4—O3 | −19.9 (4) |
O1i—La1—O5—C5 | −44.2 (4) | La1iv—O6—C5—O5 | −8.2 (3) |
O2—La1—O5—C5 | 96.2 (4) | La1iv—O6—C5—C6 | 171.1 (3) |
O2iii—La1—O5—C5 | 104.6 (4) | La1—O5—C5—O6 | −165.4 (3) |
O5iv—La1—O5—C5 | 173.5 (4) | La1iv—O5—C5—O6 | 8.6 (3) |
O5v—La1—O5—C5 | 11.8 (4) | La1—O5—C5—C6 | 15.2 (5) |
O6v—La1—O5—C5 | 33.9 (4) | La1iv—O5—C5—C6 | −170.8 (2) |
O6iv—La1—O5—C5 | 179.6 (4) | C6vi—N2—C6—C5 | 77.8 (2) |
C5v—La1—O5—C5 | 25.2 (4) | O6—C5—C6—N2 | −12.6 (4) |
C5iv—La1—O5—C5 | 174.8 (3) | O5—C5—C6—N2 | 166.8 (3) |
O5iii—La1—O5—La1iv | 107.71 (8) |
Symmetry codes: (i) −x+1, −y+1, −z+2; (ii) x, −y+1, z−1/2; (iii) −x+1, y, −z+3/2; (iv) −x+1, −y+1, −z+1; (v) x, −y+1, z+1/2; (vi) −x+2, y, −z+3/2. |
D—H···A | D—H | H···A | D···A | D—H···A |
N1—H1n···O4vii | 0.88 | 2.00 | 2.877 (4) | 176 |
N2—H2n1···O4iv | 0.88 | 1.92 | 2.752 (4) | 156 |
N2—H2n2···O4viii | 0.88 | 1.92 | 2.752 (4) | 156 |
O1w—H1w1···O6 | 0.87 | 2.31 | 3.01 (2) | 138 |
Symmetry codes: (iv) −x+1, −y+1, −z+1; (vii) x+1/2, −y+3/2, z+1/2; (viii) x+1, −y+1, z+1/2. |
Experimental details
Crystal data | |
Chemical formula | [LaNi(C4H5NO4)2(C4H6NO4)]·H2O |
Mr | 609.91 |
Crystal system, space group | Monoclinic, C2/c |
Temperature (K) | 173 |
a, b, c (Å) | 9.7390 (4), 23.859 (1), 8.5312 (4) |
β (°) | 114.732 (1) |
V (Å3) | 1800.5 (1) |
Z | 4 |
Radiation type | Mo Kα |
µ (mm−1) | 3.47 |
Crystal size (mm) | 0.29 × 0.12 × 0.12 |
Data collection | |
Diffractometer | Bruker APEX area-detector diffractometer |
Absorption correction | Multi-scan (SADABS; Sheldrick, 1996) |
Tmin, Tmax | 0.531, 0.681 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 7464, 2049, 2046 |
Rint | 0.020 |
(sin θ/λ)max (Å−1) | 0.650 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.024, 0.062, 1.25 |
No. of reflections | 2049 |
No. of parameters | 142 |
No. of restraints | 6 |
H-atom treatment | H-atom parameters constrained |
Δρmax, Δρmin (e Å−3) | 1.07, −0.59 |
Computer programs: SMART (Bruker, 2002), SAINT (Bruker, 2002), SAINT, SHELXS97 (Sheldrick, 1997), SHELXL97 (Sheldrick, 1997), X-SEED (Barbour, 2001), publCIF (Westrip, 2007).
La1—O1i | 2.558 (2) | La1—O5v | 2.673 (2) |
La1—O1ii | 2.558 (2) | La1—O6iv | 2.773 (2) |
La1—O2 | 2.585 (2) | La1—O6v | 2.773 (2) |
La1—O2iii | 2.585 (2) | Ni1—O2 | 2.048 (2) |
La1—O5 | 2.438 (2) | Ni1—O3 | 2.038 (2) |
La1—O5iii | 2.438 (2) | Ni1—N1 | 2.093 (3) |
La1—O5iv | 2.673 (2) |
Symmetry codes: (i) −x+1, −y+1, −z+2; (ii) x, −y+1, z−1/2; (iii) −x+1, y, −z+3/2; (iv) −x+1, −y+1, −z+1; (v) x, −y+1, z+1/2. |
The iminodiacetate [-O(O)CCH2NHCH2C(O)O-] dianion forms a large number of crystalline metal derivatives in which it O,N,O'-chelates to the metal. These studies have largely addressed compounds having one type of metal only; diaquadi(iminodiacetato)calciumcobalt tetrahydrate (Kuz'menko et al., 1992) and diaquadi(iminodiacetato)cadmiumcobalt (Long et al., 2003) represent unusual examples of heterometallic systems. The two compound adopt layer structures. A series of lanthanum/copper complexes is known that exhibit porosity; the three-dimensional network is also thermally stable when lattice molecules are removed (Ren et al., 2003a,b). Another series of lanthanum/copper complexes, [LnCu6(OH)3(C4H6NO4)2(C4H5NO4)4].(ClO4)2.25H2O, features antiferromagnetic Ln–Cu interactions as the rare earth atom is surrounded by six copper atoms at a distance of approximately 3.5 Å (Liu et al., 2003).
The present study extends an earlier study on a metal derivative of iminodiacetic acid that features both d- and f-block elements within the same framework. The hydrothermal reaction of lanthanum nitrate, nickel nitrate and iminodiacetic acid gave a gigantic metal cluster consisting of 20 lanthanum and 30 nickel atoms in the formula unit, [La20Ni30(C4H5NO4)30(CO3)6(NO3)6(OH)30(H2O)12](CO3)6.72H2O (Kong et al., 2007). Changing the lanthanum nitrate reactant to lanthanum chloride yielded the title compound, which has only one of each metal atom in formula unit. In [(C4H5NO4)2(C4H6NO4)LaNi.H2O]n (Fig. 1), two deprotonated iminodiacetate dianions each chelate to the nickel atom, the three chelating atoms occupying fac positions of the octahedral geometry of nickel, a feature that is also found in diaqua(iminodiacetato)nickel (Wu et al., 2003). Meanwhile, the iminodiacetate monoanion, which lies about a twofold rotation axis, O,O'-chelates to the water-coordinated lanthanum atom. One of the two oxygen atoms is additionally involved in bridging to another lanthanum atom, so that the geometry of the f-block metal is a ten-coordinate bicapped square antiprism (Fig. 2) in the layer structure. Hydrogen bonds link the layers into a three-dimensional network motif.
The somewhat uncommon iminodiacetate monoanion has also been found in other rare-earth complexes such as the neodymium (Albertsson & Oskarsson, 1968) praseodymium (Albertsson & Oskarsson, 1974; Li et al., 1999), uranium (Bombieri et al., 1974), yttrium (Li et al., 1997) and lanthanum complexes. The lanthanum complex is also a heterometallic compound having lanthanum and zinc bridged into a linear chain (Xu et al., 2004).