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Acta Cryst. (2007). E63, m2222 [ doi:10.1107/S1600536807035830 ]
Abstract: The structure of the title compound (K4CBS), poly[![[mu]](/logos/entities/mu_rmgif.gif)
4-4-chlorobenzenesulfonato-potassium(I)], [K(C6H4ClO3S)]n, resembles that of silver 4-chlorobenzenesulfonate with somewhat different geometric parameters. The supramolecular structure is constructed by Cl atoms bridging the K+ ions. Each K+ ion is heptacoordinated by two Cl ligands and four sulfonate groups, one of them in a monodentate and three in a bidentate fashion. Thus, each sulfonate group coordinates four K+ ions.
Online 27 July 2007
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