Acta Cryst. (2007). E63, m2029  [ doi:10.1107/S160053680703070X ]

(Acetonitrile-N)(2,2':6',2''-terpyridyl-³N)palladium(II)] bis(hexafluorophosphate)

G.-Q. Mei and K.-L. Huang

Abstract: In the title compound, [Pd(C₁₅H₁₁N₃)(C₂H₃N)](PF₆)₂, the Pd atom is four-coordinated by a tridentate chelating 2,2':6',2''-terpyridine ligand and an acetonitrile ligand in a square-planar geometry. The cations and hexafluoridophosphate anions are connected together via anion- interactions [P-F = 3.063 (5) and 3.076 (6) Å] and C-HF hydrogen bonds to form alternating layers along the b axis.

Online 5 July 2007

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