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Acta Cryst. (2007). E63, m2345  [ doi:10.1107/S160053680703958X ]

Dibromidobis(2-methyl-5-phenyl-s-triazolo[3,4-b][1,3,4]thiadiazole-[kappa]N)nickel(II)

L.-G. Wang

Abstract: The title complex, [NiBr2(C10H8N4S)2], is a mononuclear molecule consisting of an NiII ion, two 2-methyl-5-phenyl-s-triazolo[3,4-b][1,3,4]thiadiazole ligands and two bromide ligands. The NiII atom, located on a center of symmetry, displays a square-planar coordination geometry. Intermolecular C-H...Br hydrogen bonds and [pi]-[pi] contacts [centroid-centroid distance = 3.58 (6) Å] stabilize the supramolecular structure.

Online 15 August 2007


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