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Acta Cryst. (2007). E63, m2290  [ doi:10.1107/S1600536807037646 ]

Dichlorido{2-[3-(2-pyridyl)pyrazol-1-ylmethyl]pyridine}zinc(II)

C.-S. Liu and J.-N. Zhou

Abstract: In the title complex, [ZnCl2(C14H12N4)], ZnII is pentacoordinated by three N-atom donors from one 2-[3-(2-pyridyl)pyrazol-1-ylmethyl]pyridine (L) ligand and by two Cl- anions in a distorted trigonal-bipyramidal geometry. Adjacent mononuclear ZnII complexes form [pi]-[pi] stacking interactions between pyridine and pyrazole rings of neighbouring L ligands, with centroid-centroid separations of 3.671 (1) and 3.681 (1) Å, generating one-dimensional chains.

Online 8 August 2007


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