Acta Cryst. (2007). E63, m2299  [ doi:10.1107/S1600536807038421 ]

Diacetato(1,4,8,11-tetraazacyclotetradecane)manganese(III) perchlorate monohydrate

I.-C. Hwang and K. Ha

Abstract: The title compound, [Mn(CH₃COO)₂(C₁₀H₂₄N₄)]ClO₄·H₂O, contains two crystallographically independent cationic complexes, each located with their central Mn^III atom on a centre of inversion. Each Mn^III atom is six-coordinated in a distorted octahedral geometry by two O atoms from acetate anions occupying axial positions and four N atoms from 1,4,8,11-tetraazacyclotetradecane (cyclam) occupying equatorial positions. The compound displays intra- and intermolecular N-HO and O-HO hydrogen bonding.

Online 8 August 2007

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