Acta Cryst. (2007). E63, m2287-m2288  [ doi:10.1107/S1600536807037427 ]

Poly[[-dioxane-²O:O'-dioxane-O--diphenylamido-²N:N-potassium] dioxane solvate]

M. Gärtner, H. Görls and M. Westerhausen

Abstract: The title compound, {[K(C₁₂H₁₀N)(C₄H₈O₂)₂]·C₄H₈O₂}_n, contains a K atom surrounded by two bridging diphenylamido ligands and three molecules of dioxane. Two of these dioxane ligands are located on a centre of inversion and form bridges to neighbouring K atoms, yielding two-dimensional layers. The K atom is in a distorted square-pyramidal environment in which one bridging dioxane molecule occupies the apical position.

Online 8 August 2007

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