Acta Cryst. (2007). E63, m2269-m2270  [ doi:10.1107/S160053680703718X ]

{2-[(2-Aminophenyl)iminomethyl]-4-bromophenolato-³N,N',O}chloridobis(dimethyl sulfoxide-S)ruthenium(II)

N. E. Eltayeb, S. G. Teoh, S. Chantrapromma, H.-K. Fun and K. Ibrahim

Abstract: The title compound, [Ru(C₁₃H₁₀BrN₂O)Cl(C₂H₆OS)₂], shows a distorted octahedral Ru^II coordination with the N₂O tridentate Schiff base ligand and one dimethyl sulfoxide (DMSO) molecule bonded in the equatorial plane, and the Cl and another DMSO ligand occupying the axial positions. In the crystal structure, molecules are linked by N-HCl and N-HO hydrogen bonds into one-dimensional chains along the [100] direction. The crystal structure is further stabilized by weak C-HO and C-HCl interactions. C-H interactions are also observed in the crystal structure.

Online 3 August 2007

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