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Acta Cryst. (2007). E63, m2320 [ doi:10.1107/S1600536807039189 ]
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N)di-![[mu]](/logos/entities/mu_rmgif.gif)
4-oxido-tetra-3-oxido-hexa-2-oxido-tetradecaoxidooctamolybdate(VI) monohydrateAbstract: The anion of the title salt, (C3H5N2)4[Mo8O26(C3H4N2)2]·H2O, is a centrosymmetric Mo8O26 species in which two Mo atoms are each coordinated by an imidazole heterocycle. The anion is made up of two MoNO5 and six MoO6 edge-sharing octahedra. The cations interact with the tetraanion to give rise to a three-dimensional hydrogen-bonded network. The asymmetric unit features three cations, two of which lie on centers of inversion; the solvent water molecule is disordered with respect to one of these two cations.
Online 10 August 2007
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