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Acta Cryst. (2007). E63, m2258  [ doi:10.1107/S1600536807016893 ]

Poly[[aqua([mu]2-4,4'-bipyridine)([mu]5-4,4'-oxydibenzene-1,2-carboxylato)dizinc(II)] 4,4'-bipyridine hemisolvate]

P.-X. Yin, Z.-J. Li, X.-Y. Cao, Y.-Y. Qin and Y.-G. Yao

Abstract: A new three-dimensional metal-organic framework, {[Zn2(C16H6O9)(C10H8N2)(H2O)]·0.5C10H8N2}n, is a porous three-dimensional bipyridyl-pillared framework with rhombic channels built from two-dimensional helical double layers of Zn-DETA [DETA is 4,4'-oxydi(benzene-1,2- carboxylate)] with the 4,4'-bipyridyl guest molecules locked in the cavities through short O-H...N hydrogen bonds.

Online 3 August 2007


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