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Acta Cryst. (2007). E63, m2300  [ doi:10.1107/S1600536807037920 ]

Tetrakis([mu]3-2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}phenolato)tetracopper(II)

J.-F. Dong, L.-Z. Li, H.-Y. Xu and D.-Q. Wang

Abstract: In the title tetranuclear complex, [Cu4(C11H13NO4)4], which has crystallographic \overline{4} symmetry, the CuII ions are coordinated by the tridentate Schiff base ligands, forming a tetranuclear Cu4O4 cubane-like configuration. The CuII ion adopts a CuNO4 distorted square-pyramidal coordination environment. In the crystal structure, intermolecular O-H...O bonds help to form a three-dimensional structure.


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