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Acta Cryst. (2007). E63, m2361    [ doi:10.1107/S1600536807039955 ]

(6-Aminonaphthalene-1-sulfonato-[kappa]O)bis(3-methylisoquinoline-[kappa]N)silver(I)

X.-Y. Wang, C.-H. Ma, Q.-Q. Gao, S.-Q. Lu and X.-W. Dong

Abstract top

The title compound, [Ag(C10H8NO3S)(C10H9N)2], has a mononuclear structure in which the Ag+ cation is three-coordinated by two N atoms from two different 3-methylisoquinoline molecules and one O atom from a 6-aminonaphthalene-1-sulfonate anion in a distorted trigonal-planar AgN2O arrangement. A network of N-H...O hydrogen bonds consolidates the structure.

Comment top

In this paper, the structure of the title compound, (I) (Fig. 1), containing two 3-methylisoquinoline molecules and one 6-amino-1-naphthalenesulfonate (L) anion is described.

In (I), two 3-methylisoquinoline molecules and one L anion are coordinated to the metal, resulting in a highly distorted trigonal planar coordination geometry for Ag (Table 1). Atoms Ag1, N2, N3 and O3 are close to coplanar and the bond-angle sum about Ag is 347.11°. The Ag—N distances in (I) are similar to the equivalent values in a related compound (Li et al., 2007). The dihedral angle between the quinoline rings of the two coordinated 3-methylisoquinoline molecules is 22.2 (3)°.

The structure of (I) is completed by N—H···O hydrogen bonds (Table 2) to result in chains propagating in [100].

Related literature top

For the related compound, Ag(L1)(3-iso) (L1 = 2-amino-3,5-dimethylbenzenesulfonate, 3-iso = 3-methylisoquinoline), containing a trigonal–planar AgN3 arrangement, see: Li et al. (2007).

Experimental top

An aqueous solution (10 ml) of 6-amino-1-naphthalenesulfonic acid (0.1115 g, 0.5 mmol) was added to solid Ag2CO3 (0.069 g, 0.25 mmol) and stirred for several minutes until no further CO2 was given off; 3-methylisoquinoline (0.0715 g, 0.5 mmol) in methanol (5 ml) was then added and a white precipitate formed. The precipitate was dissolved by dropwise addition of an aqueous solution of NH3 (14 M). Crystals of (I) were obtained by evaporation of the solution for several days at room temperature.

Refinement top

The N-bound H atoms were located in a difference map and their positions were freely refined with Uiso(H) = 1.2Ueq(N). The C-bound H atoms were positioned geometrically (C—H = 0.93–0.96 Å) and refined as riding, with Uiso(H) = 1.2Ueq(C) or 1.5Ueq(methyl C).

Computing details top

Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL-Plus (Sheldrick, 1990); software used to prepare material for publication: SHELXL97.

Figures top
[Figure 1] Fig. 1. The molecular structure of (I), with 30% probability displacement ellipsoids for non-H atoms.
(6-Aminonaphthalene-1-sulfonato-κO)bis(3-methylisoquinoline-κN)silver(I) top
Crystal data top
[Ag(C10H8NO3S)(C10H9N)2]Z = 2
Mr = 616.47F000 = 628
Triclinic, P1Dx = 1.562 Mg m−3
Hall symbol: -P 1Mo Kα radiation
λ = 0.71073 Å
a = 9.8810 (14) ÅCell parameters from 5933 reflections
b = 10.2220 (17) Åθ = 2.0–28.3º
c = 13.256 (2) ŵ = 0.89 mm−1
α = 80.108 (11)ºT = 292 (2) K
β = 86.653 (11)ºBlock, colourless
γ = 84.143 (10)º0.35 × 0.33 × 0.29 mm
V = 1311.0 (4) Å3
Data collection top
Bruker SMART APEX CCD
diffractometer		5933 independent reflections
Radiation source: fine-focus sealed tube2404 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.064
T = 292(2) Kθmax = 28.3º
ω scansθmin = 2.0º
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		h = −12→12
Tmin = 0.709, Tmax = 0.766k = −13→10
8844 measured reflectionsl = −17→17
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: difmap and geom
R[F2 > 2σ(F2)] = 0.048H atoms treated by a mixture of
independent and constrained refinement
wR(F2) = 0.074  w = 1/[σ2(Fo2)]
where P = (Fo2 + 2Fc2)/3
S = 0.76(Δ/σ)max = 0.001
5933 reflectionsΔρmax = 0.38 e Å−3
351 parametersΔρmin = −0.35 e Å−3
3 restraintsExtinction correction: none
Primary atom site location: structure-invariant direct methods
Crystal data top
[Ag(C10H8NO3S)(C10H9N)2]γ = 84.143 (10)º
Mr = 616.47V = 1311.0 (4) Å3
Triclinic, P1Z = 2
a = 9.8810 (14) ÅMo Kα
b = 10.2220 (17) ŵ = 0.89 mm−1
c = 13.256 (2) ÅT = 292 (2) K
α = 80.108 (11)º0.35 × 0.33 × 0.29 mm
β = 86.653 (11)º
Data collection top
Bruker SMART APEX CCD
diffractometer		5933 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		2404 reflections with I > 2σ(I)
Tmin = 0.709, Tmax = 0.766Rint = 0.064
8844 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0483 restraints
wR(F2) = 0.074H atoms treated by a mixture of
independent and constrained refinement
S = 0.76Δρmax = 0.38 e Å−3
5933 reflectionsΔρmin = −0.35 e Å−3
351 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.45151 (4)0.67693 (4)0.24609 (3)0.05828 (15)
C10.3993 (5)0.4468 (5)0.4152 (4)0.0483 (13)
H10.47660.41320.38120.058*
C20.3389 (5)0.3592 (5)0.4960 (4)0.0488 (14)
C30.3883 (6)0.2245 (6)0.5219 (5)0.0706 (18)
H30.46440.19050.48680.085*
C40.3243 (7)0.1436 (6)0.5989 (5)0.083 (2)
H40.35590.05390.61500.099*
C50.2106 (8)0.1950 (7)0.6541 (5)0.089 (2)
H50.16920.14000.70780.107*
C60.1621 (6)0.3237 (6)0.6291 (4)0.0735 (18)
H60.08690.35580.66620.088*
C70.2215 (5)0.4123 (6)0.5483 (4)0.0534 (14)
C80.1762 (5)0.5456 (5)0.5152 (4)0.0599 (15)
H80.10070.58370.54860.072*
C90.2389 (5)0.6209 (5)0.4359 (4)0.0523 (14)
C100.1897 (5)0.7653 (5)0.3960 (4)0.0753 (17)
H10A0.18260.77750.32300.113*
H10B0.25330.82270.41240.113*
H10C0.10210.78700.42730.113*
C130.5358 (4)0.9633 (4)0.1512 (3)0.0332 (11)
C140.6092 (4)1.0543 (4)0.0927 (3)0.0397 (12)
H140.59021.14410.09730.048*
C150.7154 (4)1.0151 (4)0.0239 (3)0.0359 (12)
C160.7952 (5)1.1056 (5)−0.0401 (4)0.0494 (14)
H160.77751.1966−0.03970.059*
C170.8978 (5)1.0607 (5)−0.1025 (4)0.0533 (14)
H170.95021.1209−0.14390.064*
C180.9241 (5)0.9244 (5)−0.1040 (4)0.0497 (14)
H180.99470.8948−0.14650.060*
C190.8488 (5)0.8337 (5)−0.0447 (3)0.0445 (13)
H190.86750.7432−0.04730.053*
C200.7421 (4)0.8779 (4)0.0207 (3)0.0351 (11)
C210.6583 (4)0.7912 (4)0.0831 (4)0.0412 (13)
H210.67400.70070.07970.049*
C220.4221 (4)1.0036 (4)0.2248 (3)0.0547 (14)
H22A0.42980.94500.28950.082*
H22B0.33580.99760.19700.082*
H22C0.42881.09360.23440.082*
C230.8414 (4)0.3038 (4)0.2552 (3)0.0328 (11)
C240.8408 (5)0.1891 (4)0.3251 (4)0.0443 (13)
H240.75960.15080.34340.053*
C250.9623 (5)0.1283 (4)0.3697 (4)0.0504 (14)
H250.96070.04950.41660.061*
C260.9638 (4)0.3629 (4)0.2255 (3)0.0299 (11)
C270.9763 (4)0.4796 (4)0.1512 (3)0.0349 (12)
H270.89800.52480.12170.042*
C281.0982 (4)0.5274 (4)0.1217 (3)0.0383 (12)
H281.10190.60340.07200.046*
C291.2213 (4)0.4623 (5)0.1660 (4)0.0383 (12)
C301.2132 (5)0.3537 (4)0.2412 (3)0.0382 (12)
H301.29180.31330.27290.046*
C311.0875 (4)0.3017 (4)0.2714 (3)0.0331 (11)
C321.0812 (5)0.1832 (5)0.3453 (4)0.0496 (14)
H321.15990.14310.37720.060*
O10.7019 (3)0.3847 (3)0.0920 (2)0.0576 (9)
O20.5813 (3)0.2902 (3)0.2478 (2)0.0493 (9)
O30.6625 (3)0.5087 (3)0.2318 (2)0.0513 (9)
S10.68386 (11)0.37694 (12)0.20242 (10)0.0403 (3)
N11.3436 (4)0.5164 (4)0.1317 (3)0.0478 (12)
N20.3539 (4)0.5727 (4)0.3847 (3)0.0435 (10)
N30.5578 (4)0.8287 (3)0.1470 (3)0.0403 (10)
H1N1.419 (4)0.461 (4)0.147 (3)0.060*
H2N1.363 (5)0.556 (4)0.075 (3)0.060*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0562 (3)0.0463 (3)0.0664 (3)−0.0042 (2)0.0173 (2)0.0005 (2)
C10.051 (3)0.056 (4)0.042 (3)−0.014 (3)−0.004 (3)−0.012 (3)
C20.057 (4)0.050 (4)0.043 (4)−0.023 (3)−0.013 (3)−0.004 (3)
C30.071 (4)0.061 (4)0.081 (5)−0.016 (4)−0.017 (4)−0.006 (4)
C40.100 (6)0.061 (4)0.087 (6)−0.029 (4)−0.046 (5)0.012 (4)
C50.116 (6)0.083 (5)0.070 (5)−0.056 (5)−0.016 (5)0.015 (4)
C60.097 (5)0.088 (5)0.037 (4)−0.040 (4)0.011 (3)−0.001 (4)
C70.066 (4)0.069 (4)0.030 (3)−0.029 (3)0.005 (3)−0.009 (3)
C80.068 (4)0.070 (4)0.045 (4)−0.021 (3)0.020 (3)−0.019 (3)
C90.055 (4)0.058 (4)0.046 (4)−0.011 (3)0.015 (3)−0.017 (3)
C100.076 (4)0.064 (4)0.077 (4)0.004 (3)0.029 (3)−0.003 (4)
C130.033 (3)0.030 (3)0.036 (3)−0.002 (2)−0.005 (2)−0.004 (2)
C140.046 (3)0.028 (3)0.048 (3)−0.001 (2)−0.006 (3)−0.012 (3)
C150.035 (3)0.034 (3)0.039 (3)−0.005 (2)−0.009 (2)−0.005 (2)
C160.055 (4)0.040 (3)0.056 (4)−0.015 (3)0.000 (3)−0.010 (3)
C170.050 (3)0.062 (4)0.050 (4)−0.022 (3)0.000 (3)−0.006 (3)
C180.046 (3)0.060 (4)0.048 (4)−0.007 (3)0.000 (3)−0.024 (3)
C190.046 (3)0.045 (3)0.043 (3)0.002 (3)−0.001 (3)−0.015 (3)
C200.035 (3)0.032 (3)0.041 (3)−0.004 (2)−0.006 (2)−0.011 (3)
C210.043 (3)0.032 (3)0.051 (4)−0.001 (2)−0.005 (3)−0.013 (3)
C220.048 (3)0.054 (3)0.063 (4)−0.002 (3)0.007 (3)−0.017 (3)
C230.032 (3)0.033 (3)0.034 (3)−0.003 (2)0.001 (2)−0.008 (2)
C240.050 (3)0.036 (3)0.048 (3)−0.013 (3)0.002 (3)−0.005 (3)
C250.068 (4)0.035 (3)0.042 (3)−0.003 (3)−0.004 (3)0.009 (3)
C260.034 (3)0.026 (2)0.029 (3)0.001 (2)−0.002 (2)−0.006 (2)
C270.030 (3)0.028 (3)0.045 (3)0.000 (2)−0.006 (2)−0.002 (2)
C280.040 (3)0.031 (3)0.043 (3)−0.006 (2)−0.007 (3)0.000 (2)
C290.027 (3)0.046 (3)0.048 (3)−0.005 (2)−0.003 (3)−0.021 (3)
C300.037 (3)0.035 (3)0.043 (3)0.005 (2)−0.012 (3)−0.009 (3)
C310.037 (3)0.035 (3)0.028 (3)0.000 (2)−0.006 (2)−0.007 (2)
C320.055 (4)0.048 (3)0.040 (3)0.000 (3)−0.004 (3)0.010 (3)
O10.048 (2)0.085 (3)0.038 (2)−0.0121 (19)−0.0052 (18)−0.002 (2)
O20.0342 (19)0.048 (2)0.068 (2)−0.0149 (16)0.0086 (18)−0.0135 (18)
O30.0411 (19)0.0293 (18)0.084 (3)0.0022 (15)−0.0004 (18)−0.0138 (18)
S10.0297 (7)0.0384 (8)0.0523 (9)−0.0043 (6)0.0004 (6)−0.0065 (7)
N10.028 (2)0.064 (3)0.052 (3)−0.010 (2)0.000 (2)−0.008 (3)
N20.051 (3)0.044 (3)0.037 (3)−0.009 (2)0.000 (2)−0.011 (2)
N30.043 (2)0.031 (2)0.047 (3)−0.0069 (19)−0.006 (2)−0.003 (2)
Geometric parameters (Å, °) top
Ag1—N32.170 (4)C18—C191.361 (6)
Ag1—N22.184 (4)C18—H180.9300
Ag1—O32.583 (3)C19—C201.414 (5)
C1—N21.321 (5)C19—H190.9300
C1—C21.417 (6)C20—C211.404 (6)
C1—H10.9300C21—N31.337 (5)
C2—C31.404 (6)C21—H210.9300
C2—C71.425 (6)C22—H22A0.9600
C3—C41.366 (7)C22—H22B0.9600
C3—H30.9300C22—H22C0.9600
C4—C51.411 (8)C23—C241.364 (5)
C4—H40.9300C23—C261.412 (5)
C5—C61.345 (7)C23—S11.783 (4)
C5—H50.9300C24—C251.407 (6)
C6—C71.419 (6)C24—H240.9300
C6—H60.9300C25—C321.351 (6)
C7—C81.393 (6)C25—H250.9300
C8—C91.351 (6)C26—C271.421 (5)
C8—H80.9300C26—C311.434 (5)
C9—N21.380 (5)C27—C281.358 (5)
C9—C101.520 (6)C27—H270.9300
C10—H10A0.9600C28—C291.432 (5)
C10—H10B0.9600C28—H280.9300
C10—H10C0.9600C29—C301.364 (6)
C13—C141.349 (5)C29—N11.400 (5)
C13—N31.381 (5)C30—C311.411 (5)
C13—C221.516 (5)C30—H300.9300
C14—C151.422 (5)C31—C321.425 (6)
C14—H140.9300C32—H320.9300
C15—C201.408 (5)O1—S11.453 (3)
C15—C161.414 (6)O2—S11.450 (3)
C16—C171.364 (6)O3—S11.457 (3)
C16—H160.9300N1—H1N0.90 (3)
C17—C181.394 (6)N1—H2N0.81 (3)
C17—H170.9300
N3—Ag1—N2159.18 (13)C21—C20—C19123.2 (4)
N3—Ag1—O389.17 (12)C15—C20—C19119.5 (5)
N2—Ag1—O398.76 (13)N3—C21—C20125.0 (4)
N2—C1—C2124.9 (5)N3—C21—H21117.5
N2—C1—H1117.5C20—C21—H21117.5
C2—C1—H1117.5C13—C22—H22A109.5
C3—C2—C1122.3 (6)C13—C22—H22B109.5
C3—C2—C7120.7 (5)H22A—C22—H22B109.5
C1—C2—C7117.0 (5)C13—C22—H22C109.5
C4—C3—C2119.9 (6)H22A—C22—H22C109.5
C4—C3—H3120.1H22B—C22—H22C109.5
C2—C3—H3120.1C24—C23—C26120.7 (4)
C3—C4—C5120.5 (6)C24—C23—S1118.3 (4)
C3—C4—H4119.8C26—C23—S1121.0 (3)
C5—C4—H4119.8C23—C24—C25120.5 (4)
C6—C5—C4120.0 (7)C23—C24—H24119.8
C6—C5—H5120.0C25—C24—H24119.8
C4—C5—H5120.0C32—C25—C24120.8 (5)
C5—C6—C7122.5 (6)C32—C25—H25119.6
C5—C6—H6118.8C24—C25—H25119.6
C7—C6—H6118.8C23—C26—C27125.2 (4)
C8—C7—C6126.5 (6)C23—C26—C31118.9 (4)
C8—C7—C2117.0 (5)C27—C26—C31115.9 (4)
C6—C7—C2116.5 (5)C28—C27—C26122.4 (4)
C9—C8—C7121.8 (5)C28—C27—H27118.8
C9—C8—H8119.1C26—C27—H27118.8
C7—C8—H8119.1C27—C28—C29120.8 (4)
C8—C9—N2122.5 (5)C27—C28—H28119.6
C8—C9—C10123.1 (5)C29—C28—H28119.6
N2—C9—C10114.4 (5)C30—C29—N1123.4 (4)
C9—C10—H10A109.5C30—C29—C28118.7 (4)
C9—C10—H10B109.5N1—C29—C28117.9 (5)
H10A—C10—H10B109.5C29—C30—C31121.0 (4)
C9—C10—H10C109.5C29—C30—H30119.5
H10A—C10—H10C109.5C31—C30—H30119.5
H10B—C10—H10C109.5C30—C31—C32120.7 (4)
C14—C13—N3122.4 (4)C30—C31—C26121.0 (4)
C14—C13—C22121.6 (4)C32—C31—C26118.2 (4)
N3—C13—C22116.0 (4)C25—C32—C31120.8 (4)
C13—C14—C15121.0 (4)C25—C32—H32119.6
C13—C14—H14119.5C31—C32—H32119.6
C15—C14—H14119.5S1—O3—Ag1134.03 (16)
C20—C15—C16118.8 (4)O2—S1—O1113.23 (19)
C20—C15—C14117.5 (4)O2—S1—O3112.74 (17)
C16—C15—C14123.7 (4)O1—S1—O3111.9 (2)
C17—C16—C15120.6 (5)O2—S1—C23106.3 (2)
C17—C16—H16119.7O1—S1—C23106.46 (19)
C15—C16—H16119.7O3—S1—C23105.52 (18)
C16—C17—C18120.0 (5)C29—N1—H1N115 (3)
C16—C17—H17120.0C29—N1—H2N128 (3)
C18—C17—H17120.0H1N—N1—H2N103 (4)
C19—C18—C17121.5 (5)C1—N2—C9116.8 (4)
C19—C18—H18119.3C1—N2—Ag1116.9 (3)
C17—C18—H18119.3C9—N2—Ag1125.9 (4)
C18—C19—C20119.6 (4)C21—N3—C13116.8 (4)
C18—C19—H19120.2C21—N3—Ag1119.1 (3)
C20—C19—H19120.2C13—N3—Ag1123.9 (3)
C21—C20—C15117.3 (4)
N2—C1—C2—C3177.0 (4)C27—C28—C29—C30−2.2 (6)
N2—C1—C2—C7−0.7 (7)C27—C28—C29—N1179.7 (4)
C1—C2—C3—C4−178.5 (5)N1—C29—C30—C31−178.8 (4)
C7—C2—C3—C4−0.8 (8)C28—C29—C30—C313.2 (6)
C2—C3—C4—C5−1.4 (9)C29—C30—C31—C32176.0 (4)
C3—C4—C5—C61.9 (9)C29—C30—C31—C26−1.2 (6)
C4—C5—C6—C7−0.2 (9)C23—C26—C31—C30177.3 (4)
C5—C6—C7—C8178.1 (6)C27—C26—C31—C30−1.9 (6)
C5—C6—C7—C2−1.9 (8)C23—C26—C31—C320.1 (6)
C3—C2—C7—C8−177.6 (5)C27—C26—C31—C32−179.1 (4)
C1—C2—C7—C80.2 (7)C24—C25—C32—C31−2.0 (7)
C3—C2—C7—C62.4 (7)C30—C31—C32—C25−175.8 (4)
C1—C2—C7—C6−179.8 (4)C26—C31—C32—C251.5 (6)
C6—C7—C8—C9−178.8 (5)N3—Ag1—O3—S1−126.1 (3)
C2—C7—C8—C91.1 (7)N2—Ag1—O3—S173.2 (3)
C7—C8—C9—N2−2.1 (8)Ag1—O3—S1—O2−44.1 (3)
C7—C8—C9—C10178.2 (5)Ag1—O3—S1—O184.9 (3)
N3—C13—C14—C15−0.9 (7)Ag1—O3—S1—C23−159.8 (2)
C22—C13—C14—C15−179.9 (4)C24—C23—S1—O2−1.0 (4)
C13—C14—C15—C20−1.1 (6)C26—C23—S1—O2179.0 (3)
C13—C14—C15—C16179.4 (4)C24—C23—S1—O1−122.0 (4)
C20—C15—C16—C17−1.2 (6)C26—C23—S1—O158.0 (4)
C14—C15—C16—C17178.3 (4)C24—C23—S1—O3118.9 (4)
C15—C16—C17—C180.5 (7)C26—C23—S1—O3−61.0 (4)
C16—C17—C18—C190.4 (7)C2—C1—N2—C9−0.1 (7)
C17—C18—C19—C20−0.5 (7)C2—C1—N2—Ag1−172.5 (3)
C16—C15—C20—C21−178.2 (4)C8—C9—N2—C11.5 (7)
C14—C15—C20—C212.3 (6)C10—C9—N2—C1−178.7 (4)
C16—C15—C20—C191.0 (6)C8—C9—N2—Ag1173.1 (4)
C14—C15—C20—C19−178.5 (4)C10—C9—N2—Ag1−7.1 (6)
C18—C19—C20—C21179.0 (4)N3—Ag1—N2—C1−125.3 (4)
C18—C19—C20—C15−0.2 (6)O3—Ag1—N2—C1−13.9 (3)
C15—C20—C21—N3−1.8 (7)N3—Ag1—N2—C963.1 (6)
C19—C20—C21—N3179.0 (4)O3—Ag1—N2—C9174.5 (3)
C26—C23—C24—C250.7 (7)C20—C21—N3—C130.0 (6)
S1—C23—C24—C25−179.3 (3)C20—C21—N3—Ag1−174.9 (3)
C23—C24—C25—C320.9 (7)C14—C13—N3—C211.4 (6)
C24—C23—C26—C27178.0 (4)C22—C13—N3—C21−179.5 (4)
S1—C23—C26—C27−2.1 (6)C14—C13—N3—Ag1176.0 (3)
C24—C23—C26—C31−1.1 (6)C22—C13—N3—Ag1−4.9 (5)
S1—C23—C26—C31178.9 (3)N2—Ag1—N3—C21136.8 (4)
C23—C26—C27—C28−176.2 (4)O3—Ag1—N3—C2123.9 (3)
C31—C26—C27—C282.9 (6)N2—Ag1—N3—C13−37.6 (6)
C26—C27—C28—C29−0.9 (6)O3—Ag1—N3—C13−150.6 (3)
Hydrogen-bond geometry (Å, °) top
D—H···AD—HH···AD···AD—H···A
N1—H1N···O2i0.90 (4)2.51 (4)3.365 (5)160 (3)
N1—H2N···O1ii0.81 (4)2.30 (4)3.008 (5)146 (4)
Symmetry codes: (i) x+1, y, z; (ii) −x+2, −y+1, −z.
Table 1
Selected geometric parameters (Å, °) top
Ag1—N32.170 (4)Ag1—O32.583 (3)
Ag1—N22.184 (4)
N3—Ag1—N2159.18 (13)N2—Ag1—O398.76 (13)
N3—Ag1—O389.17 (12)
Table 2
Hydrogen-bond geometry (Å, °) top
D—H···AD—HH···AD···AD—H···A
N1—H1N···O2i0.90 (4)2.51 (4)3.365 (5)160 (3)
N1—H2N···O1ii0.81 (4)2.30 (4)3.008 (5)146 (4)
Symmetry codes: (i) x+1, y, z; (ii) −x+2, −y+1, −z.
Acknowledgements top

The authors thank JiLin Agriculture Science and Technology College (China) for support.

references
References top

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Sheldrick, G. M. (1997). SHELXS97 and SHELXL97. University of Göttingen, Germany.