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Acta Cryst. (2007). E63, m2420  [ doi:10.1107/S1600536807040809 ]

Bis([mu]-pyridine-1-carbaldehyde azine-[kappa]2N,N':[kappa]N'')disilver(I) bis(p-toluenesulfonate)

G. A. Broker and E. R. T. Tiekink

Abstract: The title compound, [Ag2(C12H10N4)2](p-CH3C6H4SO3)2, features a centrosymmetric dication and T-shaped AgN3 coordination geometry, as each ligand is tridentate, forming a bond to one Ag atom and chelating the other. The p-toluenesulfonate anion accepts a weak Ag...O contact [2.5023 (14) Å], as well as forming C-H...O interactions. The crystal structure comprises layers, stabilized by C-H...O contacts and connected by C-H...[pi] interactions.

Online 24 August 2007


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