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Acta Cryst. (2007). E63, o3682-o3683 [ doi:10.1107/S1600536807037117 ]
Abstract: The asymmetric unit of the title compound, C7H10N+·Cl-·H2O, contains a 2-methylanilinium cation, a chloride anion and one molecule of water. The crystal structure consists of alternating layers of hydrophobic and hydrophilic zones of o-toluidine along the c axis. The water molecules and the chloride anions are sandwiched between these layers. A large number of cation-anion, cation-water and water-anion hydrogen bonds result in a two-dimensional network which reinforces the cohesion of the ionic structure.
Online 3 August 2007
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