Acta Cryst. (2007). E63, m2302  [ doi:10.1107/S1600536807038603 ]

catena-Poly[[manganese(II)--[N,N,N',N'-tetrakis(2-pyridylmethyl)hexane-1,6-diamine]] bis(perchlorate) acetone disolvate dihydrate]

I.-C. Hwang and K. Ha

Abstract: The title compound, [Mn(C₃₀H₃₆N₆)](ClO₄)₂·2C₃H₆O·2H₂O, consists of a cationic complex polymer with counter-anions and solvent molecules. In the cationic polymer, Mn²⁺ ions are bridged by the hexadentate ligand N,N,N',N'-tetrakis(2-pyridylmethyl)hexane-1,6-diamine (tphn) to form a one-dimensional chain structure along the c axis. The repeat unit of the polymer, Mn^II(tphn), is disposed about a twofold axis passing through the Mn atom. The coordination geometry around the Mn centre is distorted octahedral.

Online 8 August 2007

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