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Acta Cryst. (2007). E63, m2294-m2295  [ doi:10.1107/S1600536807038536 ]

Aqua{6,6-dimethyl-2,2'-[o-phenylenebis(nitrilomethylidyne)]diphenolato-[kappa]4O,N,N',O'}zinc(II) chloroform solvate

N. E. Eltayeb, S. G. Teoh, S. Chantrapromma, H.-K. Fun and K. Ibrahim

Abstract: In the title compound, [Zn(C22H18N2O2)(H2O)]·CHCl3, the ZnII centre is in a five-coordinate square-pyramidal N2O3 environment, with the N2O2 set of atoms from the Schiff base ligand forming the basal plane; the water molecule occupies the apical position. Intermolecular O-H...O hydrogen bonds and weak C-H...O interactions link the molecules into a chain along [100]. The chains form sheets parallel to the ac plane.

Online 8 August 2007


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