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Acta Cryst. (2007). E63, m2272    [ doi:10.1107/S1600536807036902 ]

[mu]-Carbonyl-1:2[kappa]2C-carbonyl-1[kappa]C-(1[eta]5-cyclopentadienyl)([mu]-phenylvinylidene)bis(triphenylphosphine-2[kappa]P)rheniumplatinum(Re-Pt) diethyl ether hemisolvate

A. D. Vasiliev, O. S. Chudin and A. B. Antonova

Abstract top

The title compound, [PtRe(C5H5)(C8H6)(C18H15P)2(CO)2]·0.5C4H10O, represents the first example of a structurally characterized [mu]-vinylidene Re-Pt complex, and was obtained as a product of the addition of [Pt(PPh3)]2 to ([eta]5-C5H5)(CO)2Re=C=CHPh. The two metal atoms are bridged by the [mu]-phenylvinylidene ligand. The central fragment of the molecule is an almost planar methylenedimetallacyclopropane RePt([mu]-C=CHPh) system. The Re atom is bonded to the [eta]5-C5H5 ring and two CO groups, one of which has a tendency to a weak semi-bridging interaction with the Pt atom. The distorted square-planar coordination of the Pt atom is formed by the two P atoms of the PPh3 ligands, and by two C atoms of the C=CHPh ligand and one of the CO ligands. The solvent molecule is disordered equally over two positions.

Comment top

The molecule of the title compound, [η5-C5H5)(CO)2RePt (µ-C═CHPh)(PPh3)2] Et2O, is the dinuclear complex containing the Re and Pt atoms bridged by the µ-phenylvinylidene ligand. The phenyl ring and the C═C bond of vinylidene coupled with the Re—Pt-µ-C triangle form an almost planar system. Corresponding geometry was found for the analogous MnPt complex (Vasiliev et al., 2007). The structures of some µ-carbene (Casey et al., 1992; Bergamo et al., 2000) and µ-carbyne (Bergamo et al., 2000) complexes containing the Re—Pt-µ-C triangle system as the central fragment of molecule were reported.

Related literature top

The corresponding geometry in the analogous MnPt complex was reported by Vasiliev et al. (2007). For crystal structures of related µ-carbene complexes containing the Re–Pt–µ-C triangle system, see: Casey et al. (1992); Bergamo et al. (2000). For related literature, see: Allen et al. (1987).

Experimental top

The title compound was prepared by the interaction between Cp(CO)2Re═C═CHPh and Pt(PPh3)4 in benzene and at 298 K, 3 h. Suitable single crystals were obtained by recrystallization from ether at 298 K.

Refinement top

Seven phenyl cycles were idealized and refined as rigid groups with C—C bond lengths of 1.390 Å. All H atoms were positioned geometrically (C—H 0.93 Å) and refined using a riding model with Uiso(H) = 1.2Ueq(C).

There are the difference density maximum of 3.11 e/Å3 at a distance of 0.87Å from Re atom and the minimum of −1.48 e/Å3 at a distance of 0.68Å from the same atom.

The solvate diethyl ether molecule is situated close to the inversion center (the distance from the center to the oxygen atom about 0.5 Å) with the statistical occupancy of 0.5. A l l non-hydrogen atoms of the solvate molecule were refined isotropically and the C—O and C—C distances were restrained by SHELXL DFIX instructions to values of 1.43 and 1.50 Å respectively (Allen et al., 1987).

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SMART; data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXTL (Sheldrick, 2004); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Figures top
[Figure 1] Fig. 1. The molecular structure of title compound, with atom labels and 50% probability displacement ellipsoids for non-H atoms. H atoms, except for H2 atom, omitted for clarity.
µ-Carbonyl-1:2κ2C-carbonyl-1κC-(1η5– cyclopentadienyl)(µ- phenylvinylidene)bis(triphenylphosphine-2κP)rheniumplatinum(Re—Pt) diethyl ether hemisolvate top
Crystal data top
[PtRe(C5H5)(C8H6)(C18H15P)2(CO)2]·0.5C4H10OF000 = 2268
Mr = 1166.13Dx = 1.709 Mg m−3
Monoclinic, P21/cMo Kα radiation
λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 9791 reflections
a = 22.529 (1) Åθ = 2.4–27.4º
b = 9.1786 (5) ŵ = 5.86 mm−1
c = 21.941 (1) ÅT = 296 (2) K
β = 92.469 (1)ºBlock, orange
V = 4532.9 (4) Å30.36 × 0.21 × 0.18 mm
Z = 4
Data collection top
Bruker SMART 4K CCD area-detector
diffractometer		10402 independent reflections
Radiation source: fine-focus sealed tube7336 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.038
T = 296(2) Kθmax = 27.5º
φ and ω scansθmin = 1.9º
Absorption correction: multi-scan
(SADABS; Sheldrick, 2004)		h = −29→29
Tmin = 0.278, Tmax = 0.418k = −11→11
38759 measured reflectionsl = −28→28
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: constr
R[F2 > 2σ(F2)] = 0.031H-atom parameters constrained
wR(F2) = 0.073  w = 1/[σ2(Fo2) + (0.0315P)2 + 4.6963P]
where P = (Fo2 + 2Fc2)/3
S = 1.00(Δ/σ)max = 0.002
10402 reflectionsΔρmax = 3.11 e Å−3
453 parametersΔρmin = −1.48 e Å−3
4 restraintsExtinction correction: none
Primary atom site location: structure-invariant direct methods
Crystal data top
[PtRe(C5H5)(C8H6)(C18H15P)2(CO)2]·0.5C4H10OV = 4532.9 (4) Å3
Mr = 1166.13Z = 4
Monoclinic, P21/cMo Kα
a = 22.529 (1) ŵ = 5.86 mm−1
b = 9.1786 (5) ÅT = 296 (2) K
c = 21.941 (1) Å0.36 × 0.21 × 0.18 mm
β = 92.469 (1)º
Data collection top
Bruker SMART 4K CCD area-detector
diffractometer		10402 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 2004)		7336 reflections with I > 2σ(I)
Tmin = 0.278, Tmax = 0.418Rint = 0.038
38759 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0314 restraints
wR(F2) = 0.073H-atom parameters constrained
S = 1.00Δρmax = 3.11 e Å−3
10402 reflectionsΔρmin = −1.48 e Å−3
453 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Pt0.248866 (8)0.446207 (18)0.314347 (8)0.03293 (5)
Re0.186644 (9)0.56086 (2)0.215806 (8)0.04006 (6)
C110.1165 (3)0.5152 (8)0.1403 (3)0.0688 (17)
H110.08680.58330.13140.083*
C120.1711 (3)0.5085 (8)0.1141 (2)0.0674 (17)
H120.18430.57120.08430.081*
C130.2037 (3)0.3910 (7)0.1401 (3)0.0668 (17)
H130.24210.36330.13110.080*
C140.1675 (3)0.3247 (7)0.1818 (3)0.0712 (18)
H140.17770.24300.20510.085*
C150.1135 (3)0.3995 (8)0.1833 (3)0.0707 (18)
H150.08190.37790.20770.085*
P10.34065 (5)0.38572 (13)0.35326 (6)0.0352 (3)
P20.18454 (5)0.31895 (13)0.37882 (5)0.0371 (3)
C10.2770 (2)0.5451 (5)0.2392 (2)0.0387 (10)
C20.3310 (2)0.5629 (5)0.2158 (2)0.0462 (12)
H20.36190.52070.23900.055*
C30.1518 (2)0.6161 (6)0.2899 (2)0.0512 (13)
O30.12681 (18)0.6630 (5)0.33088 (18)0.0728 (12)
C40.1973 (3)0.7638 (7)0.2106 (2)0.0580 (15)
O40.2019 (3)0.8908 (5)0.2078 (2)0.0956 (17)
C50.35039 (15)0.6378 (4)0.15943 (13)0.0445 (12)
C60.41017 (14)0.6250 (4)0.14714 (16)0.0579 (15)
H60.43510.56770.17210.069*
C70.43266 (13)0.6977 (4)0.09758 (18)0.0716 (18)
H70.47270.68910.08940.086*
C80.39537 (19)0.7832 (4)0.06030 (14)0.075 (2)
H80.41040.83180.02710.090*
C90.33558 (18)0.7960 (4)0.07259 (15)0.0668 (17)
H90.31060.85330.04760.080*
C100.31309 (12)0.7233 (4)0.12215 (16)0.0547 (14)
H100.27310.73190.13040.066*
C160.39374 (13)0.5381 (3)0.36984 (15)0.0417 (11)
C170.44538 (14)0.5143 (3)0.40541 (15)0.0501 (13)
H170.45410.42150.42030.060*
C180.48397 (12)0.6292 (4)0.41877 (16)0.0584 (15)
H180.51850.61330.44260.070*
C190.47092 (15)0.7679 (3)0.39656 (18)0.0671 (17)
H190.49670.84470.40550.081*
C200.41928 (17)0.7917 (3)0.36100 (17)0.0654 (17)
H200.41050.88450.34610.078*
C210.38069 (13)0.6768 (3)0.34764 (15)0.0503 (13)
H210.34610.69270.32380.060*
C220.35058 (15)0.2911 (3)0.42695 (11)0.0381 (11)
C230.33064 (15)0.3641 (3)0.47767 (15)0.0492 (13)
H230.31100.45270.47290.059*
C240.34009 (17)0.3046 (4)0.53554 (12)0.0646 (16)
H240.32680.35350.56950.078*
C250.36947 (18)0.1722 (4)0.54270 (13)0.0702 (18)
H250.37580.13240.58140.084*
C260.38941 (16)0.0991 (3)0.49198 (18)0.0691 (18)
H260.40910.01050.49680.083*
C270.37996 (15)0.1586 (3)0.43411 (15)0.0518 (13)
H270.39330.10980.40020.062*
C280.37716 (14)0.2656 (3)0.29846 (14)0.0406 (11)
C290.43784 (14)0.2665 (4)0.28940 (17)0.0656 (16)
H290.46260.32970.31180.079*
C300.46151 (14)0.1729 (5)0.24695 (19)0.085 (2)
H300.50210.17360.24090.103*
C310.4245 (2)0.0784 (4)0.21355 (17)0.084 (2)
H310.44030.01580.18520.100*
C320.3638 (2)0.0775 (4)0.22261 (18)0.085 (2)
H320.33900.01430.20030.102*
C330.34014 (13)0.1711 (4)0.26506 (18)0.0662 (17)
H330.29950.17040.27110.079*
C340.10755 (13)0.2813 (4)0.34826 (16)0.0471 (12)
C350.06360 (18)0.3827 (4)0.35975 (18)0.0692 (17)
H350.07240.46300.38440.083*
C360.00648 (16)0.3642 (6)0.3344 (2)0.098 (3)
H36−0.02290.43210.34210.118*
C37−0.00669 (16)0.2442 (7)0.2976 (2)0.112 (3)
H37−0.04490.23180.28070.134*
C380.0373 (2)0.1428 (5)0.2861 (2)0.110 (3)
H380.02850.06250.26150.132*
C390.0944 (2)0.1614 (4)0.31145 (19)0.081 (2)
H390.12380.09350.30380.097*
C400.16695 (16)0.4012 (3)0.45167 (13)0.0417 (11)
C410.13200 (16)0.3307 (3)0.49323 (16)0.0573 (14)
H410.11710.23810.48460.069*
C420.11924 (18)0.3986 (5)0.54776 (15)0.0769 (19)
H420.09590.35140.57560.092*
C430.1414 (2)0.5370 (5)0.56073 (15)0.091 (2)
H430.13290.58240.59720.110*
C440.1764 (2)0.6075 (4)0.51916 (19)0.085 (2)
H440.19120.70010.52780.102*
C450.18914 (16)0.5396 (3)0.46463 (16)0.0554 (14)
H450.21250.58680.43680.066*
C460.21387 (15)0.1359 (3)0.39821 (14)0.0416 (11)
C470.22624 (17)0.0446 (4)0.34983 (12)0.0588 (15)
H470.21690.07380.31000.071*
C480.25250 (18)−0.0904 (3)0.36103 (16)0.0685 (17)
H480.2608−0.15150.32870.082*
C490.26641 (16)−0.1340 (3)0.4206 (2)0.0686 (18)
H490.2840−0.22430.42810.082*
C500.25405 (16)−0.0427 (4)0.46898 (14)0.0599 (15)
H500.2633−0.07190.50880.072*
C510.22778 (16)0.0922 (3)0.45779 (13)0.0485 (13)
H510.21950.15330.49020.058*
O50.0180 (7)0.0325 (16)0.5073 (8)0.143 (5)*0.50
C52−0.0330 (11)0.033 (3)0.5424 (10)0.165 (10)*0.50
H52A−0.0289−0.03140.57730.198*0.50
H52B−0.06860.00830.51810.198*0.50
C53−0.0324 (14)0.190 (3)0.5609 (13)0.186 (11)*0.50
H53A−0.06550.20950.58590.224*0.50
H53B−0.03530.25070.52520.224*0.50
H53C0.00400.21150.58360.224*0.50
C540.0247 (11)−0.115 (2)0.4895 (11)0.154 (9)*0.50
H54A−0.0133−0.15330.47420.185*0.50
H54B0.0381−0.17310.52440.185*0.50
C550.0689 (12)−0.124 (3)0.4409 (12)0.174 (10)*0.50
H55A0.0735−0.22360.42880.209*0.50
H55B0.1064−0.08680.45640.209*0.50
H55C0.0552−0.06710.40640.209*0.50
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt0.03140 (10)0.03758 (9)0.02984 (10)0.00111 (8)0.00179 (7)0.00230 (8)
Re0.04179 (12)0.04866 (12)0.02939 (10)0.00440 (9)−0.00239 (8)0.00195 (8)
C110.061 (4)0.092 (5)0.052 (4)0.001 (3)−0.020 (3)−0.013 (3)
C120.079 (5)0.093 (4)0.030 (3)−0.009 (4)0.001 (3)−0.005 (3)
C130.061 (4)0.085 (4)0.054 (4)0.005 (3)−0.006 (3)−0.027 (3)
C140.101 (6)0.054 (3)0.057 (4)−0.008 (4)−0.015 (4)−0.009 (3)
C150.064 (4)0.097 (5)0.050 (4)−0.020 (4)−0.007 (3)−0.004 (3)
P10.0319 (6)0.0366 (6)0.0369 (7)0.0020 (5)0.0011 (5)0.0019 (5)
P20.0382 (7)0.0398 (6)0.0333 (6)−0.0039 (5)0.0024 (5)0.0007 (5)
C10.039 (3)0.046 (3)0.031 (2)0.001 (2)0.003 (2)0.002 (2)
C20.044 (3)0.050 (3)0.044 (3)0.000 (2)0.001 (2)0.009 (2)
C30.042 (3)0.065 (3)0.046 (3)0.008 (3)−0.003 (3)0.004 (3)
O30.067 (3)0.097 (3)0.055 (3)0.024 (2)0.015 (2)−0.004 (2)
C40.081 (4)0.063 (4)0.031 (3)0.016 (3)−0.002 (3)0.002 (3)
O40.175 (5)0.048 (2)0.063 (3)0.010 (3)0.000 (3)0.005 (2)
C50.049 (3)0.047 (3)0.038 (3)−0.013 (2)0.005 (2)−0.004 (2)
C60.056 (4)0.071 (4)0.047 (3)−0.018 (3)0.007 (3)−0.005 (3)
C70.065 (4)0.086 (5)0.066 (4)−0.029 (4)0.026 (3)−0.010 (4)
C80.099 (6)0.074 (4)0.054 (4)−0.039 (4)0.021 (4)0.001 (3)
C90.082 (5)0.070 (4)0.048 (3)−0.015 (3)0.004 (3)0.013 (3)
C100.057 (4)0.061 (3)0.046 (3)−0.007 (3)0.004 (3)0.010 (3)
C160.040 (3)0.041 (3)0.044 (3)−0.003 (2)0.004 (2)−0.004 (2)
C170.042 (3)0.055 (3)0.053 (3)−0.005 (2)−0.003 (3)0.003 (3)
C180.043 (3)0.070 (4)0.061 (4)−0.011 (3)−0.002 (3)−0.006 (3)
C190.066 (4)0.062 (4)0.074 (4)−0.022 (3)0.010 (3)−0.019 (3)
C200.080 (5)0.038 (3)0.078 (4)−0.005 (3)0.000 (4)−0.003 (3)
C210.049 (3)0.041 (3)0.060 (3)0.005 (2)0.002 (3)−0.004 (2)
C220.037 (3)0.037 (2)0.040 (3)−0.004 (2)−0.004 (2)0.003 (2)
C230.054 (3)0.047 (3)0.046 (3)−0.004 (2)−0.005 (3)−0.002 (2)
C240.074 (4)0.077 (4)0.042 (3)−0.016 (3)−0.004 (3)0.004 (3)
C250.073 (4)0.077 (4)0.059 (4)−0.013 (4)−0.015 (3)0.032 (3)
C260.064 (4)0.056 (3)0.086 (5)0.003 (3)−0.009 (4)0.027 (3)
C270.051 (3)0.047 (3)0.057 (3)0.003 (2)0.004 (3)0.011 (3)
C280.040 (3)0.043 (3)0.039 (3)0.009 (2)0.003 (2)0.005 (2)
C290.047 (3)0.097 (5)0.054 (4)0.010 (3)0.009 (3)−0.006 (3)
C300.062 (4)0.134 (6)0.062 (4)0.028 (4)0.017 (3)−0.007 (4)
C310.097 (6)0.096 (5)0.059 (4)0.035 (4)0.021 (4)−0.010 (4)
C320.095 (6)0.083 (5)0.078 (5)−0.003 (4)0.009 (4)−0.032 (4)
C330.058 (4)0.066 (4)0.076 (4)−0.002 (3)0.017 (3)−0.029 (3)
C340.046 (3)0.058 (3)0.037 (3)−0.014 (3)0.002 (2)0.009 (2)
C350.040 (3)0.098 (5)0.070 (4)−0.004 (3)−0.001 (3)0.007 (4)
C360.046 (4)0.145 (8)0.102 (6)−0.003 (4)−0.007 (4)0.032 (6)
C370.063 (5)0.171 (9)0.099 (6)−0.053 (6)−0.025 (5)0.040 (6)
C380.095 (6)0.142 (8)0.091 (6)−0.057 (6)−0.022 (5)−0.006 (5)
C390.074 (5)0.092 (5)0.075 (5)−0.031 (4)−0.011 (4)−0.010 (4)
C400.042 (3)0.047 (3)0.036 (3)−0.001 (2)0.004 (2)−0.001 (2)
C410.065 (4)0.060 (3)0.048 (3)0.001 (3)0.017 (3)0.005 (3)
C420.077 (5)0.106 (5)0.050 (4)0.011 (4)0.023 (3)0.007 (4)
C430.088 (6)0.124 (7)0.061 (4)0.000 (5)0.005 (4)−0.042 (4)
C440.081 (5)0.095 (5)0.080 (5)−0.015 (4)0.017 (4)−0.046 (4)
C450.055 (3)0.057 (3)0.054 (3)−0.004 (3)0.004 (3)−0.013 (3)
C460.044 (3)0.038 (3)0.043 (3)−0.009 (2)0.001 (2)0.003 (2)
C470.066 (4)0.054 (3)0.057 (4)−0.002 (3)0.006 (3)−0.006 (3)
C480.076 (5)0.049 (3)0.081 (5)0.003 (3)0.007 (4)−0.012 (3)
C490.064 (4)0.043 (3)0.101 (5)0.003 (3)0.019 (4)0.014 (3)
C500.055 (4)0.059 (3)0.067 (4)0.001 (3)0.014 (3)0.026 (3)
C510.053 (3)0.047 (3)0.046 (3)−0.004 (2)0.008 (3)0.010 (2)
Geometric parameters (Å, °) top
Pt—C12.008 (4)C29—H290.9300
Pt—P12.2717 (12)C30—C311.3900
Pt—P22.3753 (12)C30—H300.9300
Pt—Re2.7360 (3)C31—C321.3900
Re—C41.883 (6)C31—H310.9300
Re—C31.905 (6)C32—C331.3900
Re—C12.083 (5)C32—H320.9300
Re—C112.278 (6)C33—H330.9300
Re—C122.294 (5)C34—C351.3900
Re—C152.305 (6)C34—C391.3900
Re—C132.322 (6)C35—C361.3900
Re—C142.327 (6)C35—H350.9300
C11—C121.382 (8)C36—C371.3900
C11—C151.424 (9)C36—H360.9300
C11—H110.9300C37—C381.3900
C12—C131.411 (9)C37—H370.9300
C12—H120.9300C38—C391.3900
C13—C141.391 (9)C38—H380.9300
C13—H130.9300C39—H390.9300
C14—C151.398 (9)C40—C411.3900
C14—H140.9300C40—C451.3900
C15—H150.9300C41—C421.3900
P1—C221.841 (3)C41—H410.9300
P1—C281.850 (3)C42—C431.3900
P1—C161.866 (3)C42—H420.9300
P2—C401.827 (3)C43—C441.3900
P2—C461.849 (3)C43—H430.9300
P2—C341.865 (3)C44—C451.3900
C1—C21.351 (6)C44—H440.9300
C2—C51.497 (5)C45—H450.9300
C2—H20.9300C46—C471.3900
C3—O31.163 (6)C46—C511.3900
C4—O41.171 (6)C47—C481.3900
C5—C61.3900C47—H470.9300
C5—C101.3900C48—C491.3900
C6—C71.3900C48—H480.9300
C6—H60.9300C49—C501.3900
C7—C81.3900C49—H490.9300
C7—H70.9300C50—C511.3900
C8—C91.3900C50—H500.9300
C8—H80.9300C51—H510.9300
C9—C101.3900O5—O5i1.05 (3)
C9—H90.9300O5—C54i1.23 (3)
C10—H100.9300O5—C52i1.30 (3)
C16—C171.3900O5—C521.409 (10)
C16—C211.3900O5—C541.420 (10)
C17—C181.3900C52—C54i1.05 (3)
C17—H170.9300C52—C55i1.23 (3)
C18—C191.3900C52—O5i1.30 (3)
C18—H180.9300C52—C531.498 (10)
C19—C201.3900C52—H52A0.97 (3)
C19—H190.9300C52—H52B0.97 (3)
C20—C211.3900C53—C55i1.02 (3)
C20—H200.9300C53—C54i1.32 (3)
C21—H210.9300C53—H53A0.96 (3)
C22—C231.3900C53—H53B0.96 (3)
C22—C271.3900C53—H53C0.96 (3)
C23—C241.3900C54—C52i1.05 (3)
C23—H230.9300C54—O5i1.23 (3)
C24—C251.3900C54—C53i1.32 (3)
C24—H240.9300C54—C551.491 (10)
C25—C261.3900C54—H54A0.97 (3)
C25—H250.9300C54—H54B0.97 (2)
C26—C271.3900C55—C53i1.02 (3)
C26—H260.9300C55—C52i1.23 (3)
C27—H270.9300C55—H55A0.96 (3)
C28—C291.3900C55—H55B0.96 (3)
C28—C331.3900C55—H55C0.96 (3)
C29—C301.3900
C1—Pt—P195.99 (14)C26—C25—C24120.0
C1—Pt—P2158.97 (14)C26—C25—H25120.0
P1—Pt—P2102.99 (4)C24—C25—H25120.0
C1—Pt—Re49.21 (14)C25—C26—C27120.0
P1—Pt—Re144.89 (3)C25—C26—H26120.0
P2—Pt—Re110.78 (3)C27—C26—H26120.0
C4—Re—C381.2 (2)C26—C27—C22120.0
C4—Re—C187.6 (2)C26—C27—H27120.0
C3—Re—C1104.0 (2)C22—C27—H27120.0
C4—Re—C11103.0 (2)C29—C28—C33120.0
C3—Re—C11111.8 (2)C29—C28—P1123.8 (2)
C1—Re—C11143.8 (2)C33—C28—P1116.2 (2)
C4—Re—C1299.4 (2)C30—C29—C28120.0
C3—Re—C12146.6 (2)C30—C29—H29120.0
C1—Re—C12109.4 (2)C28—C29—H29120.0
C11—Re—C1235.2 (2)C29—C30—C31120.0
C4—Re—C15135.1 (3)C29—C30—H30120.0
C3—Re—C1596.8 (2)C31—C30—H30120.0
C1—Re—C15135.2 (2)C32—C31—C30120.0
C11—Re—C1536.2 (2)C32—C31—H31120.0
C12—Re—C1559.2 (2)C30—C31—H31120.0
C4—Re—C13126.6 (2)C31—C32—C33120.0
C3—Re—C13151.2 (2)C31—C32—H32120.0
C1—Re—C1386.5 (2)C33—C32—H32120.0
C11—Re—C1359.2 (2)C32—C33—C28120.0
C12—Re—C1335.6 (2)C32—C33—H33120.0
C15—Re—C1359.1 (2)C28—C33—H33120.0
C4—Re—C14157.6 (2)C35—C34—C39120.0
C3—Re—C14116.4 (2)C35—C34—P2118.0 (2)
C1—Re—C14100.4 (2)C39—C34—P2121.8 (2)
C11—Re—C1458.8 (2)C34—C35—C36120.0
C12—Re—C1458.3 (2)C34—C35—H35120.0
C15—Re—C1435.1 (2)C36—C35—H35120.0
C13—Re—C1434.8 (2)C37—C36—C35120.0
C4—Re—Pt111.49 (16)C37—C36—H36120.0
C3—Re—Pt69.14 (15)C35—C36—H36120.0
C1—Re—Pt46.87 (12)C36—C37—C38120.0
C11—Re—Pt145.02 (18)C36—C37—H37120.0
C12—Re—Pt137.67 (18)C38—C37—H37120.0
C15—Re—Pt109.39 (17)C39—C38—C37120.0
C13—Re—Pt102.23 (17)C39—C38—H38120.0
C14—Re—Pt88.66 (16)C37—C38—H38120.0
C12—C11—C15108.1 (6)C38—C39—C34120.0
C12—C11—Re73.0 (3)C38—C39—H39120.0
C15—C11—Re72.9 (3)C34—C39—H39120.0
C12—C11—H11126.0C41—C40—C45120.0
C15—C11—H11126.0C41—C40—P2122.15 (19)
Re—C11—H11119.9C45—C40—P2117.85 (19)
C11—C12—C13108.8 (6)C42—C41—C40120.0
C11—C12—Re71.8 (3)C42—C41—H41120.0
C13—C12—Re73.3 (3)C40—C41—H41120.0
C11—C12—H12125.6C41—C42—C43120.0
C13—C12—H12125.6C41—C42—H42120.0
Re—C12—H12121.1C43—C42—H42120.0
C14—C13—C12106.9 (6)C44—C43—C42120.0
C14—C13—Re72.8 (3)C44—C43—H43120.0
C12—C13—Re71.1 (3)C42—C43—H43120.0
C14—C13—H13126.6C43—C44—C45120.0
C12—C13—H13126.6C43—C44—H44120.0
Re—C13—H13121.3C45—C44—H44120.0
C13—C14—C15109.6 (6)C44—C45—C40120.0
C13—C14—Re72.4 (3)C44—C45—H45120.0
C15—C14—Re71.6 (4)C40—C45—H45120.0
C13—C14—H14125.2C47—C46—C51120.0
C15—C14—H14125.2C47—C46—P2116.98 (19)
Re—C14—H14122.5C51—C46—P2122.84 (19)
C14—C15—C11106.5 (6)C46—C47—C48120.0
C14—C15—Re73.3 (4)C46—C47—H47120.0
C11—C15—Re70.9 (3)C48—C47—H47120.0
C14—C15—H15126.7C49—C48—C47120.0
C11—C15—H15126.7C49—C48—H48120.0
Re—C15—H15120.9C47—C48—H48120.0
C22—P1—C28104.41 (16)C50—C49—C48120.0
C22—P1—C1697.46 (15)C50—C49—H49120.0
C28—P1—C16105.92 (16)C48—C49—H49120.0
C22—P1—Pt121.31 (12)C49—C50—C51120.0
C28—P1—Pt108.92 (12)C49—C50—H50120.0
C16—P1—Pt117.11 (11)C51—C50—H50120.0
C40—P2—C46105.26 (16)C50—C51—C46120.0
C40—P2—C3499.07 (17)C50—C51—H51120.0
C46—P2—C34103.43 (17)C46—C51—H51120.0
C40—P2—Pt118.61 (11)O5i—O5—C54i76.8 (16)
C46—P2—Pt111.27 (12)O5i—O5—C52i72.8 (14)
C34—P2—Pt117.32 (13)C54i—O5—C52i124 (2)
C2—C1—Pt133.5 (4)O5i—O5—C5262.1 (16)
C2—C1—Re141.6 (4)C54i—O5—C5246.2 (14)
Pt—C1—Re83.92 (17)C52i—O5—C52134.8 (13)
C1—C2—C5132.0 (4)O5i—O5—C5457.4 (15)
C1—C2—H2114.0C54i—O5—C54134.2 (13)
C5—C2—H2114.0C52i—O5—C5445.0 (13)
O3—C3—Re171.5 (5)C52—O5—C54104.7 (15)
O4—C4—Re177.6 (6)C54i—C52—O5i73.4 (16)
C6—C5—C10120.0C55i—C52—O5i140 (3)
C6—C5—C2116.2 (3)C55i—C52—O5137 (3)
C10—C5—C2123.7 (3)O5i—C52—C53132 (2)
C5—C6—C7120.0O5—C52—C5399 (2)
C5—C6—H6120.0C54i—C52—H52A162 (3)
C7—C6—H6120.0C55i—C52—H52A103 (2)
C8—C7—C6120.0O5i—C52—H52A111 (2)
C8—C7—H7120.0O5—C52—H52A112 (2)
C6—C7—H7120.0C53—C52—H52A112 (2)
C9—C8—C7120.0C54i—C52—H52B88 (3)
C9—C8—H8120.0C55i—C52—H52B78 (2)
C7—C8—H8120.0O5i—C52—H52B70.8 (15)
C8—C9—C10120.0O5—C52—H52B112.0 (19)
C8—C9—H9120.0C53—C52—H52B112 (2)
C10—C9—H9120.0H52A—C52—H52B110 (2)
C9—C10—C5120.0C54i—C53—H53A135 (3)
C9—C10—H10120.0C52—C53—H53A109 (2)
C5—C10—H10120.0C55i—C53—H53B107 (3)
C17—C16—C21120.0C52—C53—H53B109 (2)
C17—C16—P1120.38 (18)H53A—C53—H53B109 (3)
C21—C16—P1119.60 (18)C55i—C53—H53C144 (4)
C16—C17—C18120.0C54i—C53—H53C114 (3)
C16—C17—H17120.0C52—C53—H53C109 (3)
C18—C17—H17120.0H53A—C53—H53C109 (3)
C17—C18—C19120.0H53B—C53—H53C109 (3)
C17—C18—H18120.0O5i—C54—C53i120 (3)
C19—C18—H18120.0C53i—C54—O5138 (2)
C20—C19—C18120.0O5i—C54—C55129 (2)
C20—C19—H19120.0O5—C54—C55109 (2)
C18—C19—H19120.0C52i—C54—H54A102 (3)
C19—C20—C21120.0O5—C54—H54A109.8 (17)
C19—C20—H20120.0C55—C54—H54A110 (2)
C21—C20—H20120.0O5i—C54—H54B121 (2)
C20—C21—C16120.0C53i—C54—H54B109.0 (18)
C20—C21—H21120.0O5—C54—H54B109.8 (19)
C16—C21—H21120.0C55—C54—H54B110 (2)
C23—C22—C27120.0H54A—C54—H54B108 (2)
C23—C22—P1116.39 (19)C54—C55—H55A109 (2)
C27—C22—P1123.46 (19)C52i—C55—H55B104 (3)
C24—C23—C22120.0C54—C55—H55B109 (3)
C24—C23—H23120.0H55A—C55—H55B109 (3)
C22—C23—H23120.0C54—C55—H55C109 (2)
C25—C24—C23120.0H55A—C55—H55C109 (3)
C25—C24—H24120.0H55B—C55—H55C109 (3)
C23—C24—H24120.0
Symmetry codes: (i) −x, −y, −z+1.
Acknowledgements top

This work was supported by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project No. NSh-4137.2006.2) and the Krasnoyarsk Regional Science Foundation (grants Nos. 10TS145 and 17 G002).

references
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