Acta Cryst. (2007). E63, m2376  [ doi:10.1107/S1600536807040238 ]

Bis{2,4-dibromo-6-[3-(cyclohexylammonio)propyliminomethyl]phenolato-²N,O}bis(thiocyanato-N)nickel(II) methanol disolvate

M. Liu, W.-B. Yuan, H.-W. Xu, Q. Zhang and J.-X. Li

Abstract: The title centrosymmetric Schiff base nickel(II) complex, [Ni(NCS)₂(C₁₆H₂₂Br₂N₂O)₂]·2CH₃OH, consists of a mononuclear complex molecule and two solvent methanol molecules. The Ni^II atom lies on an inversion centre and is six-coordinated by the imine N and phenolate O atoms of the two Schiff base ligands and by the N atoms of two thiocyanate ligands, in an octahedral coordination geometry. The cyclohexyl rings adopt chair conformations.

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