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Acta Cryst. (2007). E63, m2625-m2626  [ doi:10.1107/S1600536807047101 ]

Hexakis([mu]-naphthalene-1-acetato)bis[(1,10-phenanthroline)gadolinium(III)] N,N-dimethylformamide disolvate

Y.-F. Liu, H.-T. Xia, D.-Q. Wang and S.-P. Yang

Abstract: The title complex, [Gd2(C12H9O2)6(C12H8N2)2]·2C3H7NO, has a centrosymmetric structure. The Gd atom has a distorted monocapped square-antiprismatic coordination geometry. Molecules are linked into a chain by C-H...O hydrogen bonds parallel to a and into a sheet by C-H...[pi] hydrogen bonds parallel to the (100) plane; a combination of the a chains and (100) sheets generates a three-dimensional framework structure.

Online 29 September 2007


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